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公开(公告)号:DE4315880A1
公开(公告)日:1994-11-17
申请号:DE4315880
申请日:1993-05-12
Applicant: BASF AG
Inventor: BARWICH JUERGEN DR , PLAUMANN HEINZ DR , WISTUBA ECKEHARDT DR
IPC: C08L31/02 , C08F218/04 , C08F220/12 , C08L31/04 , C08L33/04 , C08L33/06 , C08L43/00 , C08L43/04 , C09D133/04 , C09D133/06 , C09D137/00 , C09D143/04 , C09J131/00 , C09J131/02 , C09J133/04 , C09J133/06 , C09J137/00 , C09J143/04 , C09K3/10 , C08J3/24 , C08K5/57 , C09D131/02
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公开(公告)号:DE59102431D1
公开(公告)日:1994-09-08
申请号:DE59102431
申请日:1991-11-08
Applicant: BASF AG
Inventor: BARWICH JUERGEN DR , REHMER GERD DR , BOTT KASPAR DR
IPC: C07C231/06 , C07C235/20 , C07C235/78 , C07C235/84 , C08F20/60 , C08F220/60 , C08F246/00 , C09J7/02 , C09J133/24
Abstract: Unsaturated phenone derivatives of the general formula I I where R1 is C1-C4-alkyl, cyclopropyl, cyclopentyl, cyclohexyl, indanonyl, tetralonyl, phenyl or phenyl in which some or all of the hydrogen atoms have been replaced by a C1-C4-alkyl, C1-C4-alkoxy or C1-C4-thioalkyl group, or together with R2 or R6 forms an ethylene or propylene bridge, R2 to R6 are each hydrogen, C1-C4-alkyl, C1-C4-alkoxy or C1-C4-thioalkyl, and R3, R4 and R5 may each additionally be hydroxyl, R2 or R6 may additionally together with R1 form an ethylene or propylene bridge and one or more, but not more than three, of the radicals R2 to R6 are a group of the general formula II II or III III where K is C1-C10-alkylene which may contain 1 or 2 oxygen or sulfur atoms, Y is straight-chain or branched C1-C10-alkylene or is C1-C10-alkylene which is substituted by carboxyl, a carboxylate anion, an alkyl C1-C4-carboxylate group or hydroxyl, X is -NH- or -(N-Alkyl)- of 1 to 4 carbon atoms and Z is hydrogen or C1-C4-alkyl.
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公开(公告)号:DE19709723A1
公开(公告)日:1998-09-17
申请号:DE19709723
申请日:1997-03-10
Applicant: BASF AG
Inventor: KROBB JOACHIM , FICKEISEN PETER , DAEUMER BERND DR , BARWICH JUERGEN DR , WISTUBA ECKEHARDT DR
IPC: E04F15/12 , C08L33/06 , C09J133/06 , C09J133/08 , C09J133/14 , E04B1/62 , E04B1/66 , E04F15/08
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公开(公告)号:ES2108327T3
公开(公告)日:1997-12-16
申请号:ES94106961
申请日:1994-05-04
Applicant: BASF AG
Inventor: BARWICH JUERGEN DR , PLAUMANN HEINZ DR , WISTUBA ECKEHARDT DR
IPC: C08L31/02 , C08F218/04 , C08F220/12 , C08L31/04 , C08L33/04 , C08L33/06 , C08L43/00 , C08L43/04 , C09D133/04 , C09D133/06 , C09D137/00 , C09D143/04 , C09J131/00 , C09J131/02 , C09J133/04 , C09J133/06 , C09J137/00 , C09J143/04 , C09K3/10
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公开(公告)号:DE19540997A1
公开(公告)日:1997-05-07
申请号:DE19540997
申请日:1995-11-03
Applicant: BASF AG
Inventor: WILDBURG GERALD DR , BARWICH JUERGEN DR , WUESTEFELD RENATE DR , FRICKE HANS-JOACHIM , REHMER GERD DR
IPC: C08F2/22 , C08F2/44 , C08G18/62 , C08G18/63 , C09J175/00 , B32B7/12 , C08F251/00 , C09J11/08
Abstract: Described are dispersions of radical-polymerized polymers, the dispersions containing a polyisocyanate as the crosslinking agent. The dispersions are characterized in that the polymer is obtained by the emulsion polymerization of ethylenically unsaturated monomers in the presence of a protective colloid containing hydroxyl groups.
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公开(公告)号:DE59107998D1
公开(公告)日:1996-08-14
申请号:DE59107998
申请日:1991-11-23
Applicant: BASF AG
Inventor: FILGES ULRICH DR , AYDIN ORAL DR , AUCHTER GERHARD DR , BARWICH JUERGEN DR , ANDERS HERMANN DR , LANGER WERNER DR , VORSPOHL KLAUS DR
IPC: C08L33/00 , C08F2/38 , C08F8/00 , C08F8/30 , C08F8/46 , C08F218/04 , C08F220/12 , C08F220/18 , C08G18/30 , C08G18/32 , C08G18/62 , C08G18/72 , C08K5/54 , C08L31/02 , C08L33/04 , C08L33/06 , C08L75/00 , C08L75/04 , C09D131/02 , C09D133/06 , C09D175/00 , C09J131/02 , C09J133/06 , C09J175/00 , C09K3/10
Abstract: Copolymers based on acrylic, methacrylic and/or vinyl esters which are self-curable in the presence of atmospheric moisture and have been prepared using silicon-containing regulators, and mixtures of such polymers with crosslinking components. The products are suitable as adhesives, sealants and coating materials which are self-curable in the presence of atmospheric moisture.
