公开(公告)号：US11685671B2

公开(公告)日：2023-06-27

申请号：US17592799

申请日：2022-02-04

Applicant: POSTECH RESEARCH AND BUSINESS DEVELOPMENT FOUNDATION

Inventor： Hyo Joo Kim ,  Woo Yong Um

IPC: C02F1/28 ,  B01J20/10 ,  B01J20/28 ,  B01J20/30 ,  C03B21/00 ,  C02F101/00

CPC classification number: C02F1/288 ,  B01J20/103 ,  B01J20/28057 ,  B01J20/28071 ,  B01J20/28083 ,  B01J20/3085 ,  C03B21/00 ,  C02F2101/00 ,  C03B2201/06 ,  C03B2201/12

Abstract: Provided is a hydrogen isotope adsorbent with differential binding properties and including mesoporous silica doped with fluorine.

公开(公告)号：US20230192529A1

公开(公告)日：2023-06-22

申请号：US18168731

申请日：2023-02-14

Applicant: D. SWAROVSKI KG

Inventor： Georg Czermak ,  Matthias Gander ,  Christina Streiter ,  Christian Gabl ,  Christian Lipp ,  Roy Layne Howell ,  Nina Stepanik

IPC: C03C3/076 ,  C03C1/00 ,  C03B19/12

CPC classification number: C03C3/076 ,  C03B19/12 ,  C03C1/006 ,  C03B2201/06 ,  C03B2201/40 ,  C03B2201/42

Abstract: A continuous sol-gel process for producing silicate-containing glasses and glass ceramics is proposed, comprising the following steps:

(a) continuously feeding a silicon tetraalkoxide, a silicon alkoxide with at least one non-alcoholic functional group and an alcohol into a first reactor (R1), and at least partially hydrolyzing by the addition of a mineral acid to obtain a first product stream (A);
(b) continuously providing a second product stream (B) in a second reactor (R2) by feeding a metal alkoxide component or continuously mixing an alcohol and a metal alkoxide component;
(c) continuously mixing product streams (A) and (B) in a third reactor (R3) for producing a presol to obtain a third product stream (C);
(d) continuously adding water or a diluted acid to the product stream (C) to obtain a sol (gelation);
(e) continuously filling the emerging sol into molds to obtain an aquagel;
(f) drying the aquagels to obtain xerogels;
(g) sintering the xerogels to obtain silicate-containing glasses and glass ceramics.

公开(公告)号：US09518218B2

公开(公告)日：2016-12-13

申请号：US14411332

申请日：2013-06-25

Applicant: Heraeus Quarzglas GmbH & Co. KG

Inventor： Mario Such ,  Gerhard Schoetz ,  Andreas Langner

IPC: C09K11/77 ,  C01B33/18 ,  C03B19/06 ,  C09K11/02 ,  C03C1/00 ,  C03C4/12 ,  C03C3/06

CPC classification number: C09K11/7706 ,  C01B33/18 ,  C03B19/066 ,  C03B2201/06 ,  C03B2201/32 ,  C03B2201/34 ,  C03B2201/36 ,  C03C1/006 ,  C03C3/06 ,  C03C3/061 ,  C03C4/12 ,  C03C2201/06 ,  C03C2201/3488 ,  C03C2201/36 ,  C09K11/025

Abstract: The invention relates to a method for producing a doped SiO2 slurry in which an SiO2 suspension is brought into interaction with at least one doping solution, wherein the SiO2 suspension and/or the doping solution act on one another in the form of an atomized spray, the average droplet diameter of which is in the range between 10 μm and 100 μm. The invention further relates to the use of an SiO2 slurry doped by the atomized spray method for the production of doped quartz glass, particularly for the production of laser-active quartz glass.

Abstract translation: 本发明涉及一种用于制备掺杂SiO 2浆料的方法，其中SiO 2悬浮液与至少一种掺杂溶液相互作用，其中SiO 2悬浮液和/或掺杂溶液以雾化喷雾的形式彼此作用， 其平均液滴直径在10μm和100μm之间的范围内。 本发明还涉及通过雾化喷雾方法掺杂的SiO 2浆料用于生产掺杂石英玻璃，特别是用于生产激光活性石英玻璃的用途。

公开(公告)号：US20160147010A1

公开(公告)日：2016-05-26

申请号：US14943190

申请日：2015-11-17

Applicant: SUMITOMO ELECTRIC INDUSTRIES, LTD.

