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    61.
    发明专利
    未知

    公开(公告)号：DE59103732D1

    公开(公告)日：1995-01-19

    申请号：DE59103732

    申请日：1991-02-09

    Applicant: BASF AG

    Inventor： BOTT KASPAR DR ,  STRAEHLE WOLFGANG DR ,  ABEL ULRICH DR

    IPC: C08G18/48 ,  C08G18/42 ,  C08G18/44 ,  C08G63/64 ,  C08G63/66 ,  C08G64/00 ,  C08G64/02 ,  C08G65/32 ,  C08G69/40 ,  C08G69/44

    Abstract: Polyether polycarbonate diols built up essentially from …… A) from 3 to 63.7 mol% of units derived from a polyoxytetramethylenediol, … B) from 3 to 63.7 mol% of units derived from a polyoxyalkylenediol which is different from A) and contains C2- to C8-alkylene groups, an aliphatic alkanediol having 2 to 14 carbon atoms, an alicyclic alkanediol having 3 to 14 carbon atoms or an alkylene oxide having 2 or 3 carbon atoms, or mixtures thereof, and … C) from 33.3 to 50 mol% of units derived from phosgene, a dialkyl carbonate containing C1- to C4-alkyl groups, or a cyclic carbonate containing C2- to C4-alkylene bridges, or mixtures thereof. …

    62.
    发明专利
    未知

    公开(公告)号：DE59102431D1

    公开(公告)日：1994-09-08

    申请号：DE59102431

    申请日：1991-11-08

    Applicant: BASF AG

    Inventor： BARWICH JUERGEN DR ,  REHMER GERD DR ,  BOTT KASPAR DR

    IPC: C07C231/06 ,  C07C235/20 ,  C07C235/78 ,  C07C235/84 ,  C08F20/60 ,  C08F220/60 ,  C08F246/00 ,  C09J7/02 ,  C09J133/24

    Abstract: Unsaturated phenone derivatives of the general formula I I where R1 is C1-C4-alkyl, cyclopropyl, cyclopentyl, cyclohexyl, indanonyl, tetralonyl, phenyl or phenyl in which some or all of the hydrogen atoms have been replaced by a C1-C4-alkyl, C1-C4-alkoxy or C1-C4-thioalkyl group, or together with R2 or R6 forms an ethylene or propylene bridge, R2 to R6 are each hydrogen, C1-C4-alkyl, C1-C4-alkoxy or C1-C4-thioalkyl, and R3, R4 and R5 may each additionally be hydroxyl, R2 or R6 may additionally together with R1 form an ethylene or propylene bridge and one or more, but not more than three, of the radicals R2 to R6 are a group of the general formula II II or III III where K is C1-C10-alkylene which may contain 1 or 2 oxygen or sulfur atoms, Y is straight-chain or branched C1-C10-alkylene or is C1-C10-alkylene which is substituted by carboxyl, a carboxylate anion, an alkyl C1-C4-carboxylate group or hydroxyl, X is -NH- or -(N-Alkyl)- of 1 to 4 carbon atoms and Z is hydrogen or C1-C4-alkyl.

    63.
    发明专利
    未知

    公开(公告)号：ES2052810T3

    公开(公告)日：1994-07-16

    申请号：ES89109914

    申请日：1989-06-01

    Applicant: BASF AG

    Inventor： BOTT KASPAR DR ,  NICK BERNHARD DR ,  SCHULZ GUNTHER DR

    IPC: C07D231/12 ,  C07D261/08 ,  C08F20/60

    Abstract: The invention relates to novel 4-[(meth)acrylamidomethyl]pyrazoles and isoxazoles of the general formula (I) in which R denotes a hydrogen atom or a methyl group; R denotes a hydrogen atom, a methyl group or an ethyl group; R and R denotes an alkyl group having 1 to 6 C atoms or an unsubstituted or substituted aryl group having 6 to 20 C atoms, where R and R can be identical to or different from one another; X denotes an oxygen atom or an NR group in which R stands for a hydrogen atom or a radical having the meaning of R or R . The invention in addition relates to a process for the preparation of the 4-[(meth)acrylamidomethyl]pyrazoles and -isoxazoles of the general formula (I) and the use of these compounds, in particular for polymerisation and preparation of homo- and copolymers.