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公开(公告)号:DE59108983D1
公开(公告)日:1998-06-18
申请号:DE59108983
申请日:1991-06-15
Applicant: BASF AG
Inventor: REHMER GERD DR , BARWICH JUERGEN DR , AUCHTER GERHARD DR
IPC: C08F2/00 , C08F2/04 , C08F2/06 , C08F220/10 , C08F220/18 , C08L33/04 , C08L33/08 , C09J133/04 , C09J133/08
Abstract: Polymers of olefinically unsaturated monomers and solutions of polymers of olefinically unsaturated monomers obtainable by polymerising the olefinically unsaturated monomers in the presence of free radical-forming initiators in solution under otherwise prespecified polymerisation conditions in a process in which a solvent and/or a liquid part of one or more reaction components of the polymerisation batch is initially introduced and heated to the polymerisation temperature, and, while maintaining or initiating the polymerisation, some or all of the monomers to be polymerised are fed continuously, via at least one feed, to the initially introduced part of the polymerisation batch (which is kept in motion), in such a manner that the exit opening of the at least one feed is above the surface of the initially introduced liquid part of the polymerisation batch.
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公开(公告)号:DE59404386D1
公开(公告)日:1997-11-27
申请号:DE59404386
申请日:1994-05-04
Applicant: BASF AG
Inventor: BARWICH JUERGEN DR , PLAUMANN HEINZ DR , WISTUBA ECKEHARDT DR
IPC: C08L31/02 , C08F218/04 , C08F220/12 , C08L31/04 , C08L33/04 , C08L33/06 , C08L43/00 , C08L43/04 , C09D133/04 , C09D133/06 , C09D137/00 , C09D143/04 , C09J131/00 , C09J131/02 , C09J133/04 , C09J133/06 , C09J137/00 , C09J143/04 , C09K3/10
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公开(公告)号:DE4442684A1
公开(公告)日:1996-06-05
申请号:DE4442684
申请日:1994-11-30
Applicant: BASF AG
Inventor: REHMER GERD DR , AUCHTER GERHARD DR , JAEGER HELMUT , BARWICH JUERGEN DR
IPC: C09D133/06 , C09J133/06 , C08L33/06 , C08F218/04 , C08F220/18 , C08L31/02 , C09D4/00 , C09D131/02 , C09J11/06 , C09J131/02
Abstract: A material for adhesion to solid surfaces contains (A) copolymer(s) of (a) 65-99.9 wt.% cpds. of formula CH2=CR -CO-OR (I). R = H or 1-4C alkyl; R = 1-18C alkyl; and/or vinyl esters of formula R -CO-O-CH=CH2 (II). R = 1-12C alkyl; (b) 0-6 wt.% alpha,beta-unsatd. 3-8C mono- and/or dicarboxylic acids and/or anhydrides of 3-8C diacids, (c) 0.1-4 wt.% (meth)acrylamido-glycolic acid and (d) 0-34.9 wt.% other unsatd. comonomers, pref. with 2-10 C atoms; (B) 0.05-5 wt.% (w.r.t. A) of a metal chelate, pref. a Zr chelate, and/or an opt. polymerised metal acid ester of formula RnT(OR )z (III) or (IV): T = di- to tetra-valent metal atom, pref. a Gp. II, III, IV or V metal, esp. pref. Ti; R = 1-8C alkyl or 6-16C aryl; R , R = 1-4C alkoxy or 1-18C aliphatic residue; R = as for R /R , or 1-4C alkylamino; n = 0 or a whole no.; z = at least 1, pref. at least 2; n + z = valency of T; (C) 10-900 wt.% (w.r.t. A) organic solvent or a mixt. thereof with water; and (D) opt. fillers, tackifying resins and/or stabilisers.
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公开(公告)号:DE19528369A1
公开(公告)日:1996-02-15
申请号:DE19528369
申请日:1995-08-02
Applicant: BASF AG
Inventor: BARWICH JUERGEN DR , DITTRICH UWE DR , ROESCH JOACHIM DR , MUELLER HANS-JOACHIM DR , SEELERT STEFAN DR , MEYER-ROSCHER BERND DR
IPC: C08F290/04 , C09J123/14 , C09J133/06 , C09J153/00 , C08F293/00 , C08F299/00 , C09J5/06 , C09J157/04
Abstract: Polymer-based adhesives are claimed, contg. 0.2-80 wt%(w.r.t. polymer) of oligopropene derivs. of formula (I), (II) or (III) (where n = 0-100; X = a gp.) with a mol. wt. of less than 300 contg. at least one copolymerisable olefinic double bond or a reactive H atom. Also claimed are substrates coated with these adhesives. Pref. the polymer has a Tg of -50 to+40 deg C and contains 1-65 wt% (I-III). Pref. polymer is obtd. by polymerisation of (a) 20-99.8 wt% 1-10C alkyl (meth)acrylate, vinyl 1-20C carboxylate, up to 20C vinylaromatic, unsatd. nitrile, vinyl halide, 1-10C alkyl vinyl ether and/or 2-8C aliphatic mono- or di-olefin as main monomer, (b) 0.2-80 wt% (I), (III) or unsatd. oligomer (II) and (c) 0-50 wt% other comonomers; or a mixt. of 50-99.8 wt% (a) and 0.2-50 wt% (c) is polymerised first and then reacted with oligomer (II) contg. a reactive H atom.
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