公开(公告)号：BR7805113A

公开(公告)日：1979-04-10

申请号：BR7805113

申请日：1978-08-09

Applicant: STANDARD OIL CO

Inventor： GRASSELLI R ,  BRAZDIL J ,  SURESH D

IPC: B01J23/24 ,  B01J23/31 ,  B01J23/88 ,  B01J27/057 ,  B01J27/192 ,  B01J35/00 ,  B01J37/02 ,  C07C45/34 ,  C07C45/35 ,  C07C51/25

Abstract: Process for forming multi-component oxide catalysts. According to the invention the key catalytic phase of the catalyst is preformed and the elements of the host-catalyst phase are added together or separately. The key catalytic phase contains a molybdate or a tungstate of Bi, Te, Sb, Sn Cu or mixtures thereof. A representative catalyst is 50% [Bi2Mo3O12] 1/2 [K0.1Ni2.5Co4.5Fe3P0.5Mo10.5 Ox] + 50% SiO2 In the production of this catalyst a preformed bismuth molybdate slurry is added to a host-catalyst slurry. The mixture was then dried, calcined, ground and calcined once again.

公开(公告)号：ZA7800690B

公开(公告)日：1978-12-27

申请号：ZA7800690

申请日：1978-02-06

Applicant: STANDARD OIL CO

Inventor： GUTTMANN A ,  GRASSELLI R ,  CALLAHAN J

IPC: C07C67/24 ,  B01J23/00 ,  B01J27/00 ,  C07B61/00 ,  C07C1/20 ,  C07C7/148 ,  C01G51/00 ,  A61K31/00 ,  C01G37/00

CPC classification number: C07C7/14891 ,  C07C1/20 ,  C07C67/24 ,  C07C11/09 ,  C07C11/10 ,  C07C69/54

公开(公告)号：IN145044B

公开(公告)日：1978-08-19

申请号：IN2377CA1975

申请日：1975-12-23

Applicant: STANDARD OIL CO OHIO

Inventor： SURESH D ,  GRASSELLI R

IPC: B01J23/02 ,  B01J23/28 ,  B01J23/30 ,  B01J23/31 ,  B01J23/32 ,  B01J23/68 ,  B01J23/88 ,  B01J23/887 ,  B01J23/888 ,  B01J23/89 ,  B01J27/192 ,  C07B61/00 ,  C07C255/08 ,  B01J11/06 ,  C07B3/00 ,  C07C121/32

公开(公告)号：IN144975B

公开(公告)日：1978-08-05

申请号：IN1413CA1975

申请日：1975-07-19

Applicant: STANDARD OIL CO OHIO

Inventor： SURESH D ,  GRASSELLI R ,  HARDMAN H

IPC: B01J23/88 ,  B01J23/887 ,  B01J23/89 ,  B01J27/02 ,  B01J27/192 ,  C07C45/34 ,  C07C45/35 ,  C07C51/25 ,  C07B3/00 ,  C07C47/22 ,  C07C51/32 ,  C07C53/22

Abstract: 1523141 Oxidation catalyst STANDARD OIL CO 15 July 1975 [22 July 1974 5 Aug 1974] 29589/75 Heading B1E [Also in Division C2] An oxidation catalyst used for the preparation of unsaturated aldehydes (see Division C2) formula wherein X is Ce, Th, Pr, Nb, Ge, Y, Zr, Ru, Ga, In, Cu, La, Ta, Sb or mixtures thereof; A is alkali metal or Tl or mixture thereof; D is Ni, Co, Mg, Mn, Zn, Cd, Ca, Sr or mixture thereof, except that D is not Mn unless X is Sb; E is P; As, B, S, Al or mixture thereof; a is greater than O but less than S; b and d are 0-4 except that b is not zero if X is Ga, In, La, Nb, Ge or Ta; c, f and g are 0.1-12; and X is a positive number. The catalyst may be supported, e.g. on alumina, silica, titania, zirconia or silicon carbide. The Examples relate to silicasupported catalysts formed by mixing a silica sol with solutions of compounds of the elements to be present, evaporating and calcining.

公开(公告)号：PT66580A

公开(公告)日：1977-06-01

申请号：PT6658077

申请日：1977-05-20

Applicant: STANDARD OIL CO

Inventor： MILLER A ,  ZAGATA R ,  GRASSELLI R

IPC: B01J23/00 ,  C07B61/00 ,  C07C67/39 ,  C07C69/54 ,  B01J23/28

Abstract: The production of acrylates and methacrylates, made by the oxidative esterification of propylene or isobutylene wherein gaseous reactants are contacted with one or more catalysts and ethylene or an alcohol can be advantageously conducted in a single fluid bed reactor to obtain the desired ester.

公开(公告)号：EG11347A

公开(公告)日：1977-02-28

申请号：EG14874

申请日：1974-04-28

Applicant: STANDARD OIL CO

Inventor： GRASSELLI R ,  TERRILL D ,  MILLER A

IPC: C07C57/05 ,  B01J23/30 ,  B01J27/186 ,  C07C45/35 ,  C07C51/00 ,  C07C51/21 ,  C07C51/25 ,  C07C67/00 ,  C07C57/04

公开(公告)号：BR7504681A

公开(公告)日：1976-07-06

申请号：BR7504681

申请日：1975-07-22

Applicant: STANDARD OIL CO

Inventor： GRASSELLI R ,  SURESH D ,  HARDMAN H

IPC: B01J23/88 ,  B01J23/887 ,  B01J23/89 ,  B01J27/02 ,  B01J27/192 ,  C07C45/34 ,  C07C45/35 ,  C07C51/25 ,  C07C47/22

Abstract: 1523141 Oxidation catalyst STANDARD OIL CO 15 July 1975 [22 July 1974 5 Aug 1974] 29589/75 Heading B1E [Also in Division C2] An oxidation catalyst used for the preparation of unsaturated aldehydes (see Division C2) formula wherein X is Ce, Th, Pr, Nb, Ge, Y, Zr, Ru, Ga, In, Cu, La, Ta, Sb or mixtures thereof; A is alkali metal or Tl or mixture thereof; D is Ni, Co, Mg, Mn, Zn, Cd, Ca, Sr or mixture thereof, except that D is not Mn unless X is Sb; E is P; As, B, S, Al or mixture thereof; a is greater than O but less than S; b and d are 0-4 except that b is not zero if X is Ga, In, La, Nb, Ge or Ta; c, f and g are 0.1-12; and X is a positive number. The catalyst may be supported, e.g. on alumina, silica, titania, zirconia or silicon carbide. The Examples relate to silicasupported catalysts formed by mixing a silica sol with solutions of compounds of the elements to be present, evaporating and calcining.

公开(公告)号：ZA7403514B

公开(公告)日：1975-05-28

申请号：ZA7403514

申请日：1974-06-03

Applicant: STANDARD OIL CO

Inventor： MILLER A ,  HARDMAN H ,  GRASSELLI R ,  SURESH D

IPC: B01J20060101 ,  B01J

公开(公告)号：BR7403459D0

公开(公告)日：1974-11-19

申请号：BR345974

申请日：1974-04-29

Applicant: STANDARD OIL CO

Inventor： MILLES A ,  GRASSELLI R ,  TERRILL D

IPC: C07C57/05 ,  B01J23/30 ,  B01J27/186 ,  C07C45/35 ,  C07C51/00 ,  C07C51/21 ,  C07C51/25 ,  C07C67/00 ,  C07C57/04 ,  C07C51/32

公开(公告)号：CA937949A

公开(公告)日：1973-12-04

申请号：CA61393

申请日：1969-09-08

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI R ,  HARDMAN H