公开(公告)号：KR1020110079480A

公开(公告)日：2011-07-07

申请号：KR1020100082354

申请日：2010-08-25

Applicant: 제일모직주식회사

Inventor： 고창홍 ,  이선애 ,  배임혁 ,  주범준 ,  이원기

IPC: C08K5/53 ,  C08L69/00 ,  C08L53/02 ,  C08G79/02

CPC classification number: C08G79/04 ,  C08L51/04 ,  C08L55/02 ,  C08L69/00 ,  C08L85/02 ,  C08L2201/02 ,  C09K21/14 ,  C08L2666/02

Abstract: PURPOSE: A thermoplastic resin composition, a plastic molded article produced therefrom, and a method for preparing a polymerizable phosphorus-based compound are provided to ensure excellent flame retardancy, impact resistance, heat resistance, and fluidity. CONSTITUTION: A thermoplastic resin composition comprises: 100 wt % of a base resin including 30 to 100 wt % of a polycarbonate-based resin; and 0.1 to 40 wt % of a polymerizable phosphorus-based compound represented by chemical formula 1. In chemical formula 1, A is a single bond, C1-C5 alkylene, C1-C5 alkylidene, C5-C6 cycloalkylidene, -S- or -SO2-; R is C1-C20 aryl; and n is an integer of 4 - 500. The base resin comprises 30~100 weight% of a polycarbonate resin and 0~70 weight% of a rubber-modified aromatic vinyl polymer.

Abstract translation: 目的：提供一种热塑性树脂组合物，由其制造的塑料模塑制品和可聚合的磷基化合物的制备方法，以确保优异的阻燃性，耐冲击性，耐热性和流动性。 构成：热塑性树脂组合物包含：100重量％的基础树脂，其包含30至100重量％的聚碳酸酯基树脂; 在化学式1中，A为单键，C1-C5亚烷基，C1-C5亚烷基，C5-C6亚环烷基，-S-或 - SO2-; R是C 1 -C 20芳基; n为4〜500的整数。该基础树脂包含30〜100重量％的聚碳酸酯树脂和0〜70重量％的橡胶改性芳族乙烯基聚合物。

公开(公告)号：KR1020100078561A

公开(公告)日：2010-07-08

申请号：KR1020080136857

申请日：2008-12-30

Applicant: 제일모직주식회사

Inventor： 김만석 ,  김우중 ,  주범준 ,  이선애 ,  이변근

IPC: C08L69/00 ,  C08L53/02 ,  C08K5/527 ,  C08J5/00

Abstract: PURPOSE: A non-halogen flame-retarding polycarbonate resin composition is provided to secure the stability to the fire, and to prevent the environmental contamination by avoid using a halogen based flame retardant. CONSTITUTION: A non-halogen flame-retarding polycarbonate resin composition contains the following: 100 parts of base resin by weight formed with 50~100wt% of polycarbonate resin, and 0~50wt% of rubber-modified styrenic resin; 0.5~20 parts of cyclic benzyl phosphonate compound by weight marked with chemical formula 1; and 0~20 parts of aromatic phosphate ester compound by weight. In the chemical formula 1, R1, R1`, R2, and R2` are hydrogen, a C1~C8 alkyl group, a C6~C20 aryl group, or a C1~C8 alkyl-substituted C6~C20 aryl group.

