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公开(公告)号:CA1226574A
公开(公告)日:1987-09-08
申请号:CA474432
申请日:1985-02-15
Applicant: BASF AG
Inventor: WERNER FRANK , MARX MATTHIAS , SCHMIDT HANS U
IPC: B29C33/60 , B29C67/24 , C08G18/38 , C08G18/66 , C08K5/09 , C08K5/16 , C08K5/20 , C07C93/193 , C08G18/50
Abstract: INTERNAL RELEASE AGENTS FOR POLYISOCYANATE ADDITION POLYMERIZATION, THEIR USE IN THE PREPARATION OF CELLULAR, MICROCELLULAR, AND NONCELLULAR POLYURETHANEPOLYUREA MOLDED PARTS HAVING IMPROVED DEMOLDING PROPERTIES The invention relates to a process for the preparation of cellular, microcellular, and noncelluar polyurethane polyurea molded parts with improved demolding characteristics through the reaction injection molding technique wherein unique internal mold release agents are used which are esters and/or amides prepared by reacting a mixture of montanic acid and a carboxylic acid having ten or more carbon atoms with a polyol, alkanolamine, or polyamine.
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公开(公告)号:CA1221216A
公开(公告)日:1987-05-05
申请号:CA458663
申请日:1984-07-11
Applicant: BASF AG
Inventor: HORN PETER , MARX MATTHIAS , WELZ MARTIN , BAUMANN EDWIN
Abstract: Sheet-like moldings of fiber-reinforced nylon are produced by activated alkaline polymerization of a lactam melt in a mold which contains a textile fiber structure, preferably a glass mat. In this process, the lactam melt is forced, in the course of from 2 to 50 sec, into a mold heated at from 120 to 180.degree.C and is polymerized in the course of less than 3 min to give a nylon having a K value greater than 100. The moldings can be used for the production of automotive and aircraft components.
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公开(公告)号:CA1221181A
公开(公告)日:1987-04-28
申请号:CA468424
申请日:1984-11-22
Applicant: BASF AG
Inventor: HORN PETER , HESSE ANTON , MANN WALTER , FRANK WOLFRAM , MARX MATTHIAS , HECKMANN WALTER
Abstract: CRYSTALLITE SUSPENSIONS OF CRYSTALLINE, ETHYLENICALLY UNSATURATED POLYESTERS AND POLYHYDROXYL COMPOUNDS; PROCESS FOR THEIR PREPARATION AND THEIR USE FOR THE PREPARATION OF POLYURETHANE- OR POLYURETHANE GROUP-CONTAINING POLYISOCYANURATE POLYMERS Crystallite suspensions containing from 3 to 70 weight percent of a crystalline, ethylenically unsaturated polyester prepared through condensation polymerization, and having a molecular weight factor per double bond of 154.4 to 408, as the dispersed phase, and from 30 to 97 weight percent of a polyhydroxyl compound having a functionality of from 2 to about 8, a hydroxyl number of from 20 to 800, and a melting point of less than 30.degree.C as the coherent phase are suitable for preparing non-cellular and cellular polyurethane- or polyurethane group-containing polyisocyanurate foams.
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公开(公告)号:CA1219987A
公开(公告)日:1987-03-31
申请号:CA452232
申请日:1984-04-17
Applicant: BASF AG
Inventor: STRAEHLE WOLFGANG , BUETHE INGOLF , MARX MATTHIAS
Abstract: PROCESS FOR THE PREPARATION OF CELLULAR OR NON-CELLULAR POLYURETHANES The invention relates to a process for the preparation of cellular or non-cellular polyurethanes through the reaction of organic polyisocyanates with a polyether-polyester polyol component containing di- to tetrafunctional polyether-polyester polyols having hydroxyl numbers of from 10 to 200, which are themselves prepared by esterifying conventional di- to tetrafunctional polyether polyols with carboxylic acid anhydrides, preferably aromatic carboxylic acid anhydrides, in the presence of selected catalysts to form carboxylic acid half esters, and oxyalkylating the resulting carboxylic acid half esters with alkylene oxides in the presence of N-methylimidazole, triethylene diamine, triphenylphosphine or mixtures thereof with thiodlalkylene glycol as catalysts.
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公开(公告)号:CA1197264A
公开(公告)日:1985-11-26
申请号:CA433423
申请日:1983-07-28
Applicant: BASF AG
Inventor: STRAEHLE WOLFGANG , DENNI RAYMOND , MARX MATTHIAS
Abstract: PROCESS FOR PURIFICATION OF CRUDE POLYETHER POLYOLS A process for purifying crude polyether polyols which are prepared by anionic polymerization of alkylene oxides in the presence of basic catalysts. The polyols are mixed with water and ortho-phosphoric acid in certain quantity ratios, an adsorption agent is incorporated in the reaction mixture, the mixture is filtered and the water is removed from the polyether polyol by distillation.
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公开(公告)号:CA1192698A
公开(公告)日:1985-08-27
申请号:CA406503
申请日:1982-07-02
Applicant: BASF AG
Inventor: NISSEN DIETMAR , STRAEHLE WOLFGANG , MARX MATTHIAS
Abstract: For the preparation of optionally cellular and non-cellular polyurethane elastomers, preferably by reaction injection molding, organic polyisocyanates, polyether polyols based on polyoxyalkylene polyether polyols with terminal hydroxyethylene groups and an ethoxylation degree of 1 to 13, having a content of primary hydroxyl groups at the corresponding degree of ethoxylation as the value of curve A to 100 percent with curve A describing the dependency of the primary hydroxyl group content upon the degree of ethoxylation are reacted with chain extenders and/or cross-linking agents in the presence of catalysts as well as optionally blowing agents, auxiliaries and additives.
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公开(公告)号:CA994618A
公开(公告)日:1976-08-10
申请号:CA170443
申请日:1973-05-04
Applicant: BASF AG
Inventor: EISELE WOLFGANG , HANN ERNST W , HENKEL HELMUT , MARX MATTHIAS
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公开(公告)号:CA888772A
公开(公告)日:1971-12-21
申请号:CA888772D
Applicant: BASF AG
Inventor: MARX MATTHIAS , SPOOR HERBERT , SANDER HANS
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公开(公告)号:CA881579A
公开(公告)日:1971-09-21
申请号:CA881579D
Applicant: BASF AG
Inventor: BACHMANN GERHARD , MARX MATTHIAS
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公开(公告)号:GB1146858A
公开(公告)日:1969-03-26
申请号:GB3071166
申请日:1966-07-08
Applicant: BASF AG
Inventor: FLORUS GERHARD , MARX MATTHIAS , HARTMANN JOB-WERNER , WILHELM HANS
IPC: C09D5/44 , C09D133/06
Abstract: 1,146,858. Electrochemical coating compositions. BADISCHE ANILIN & SODAFABRIK A.G. 8 July, 1966 [9 July, 1965], No. 30711/66. Headings C3P and C3R. [Also in Division C7] An example illustrates compositions which are suitable for electrodeposition coating and which comprise a butanol solution of (a) a copolymer of 2-ethyl hexyl acrylate, acrylic acid, N - butoxymethylacrylamide, 4 - hydroxybutyl acrylate and styrene, the acid groups being neutralized with N,N-dimethyl-N-(#-hydroxyethyl)-amine and (b) N,N 1 ,N 11 ,N 111 -tetramethyl olglyoxal diureine, the compositions additionally containing titanium dioxide pigment and being diluted with water. Coatings of the compositions are stoved at 150‹ C.
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