    64.
    发明专利
    未知

    公开(公告)号：DE4219385A1

    公开(公告)日：1993-12-16

    申请号：DE4219385

    申请日：1992-06-13

    Applicant: BASF AG

    Inventor： BOTT KASPAR DR ,  GOETZ NORBERT DR ,  BAUER GERHARD DR ,  AYDIN ORAL DR

    IPC: C07C249/12 ,  C07C251/54 ,  C07C259/06 ,  C08F20/34 ,  C08F220/36 ,  C09J133/04 ,  C09J133/14 ,  C08F246/00 ,  C09D133/04

    Abstract: The invention concerns copolymerizable oxime ethers of generale formula (I), in which A is a bivalent link group; R is a hydrogen atom or a C1 to C4 alkyl group; and R and R , independently of each other, may be a hydrogen atom, a C1 to C10 alkyl group, a C1 to C10 alkoxy group, a C5 to C10 cycloalkyl group or a C5 to C10 aryl group which may also contain 1 to 3 non-adjacent nitrogen, oxygen or sulphur hetero-atoms in the carbon chain or in the carbon ring and may be substituted by C1 to C4 alkyl or alkoxy groups, R or R may be a hydrogen atom or R and R together may form a bridge made up of 3 to 14 carbon atoms, in which case some of these carbon atoms may also form part of an aromatic ring.

    66.
    发明专利
    未知

    公开(公告)号：DE3874644D1

    公开(公告)日：1992-10-22

    申请号：DE3874644

    申请日：1988-07-23

    Applicant: BASF AG

    Inventor： BOTT KASPAR DR ,  IRNICH RUDOLF DR

    IPC: C07B61/00 ,  B01J31/14 ,  C07B31/00 ,  C07B41/10 ,  C07C51/00 ,  C07C51/58 ,  C07C53/42 ,  C07C67/00

    Abstract: Prepn. of carboxylic acid chlorides comprises reaction of sec. or tert. halides of non-aromatic hydrocarbons with carbon monoxide at elevated pressure in the presence of catalytic amts. of a Lewis acid. The reaction is carried out in the presence of alkylaluminium halides of formula Rn-Al-X3-n (III), where R is 1-8C alkyl, X is halogen and n is a statistical value from 0.5-2.5. Prepn. of carboxylic acid halides of formula (I') starts from halides of formula (II'), R1 is H, branched or pref. straight alkyl, omega-haloalkyl, pref. omega-chloro or omega-bromoalkyl or cycloalkyl. The carbon number of the alkyl residues is pref. 1-5 and the cycloalkyl residues have pref. 4-7 ring members. R2, R3 are alkyl, omega-haloalkyl and cycloalkyl or can form together a 5-7 membered ring, Y is halogen pref. chlorine. The carbon monoxide pressure is pref. 300-400 bar and the temp. 0-10 deg.C, the optimum depending on the starting material used.

    69.
    发明专利
    未知

    公开(公告)号：DE3867389D1

    公开(公告)日：1992-02-13

    申请号：DE3867389

    申请日：1988-08-26

    Applicant: BASF AG

    Inventor： BRONSTERT KLAUS DR ,  BOHNET SIEGBERT DR ,  HIMMELE WALTER DR ,  BOTT KASPAR DR

    IPC: C07F1/00 ,  C07F1/02 ,  C07F1/04 ,  C08F4/42 ,  C08F4/46 ,  C08F4/48 ,  C08F12/00 ,  C08F12/08 ,  C08F36/00 ,  C08F36/06

    Abstract: Prodn. of bifunctional anionic polymerisation initiators (I) is carried out by dimerising an alkenyl-aromatic cpd. of formula (II: Ar-CH=C(R1)(R2) (II); Ar = an aromatic hydrocarbyl gp., opt. contg. N and opt. substd. by alkyl gps. or other gps. inert towards alkali-organic cpds.; R1 = linear or branched alkyl, cycloalkyl, alkenyl or aralkyl, in which at least the C atom adjacent to the double bond is satd. and aliphatic; R2 = H or as R1; or R1 + R2 = a cycloaliphatic ring; with alkali metals (III) under inert gas atmos. in the presence of ether(s) (IV) and/or tert. amine(s) (V) and opt. inert aliphatic, alicyclic or aromatic solvent (VI) at -20 to +70 deg. C.

    70.
    发明专利
    未知

    公开(公告)号：DE3831681A1

    公开(公告)日：1990-03-22

    申请号：DE3831681

    申请日：1988-09-17

    Applicant: BASF AG

    Inventor： BOTT KASPAR DR

    IPC: C07C67/03 ,  C07C69/675 ,  C08G18/06 ,  C08G18/32 ,  C08L75/04

    Abstract: The invention relates to dihydroxy compounds which are attached to ester groups and have reduced reactivity and the formula I in which R is a linear or branched alkylene radical with 2 to 20 C atoms, an optionally substituted cycloalkylene radical with 5 to 10 carbon atoms, or a polyoxyalkylene radical composed of 2 to 50 oxyalkyl groups which are linked blockwise or in random distribution and have 2 to 4 C atoms in the alkylene radical. The dihydroxy compounds are prepared by transesterification of alkyl hydroxypivalates with alkanediols, cycloalkanediols or polyoxyalkylene glycols and are used in polyurethane chemistry.

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