Aq. alkaline developer soln. for offset printing plate - contg. silane cpd. with carboxylic acid or anhydride or sulphonic or phosphonic acid or acid halide gp. to maximise developer life

    公开(公告)号:DE4211934A1

    公开(公告)日:1993-10-14

    申请号:DE4211934

    申请日:1992-04-09

    Applicant: BASF AG

    Abstract: Aq. developer soln. (I) contg. basic cpd(s)., with pH over 7, for negative or positive working light-sensitive offset printing plates based on light-sensitive diazo cpds. contains 0.1-50 g/l (silane(s) of the formula X-(CH2)y-Si(R1)n(OR2)3-n (II), where R1 and R2 are 1-9C alkyl or 6-12C aryl; X is ZO-CO-CHR3-, R4O-CO-CHR3-, ZO-CO-CH=C(COOR5)-, R4O-CO-CH=C(COOR5)-, a 2,5-dioxo-2,5-dihydro-fur-3-yl gp., (R6O)2P(=O)-, (Hal)2P(=O)-, ZO3S-, HalO2S-, ZO3S-Ar- or HalO2S-Ar- gp.; R3 is H, 1-9C alkyl or 1-9C acyl; or the acyl gp. R3 + the HO-CO-=CH= gp. form a carboxylic anhydride ring; R4 and R5 are 1-9C alkyl or 6-12C aryl; R6 is H, 1-9C alkyl or 6-12C aryl; Z is H or an alkali metal; Ar is 6-12C arylene; Hal is Cl or Br; y is 1-4 and n is 0-1. (II) is dissolved in (I) in hydrolysed form, esp. in salt form. More specficially, X is (R6O)2P(=O)-; R2 and R6 are H, 1-9C alkyl or 6-12C aryl; y = 2; and n = 0. In particular, (II) is the K (2-(trihydroxysilyl)ethyl)phosphoante (IIA). ADVANTAGE - The addn. of (II), esp. phosphonic acid silanes, maximises the life of (I), without impariing the reproduction quality and ensures that the developed printing plates run freely in the printing machines and give large editions.

    4.
    发明专利
    未知

    公开(公告)号:DE58902274D1

    公开(公告)日:1992-10-22

    申请号:DE58902274

    申请日:1989-06-01

    Applicant: BASF AG

    Abstract: The invention relates to novel 4-[(meth)acrylamidomethyl]pyrazoles and isoxazoles of the general formula (I) in which R denotes a hydrogen atom or a methyl group; R denotes a hydrogen atom, a methyl group or an ethyl group; R and R denotes an alkyl group having 1 to 6 C atoms or an unsubstituted or substituted aryl group having 6 to 20 C atoms, where R and R can be identical to or different from one another; X denotes an oxygen atom or an NR group in which R stands for a hydrogen atom or a radical having the meaning of R or R . The invention in addition relates to a process for the preparation of the 4-[(meth)acrylamidomethyl]pyrazoles and -isoxazoles of the general formula (I) and the use of these compounds, in particular for polymerisation and preparation of homo- and copolymers.

    5.
    发明专利
    未知

    公开(公告)号:DE3627758A1

    公开(公告)日:1988-02-18

    申请号:DE3627758

    申请日:1986-08-16

    Applicant: BASF AG

    Abstract: An electrophotographic recording element consisting of an aluminum base, which is mechanically, chemically and/or electrochemically pretreated in a conventional manner, and a photoconductive layer which is applied to this base is produced by a process in which a thin layer which imparts hydrophilic properties and consists of a hydrolysis product or condensate of a silane is applied between the base and the photoconductive layer. These recording elements are particularly useful for electrophotographic offset printing.

    6.
    发明专利
    未知

    公开(公告)号:DE3787426D1

    公开(公告)日:1993-10-21

    申请号:DE3787426

    申请日:1987-06-24

    Applicant: BASF AG

    Abstract: The process produces a sensitized lithographic printing plate from an aluminium base which has been pretreated mechanically, chemically and/or electrochemically in the standard way and anodised, and a photosensitive copying layer applied to said base, a thin hydrophilising layer consisting of a hydrolysate or condensate of at least one silane being applied between said base and copying layer. … These lithographic printing plates are suitable, in particular, for offset printing.

    9.
    发明专利
    未知

    公开(公告)号:DE3740698A1

    公开(公告)日:1989-06-15

    申请号:DE3740698

    申请日:1987-12-01

    Applicant: BASF AG

    Abstract: Process for anodising the surface of plates, foils or strips made of aluminium or aluminium alloys in an aqueous electrolyte which contains one or more acids and also, optionally, one or more additives and which contains, as additive or as one of the additives or as acid or as one of the acids, a silane or a plurality of silanes of the general formula I where the indices and the variables have the following meaning: y is an integer from 1 to 4; n is 0, 1 and 2 independently of y; R and R are C1-C9-alkyl and C6-C12-aryl, R and R being identical to, or different from, each other; and X is the radicals X to X , where the variables have the following meaning: R is a hydrogen atom, C1-C9-alkyl, an alkane-carboxylic anhydride ring formed from the alkanecarboxylic acid radical containing 1 to 9 carbons atoms and a carboxylic acid group linked to R3 R and R are the radical R ; R is a hydrogen atom and the radical R ; Z is a hydrogen atom and an alkali metal cation; Ar is C6-C12-arylene; and Hal is a chlorine and bromime atom; the silanes of the general formula I (= silanes I) being dissolved in the electrolyte solution in hydrolysed and/or condensed form. Also the use of the plates, foils or strips made of aluminium or aluminium alloy anodised by this process for producing bases for photosensitive lithographic printing plates or offset printing plates.

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