Abstract translation: 目的：提供无卤阻燃聚碳酸酯树脂组合物以确保火灾的稳定性，并且通过避免使用卤素类阻燃剂来防止环境污染。 构成：无卤阻燃聚碳酸酯树脂组合物含有：由50〜100重量％的聚碳酸酯树脂形成的100重量份的基础树脂和0〜50重量％的橡胶改性苯乙烯树脂; 0.5〜20份以化学式1表示的重量的环状苄基膦酸酯化合物; 和0〜20份重量的芳族磷酸酯化合物。 在化学式1中，R 1，R 1，R 2和R 2'是氢，C 1〜C 8烷基，C 6〜C 20芳基或C 1〜C 8烷基取代的C 6〜C 20芳基。

公开(公告)号：KR1020100075184A

公开(公告)日：2010-07-02

申请号：KR1020080133816

申请日：2008-12-24

Applicant: 제일모직주식회사

Inventor： 이선애 ,  주범준 ,  김명준

IPC: C08K3/10 ,  C08L101/00

CPC classification number: C08K3/10 ,  C08K3/30 ,  C08K5/0066 ,  C08L55/02 ,  C08L69/00 ,  C08L71/00 ,  C08L101/00 ,  C08L2201/02

Abstract: PURPOSE: A flameproof thermoplastic resin composition is provided to secure the environment-friendly property of the composition by using an environment-friendly compound instead of a halogen based flame retardant, or a phosphate flame retardant. CONSTITUTION: A flameproof thermoplastic resin composition contains 100 parts of thermoplastic resin by weight, and 0.1~40 parts of selenium based flame retardant by weight. A thermoplastic resin is selected from the group consisting of an aromatic vinyl resin, a rubber modified aromatic vinyl resin, a polyphenylene resin, a polycarbonate resin, a polyester resin, a methacrylate resin, a polyarylene sulfide resin, a polyamide resin, a polyvinylchloride resin, a polyolefin resin, and their compound.

Abstract translation: 目的：提供一种防火热塑性树脂组合物，以通过使用环境友好的化合物代替卤素阻燃剂或磷酸酯阻燃剂来确保组合物的环境友好性。 构成：防火热塑性树脂组合物含有100重量份的热塑性树脂，和0.1-40重量份的基于硒的阻燃剂。 热塑性树脂选自芳族乙烯基树脂，橡胶改性芳族乙烯基树脂，聚苯醚树脂，聚碳酸酯树脂，聚酯树脂，甲基丙烯酸酯树脂，聚芳硫醚树脂，聚酰胺树脂，聚氯乙烯树脂 ，聚烯烃树脂及其化合物。

公开(公告)号：KR1020100075172A

公开(公告)日：2010-07-02

申请号：KR1020080133801

申请日：2008-12-24

Applicant: 제일모직주식회사

Inventor： 이선애 ,  주범준 ,  이변근 ,  김명준

IPC: C08L69/00 ,  C08L53/02 ,  C08K3/38 ,  C08J5/00

Abstract: PURPOSE: A thermoplastic resin composition is provided for molding electrical/electronic material with improved heat resistance, and to secure the environment-friendly property of the composition. CONSTITUTION: A thermoplastic resin composition with improved fire retardant property contains the following: 30~100 parts of polycarbonate resin by weight; 0~70 parts of rubber-modified aromatic vinyl polymer by weight; and 0.1~40 parts of boron-based compound by weight marked as chemical formula 2, for 100 parts of base resin by weight including the polycarbonate resin and the rubber-modified aromatic vinyl polymer. In the chemical formula 2, R1, R2, and R3 are an amine group, a sulfone group, a hydroxyl group, a phenol group, a phenyl group, an alkyl group of C1~C10, and others, respectively.

Abstract translation: 目的：提供热塑性树脂组合物，用于模塑具有改善的耐热性的电气/电子材料，并确保组合物的环境友好性。 构成：具有改善阻燃性能的热塑性树脂组合物包含以下物质：30〜100重量份的聚碳酸酯树脂; 橡胶改性芳族乙烯基聚合物重量为0〜70份; 和0.1〜40份以化学式2表示的重量的硼基化合物，对于100重量份的包含聚碳酸酯树脂和橡胶改性的芳族乙烯基聚合物的基础树脂。 在化学式2中，R1，R2和R3分别是胺基，砜基，羟基，苯酚基，苯基，C1〜C10的烷基等。