Inventor： Yoshiaki TAMURA ,  Tetsuya HARUNA ,  Yoshihiro SAITO ,  Yuki KAWAGUCHI ,  Masaaki HIRANO

IPC: G02B6/02

CPC classification number: G02B6/02 ,  C03B37/01211 ,  C03B37/014 ,  C03B37/01807 ,  C03B37/01861 ,  C03B37/01892 ,  C03B2201/06 ,  C03B2201/07 ,  C03B2201/12 ,  C03B2201/20 ,  C03B2201/50 ,  C03B2203/22 ,  C03B2203/26 ,  C03B2205/40 ,  C03C3/06 ,  C03C13/045 ,  C03C2201/11 ,  C03C2201/12 ,  C03C2201/50 ,  C03C2203/40

Abstract: An optical fiber containing an alkali metal and capable of reducing Rayleigh scattering loss is provided. An optical fiber has a core and a cladding made of silica glass and enclosing the core. The cladding contains fluorine and has a refractive index lower than the refractive index of the core. The core contains first group dopants selected from the group of Na element, K element, or a compound thereof at an average concentration of 0.2 ppm or more and 10 ppm or less. The core also contains second group dopants for reducing the viscosity of silica glass and having a diffusion coefficient of 1×10−12 cm2/s or more and smaller than the diffusion coefficient of the first group dopants, by an average concentration of 0.2 ppm or more at a temperature of 2000° C. to 2300° C.

Abstract translation: 提供含有碱金属并能够降低瑞利散射损失的光纤。 光纤具有由石英玻璃制成的芯和包层，并且包围芯。 包层含氟，折射率低于芯的折射率。 核心包含平均浓度为0.2ppm以上且10ppm以下的选自Na元素，K元素或其化合物的第一族掺杂剂。 该芯还含有第二组掺杂剂，用于降低石英玻璃的粘度，并且扩散系数为1×10-12cm2 / s以上且小于第一组掺杂剂的扩散系数，平均浓度为0.2ppm或 更高温度在2000°C至2300°C

公开(公告)号：US08571371B2

公开(公告)日：2013-10-29

申请号：US13160760

申请日：2011-06-15

Applicant: Daniel J. Gibson ,  Jasbinder S. Sanghera ,  Frederic H. Kung ,  Pablo C Pureza ,  Robert E Miklos ,  Guillermo R. Villalobos ,  Leslie Brandon Shaw ,  Ishwar D. Aggarwal

Inventor： Daniel J. Gibson ,  Jasbinder S. Sanghera ,  Frederic H. Kung ,  Pablo C Pureza ,  Robert E Miklos ,  Guillermo R. Villalobos ,  Leslie Brandon Shaw ,  Ishwar D. Aggarwal

IPC: G02B6/032

CPC classification number: C03B37/0122 ,  C03B37/01274 ,  C03B2201/06 ,  C03B2201/60 ,  C03B2201/62 ,  C03B2201/70 ,  C03B2201/78 ,  C03B2201/86 ,  C03B2201/88 ,  C03B2203/14 ,  C03B2203/16 ,  C03B2203/42 ,  C03C3/321 ,  C03C4/10 ,  C03C13/043 ,  G02B6/02328 ,  G02B6/02347

Abstract: A method and apparatus for making a substantially void-free preform for a microstructured optical fiber using a one-step process is provided. A preform is prepared from specialty glasses using a direct extrusion method. A die for use with the direct extrusion method is also provided, and a method for drawing the preform into a HC-PBG fiber for use in transmitting infra-red wavelength light is also provided. The preform comprises an outer jacket made of solid glass, a cladding having a plurality of air holes arranged in a desired pattern within the jacket, and a core which is hollow.

Abstract translation: 提供一种用于使用一步法制造用于微结构光纤的基本上无空隙的预制件的方法和装置。 使用直接挤出法从特种玻璃制备预制件。 还提供了一种用于直接挤压方法的模具，还提供了一种用于将预成型件拉制成用于传输红外波长光的HC-PBG纤维的方法。 预成型件包括由实心玻璃制成的外套，具有以夹套内的所需图案布置的多个气孔的包层和中空的芯。

公开(公告)号：US08230701B2

公开(公告)日：2012-07-31

申请号：US12154908

申请日：2008-05-28

Applicant: Raymond D Groh ,  Brian Lee Harper ,  John Edward Maxon

Inventor： Raymond D Groh ,  Brian Lee Harper ,  John Edward Maxon

IPC: C03B37/018

CPC classification number: C03B19/1423 ,  C03B2201/02 ,  C03B2201/06 ,  C03B2207/52 ,  C03B2207/62 ,  C03B2207/70 ,  Y02P40/57

Abstract: A method for forming a silica glass blank includes generating soot using an array of soot producing burners, directing the soot along a first direction onto a bait, collecting the soot on the bait, imparting relative oscillatory motion having a repeat period between the array of soot producing burners and the bait along a second direction orthogonal to the first direction while collecting the soot, and offsetting the relative oscillatory motion by a selected distance along the second direction after each repeat period.

Abstract translation: 一种用于形成二氧化硅玻璃坯料的方法包括使用产生烟炱的燃烧器阵列产生烟灰，将烟尘沿第一方向引导到诱饵上，将烟炱收集在诱饵上，赋予在烟炱阵列之间具有重复周期的相对振荡运动 在收集烟灰的同时沿着与第一方向正交的第二方向产生燃烧器和诱饵，并且在每个重复周期之后沿着第二方向将相对振荡运动偏移选定的距离。

公开(公告)号：US20110314874A1

公开(公告)日：2011-12-29

申请号：US13165236

申请日：2011-06-21

Applicant: Takayuki KITAMURA

Inventor： Takayuki KITAMURA

IPC: C03B37/018

CPC classification number: C03B37/01413 ,  C03B37/01807 ,  C03B37/01815 ,  C03B2201/06 ,  C03B2201/50 ,  C03B2201/54 ,  C03B2207/80 ,  C03B2207/90

Abstract: An apparatus for manufacturing a glass perform, includes: a dummy tube section, a reservoir portion, and a cooling portion; and a glass tube section in which particles of an alkali metal compound or an alkaline earth metal compound which have flowed into the glass tube section from the dummy tube section are heated by a second heat source which performs traverse, and oxides of the particles being deposited on an inner wall and dispersed in the glass tube section. In the cooling portion of the dummy tube section, vapor of the alkali metal compound or the alkaline earth metal compound generated by heating of a first heat source is cooled and condensed by a dry gas flowing into the dummy tube section, and thereby the particles are generated.

Abstract translation: 一种玻璃制造装置，包括：虚拟管部，储存部和冷却部; 以及玻璃管部分，其中由虚拟管部分流入玻璃管部分的碱金属化合物或碱土金属化合物的颗粒被进行横越的第二热源加热，并且沉积的颗粒的氧化物 在内壁上分散在玻璃管部分。 在虚拟管部的冷却部中，通过第一热源的加热而产生的碱金属化合物或碱土金属化合物的蒸气被流入虚拟管部的干燥气体冷却并冷凝， 生成。

公开(公告)号：US20040216492A1

公开(公告)日：2004-11-04

申请号：US10857684

申请日：2004-05-28

Applicant: Universidad de Sevilla and Flow Focusing, Inc.

Inventor： Alfonso M. Ganan-Calvo ,  Dianna L. DeVore

IPC: C03B037/06

CPC classification number: C03B37/027 ,  C03B37/023 ,  C03B2201/06 ,  C03B2203/42 ,  Y02P40/57

Abstract: The invention is directed to the production of optical fibers from optical fiber preforms using flow physics. The present methods provide for the nulldrawingnull of an optical fiber preform using focusing of the preform by a surrounding fluid, e.g. a heated gas.