公开(公告)号：KR100890901B1

公开(公告)日：2009-04-03

申请号：KR1020070138422

申请日：2007-12-27

Applicant: 제일모직주식회사

Inventor： 이선애 ,  주범준 ,  김준명

IPC: C08L25/06 ,  C08L71/10 ,  C08L67/03 ,  C08K5/49

Abstract: A flameproof styrene-based resin composition having phosphorus-based compounds as a flame retardant is provided to ensure excellent chemical resistance and flame retardancy by applying the phosphorus-based compounds to a blend of styrene-based copolymer, polyphenylene ether resin and polyethylene terephthalate resin. A flameproof styrene-based resin composition having phosphorus-based compounds as a flame retardant comprises a 100 part of base resin and 1~30 part of one or more phosphorus-based compounds selected from the group consisting of alkyl phosphinic acid metal salt compounds and aromatic phosphoric acid ester compounds by weight. The base resin contains 40~98wt% of styrene-based resin, 1~30wt% of polyphenylene ether resin, and 1~30wt% of polyethylene terephthalate resin.

Abstract translation: 提供具有磷系化合物作为阻燃剂的防火苯乙烯类树脂组合物，以通过将苯基类共聚物，聚苯醚树脂和聚对苯二甲酸乙二醇酯树脂的共混物施用于磷系化合物来确保优异的耐化学性和阻燃性。 具有磷基化合物作为阻燃剂的防火苯乙烯类树脂组合物包括100份基础树脂和1〜30份选自烷基次膦酸金属盐化合物和芳族化合物的一种或多种磷基化合物 磷酸酯化合物。 基础树脂含有苯乙烯系树脂40〜98重量％，聚苯醚树脂1〜30重量％，聚对苯二甲酸乙二醇酯树脂1〜30重量％。

公开(公告)号：KR100842205B1

公开(公告)日：2008-06-30

申请号：KR1020070060801

申请日：2007-06-20

Applicant: 제일모직주식회사

Inventor： 장복남 ,  최진환 ,  주범준 ,  김진환 ,  김우중 ,  니옌콩트란

IPC: C07F9/6564 ,  C07F9/6584

CPC classification number: C07F9/657172 ,  C08K5/5313 ,  C08L2201/02 ,  C08L2666/84 ,  C09K21/12

Abstract: A phosphorous-containing cyclic compound is provided to improve flameproof effects when the compound is applied to thermoplastic resin by increasing phosphorous content and inhibit environment pollution by burning through suppression of halogenized gas release. A phosphorous-containing cyclic compound represented by the formula(1), in which R is hydrogen atom or C1-C6 alkyl, phenyl or phenoxy; and n is 1 or 2, is prepared by reacting 2-(6-oxid-6H-dibezoxa-phosphorin-6-yl)methanol with compounds represented by the formula(3) in organic solvent at 90-120 deg. C, wherein the organic solvent is selected from benzene, toluene, xylene, 1,4-dioxane, dichloromethane and dichloroethane. A flameproof thermoplastic resin composition comprises 0.1-50 parts by weight of the phosphorous-containing cyclic compound represented by the formula(1), and 100 parts by weight of thermoplastic resin.

Abstract translation: 提供含磷环状化合物以通过增加磷含量并通过抑制卤化气体释放而燃烧而抑制环境污染而将化合物施用于热塑性树脂时提高隔爆效果。 由式（1）表示的含磷环状化合物，其中R是氢原子或C1-C6烷基，苯基或苯氧基; 通过使2-（6-氧化-6H-二唑氧化物-6-基）甲醇与式（3）表示的化合物在有机溶剂中在90-120度反应制备，n为1或2。 其中有机溶剂选自苯，甲苯，二甲苯，1,4-二恶烷，二氯甲烷和二氯乙烷。 防火热塑性树脂组合物包含0.1-50重量份由式（1）表示的含磷环状化合物和100重量份热塑性树脂。