公开(公告)号：US06312656B1

公开(公告)日：2001-11-06

申请号：US08903501

申请日：1997-07-30

Applicant: Jeffery Lynn Blackwell ,  Xiaodong Fu ,  Daniel Warren Hawtof ,  Dale Robert Powers

Inventor： Jeffery Lynn Blackwell ,  Xiaodong Fu ,  Daniel Warren Hawtof ,  Dale Robert Powers

IPC: C01B3312

CPC classification number: B01J19/26 ,  B01J2219/00157 ,  B01J2219/00159 ,  C01B33/183 ,  C03B19/106 ,  C03B19/1415 ,  C03B19/1423 ,  C03B37/01413 ,  C03B37/0142 ,  C03B2201/06 ,  C03B2207/06 ,  C03B2207/14 ,  C03B2207/20 ,  C03B2207/32 ,  C03B2207/34 ,  C03B2207/42 ,  C03C1/00 ,  C03C3/06 ,  C03C2201/06 ,  C03C2203/40 ,  Y02P40/57

Abstract: The present invention is directed to a method for making silica. A liquid, preferably halide-free, silicon-containing compound capable of being converted by thermal oxidative decomposition to SiO2 is provided and introduced directly into the flame of a combustion burner, which converts the compound to silica, thereby forming finely divided amorphous soot. The soot is vaporized at the site where the liquid is converted into silica by pneumatically atomizing the liquid with a stream of oxygen gas, or a mixture of oxygen gas and nitrogen gas. The amorphous soot is deposited on a receptor surface where, either substantially simultaneously with or subsequently to its deposition, the soot is consolidated into a body of fused silica glass.

Abstract translation: 本发明涉及制备二氧化硅的方法。 提供能够通过热氧化分解转化为SiO 2的液体，优选不含卤素的含硅化合物，并将其直接引入燃烧器的火焰中，该燃烧器将该化合物转化为二氧化硅，从而形成细碎的无定形烟灰。 在通过用氧气流或氧气和氮气的混合物气动雾化液体的情况下，在将液体转化为二氧化硅的位置将烟灰气化。 无定形烟灰沉积在受体表面上，其中基本上同时或随后沉积，烟灰被固结成熔融石英玻璃体。

公开(公告)号：US5991486A

公开(公告)日：1999-11-23

申请号：US962371

申请日：1997-10-31

Applicant: Marco Braglia

Inventor： Marco Braglia

IPC: G02B6/00 ,  C03B37/012 ,  C03B37/014 ,  C03B37/023 ,  C03B37/027 ,  C03C3/32 ,  C03C13/04 ,  H01S3/06 ,  H01S3/10 ,  G02B6/16

CPC classification number: C03C13/046 ,  C03B37/01211 ,  C03B37/01268 ,  C03B37/027 ,  C03C13/041 ,  C03C13/043 ,  C03B2201/06 ,  C03B2201/30 ,  C03B2201/40 ,  C03B2201/42 ,  C03B2201/80 ,  C03B2201/82 ,  C03B2201/86 ,  C03B2203/24

Abstract: An active single-mode optical fiber has the core made of a rare earth doped non-oxide glass and the cladding made of an oxide glass. The glass of the core has a melting temperature lower than that of the glass of the cladding and lying within the range of the softening temperatures of the latter. In a preferred embodiment the core is made of a chalcogenide glass and the cladding is made of a lead silicate glass. To produce the fiber, a preform, obtained by introducing an element made of the non-oxide glass into the hole of a capillary tube made of the oxide glass, is brought to a temperature lying within the range of softening temperatures of the oxide glass and not lower than the melting temperature of the non-oxide glass, and is drawn. The capillary tube, during the drawing process, serves as a container for the molten glass of the core.

Abstract translation: 有源单模光纤具有由稀土掺杂的非氧化物玻璃制成的芯和由氧化物玻璃制成的包层。 芯的玻璃的熔融温度低于包层玻璃的熔化温度，并且处于软化温度的范围内。 在优选实施例中，芯由硫族化物玻璃制成，并且包层由硅酸铅玻璃制成。 为了制造纤维，通过将由非氧化物玻璃制成的元件引入到由氧化物玻璃制成的毛细管的孔中而获得的预成型体达到处于氧化物玻璃的软化温度范围内的温度， 不低于非氧化物玻璃的熔融温度，并被拉伸。 毛细管在拉伸过程中用作芯的熔融玻璃的容器。