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    PRODUCTION OF DENSE AND TRANSPARENT POLYISOCYANATE POLYADDITION PRODUCT
    1.
    发明专利
    PRODUCTION OF DENSE AND TRANSPARENT POLYISOCYANATE POLYADDITION PRODUCT 失效

    公开(公告)号：JP2000143763A

    公开(公告)日：2000-05-26

    申请号：JP25342699

    申请日：1999-08-04

    Applicant: BASF AG

    Inventor： MALETZKO CHRISTIAN DR ,  BAUMANN EDWIN

    IPC: C08J5/00 ,  C08G18/08 ,  C08G18/10 ,  C08G18/42 ,  C08G18/48 ,  C08G18/72 ,  C08G18/75

    Abstract: PROBLEM TO BE SOLVED: To produce the subject product having a high hardness and a low coefficient of thermal expansion, further having an extremely smooth surface, useful as a glass substitute for a car by reacting an isocyanate with a specific compound under a specified condition. SOLUTION: When (A) an isocyanate and (B) a compound reactive with the component A are reacted in the presence or absence of (C) a catalyst, (D) an adjuvant and/or (E) an additive, the reaction of the component A with the component B is carried out under the pressure of 1-20 MPa in a mold. Preferably, the reaction is carried out at 20-220 deg.C mold temperature. Especially, it is preferable that the reaction of the components A with B is carried out in the mold having 20-140 deg.C mold temperature for 0.5-15 min, and, thereafter, the partially reacted product is compressed in the same or another mold having 100-220 deg.C mold temperature under 1-20 MPa pressure.

    BIOLOGICALLY DEGRADABLE POLYMERS, PROCESSES FOR MANUFACTURING THE SAME AND THE USE THEREOF FOR PRODUCING BIODEGRADABLE MOULDED ARTICLES
    3.
    发明申请
    BIOLOGICALLY DEGRADABLE POLYMERS, PROCESSES FOR MANUFACTURING THE SAME AND THE USE THEREOF FOR PRODUCING BIODEGRADABLE MOULDED ARTICLES 审中-公开
    生物降解聚合物，方法的生产和使用，其用于制造生物可降解成型

    公开(公告)号：WO9621689A2

    公开(公告)日：1996-07-18

    申请号：PCT/EP9502493

    申请日：1995-06-27

    Applicant: BASF AG ,  WARZELHAN VOLKER ,  SCHORNICK GUNNAR ,  BAUMANN EDWIN ,  SEELIGER URSULA ,  YAMAMOTO MOTONORI ,  RAMLOW GERHARD

    Inventor： WARZELHAN VOLKER ,  SCHORNICK GUNNAR ,  BAUMANN EDWIN ,  SEELIGER URSULA ,  YAMAMOTO MOTONORI ,  RAMLOW GERHARD

    IPC: C08G18/60 ,  C08G69/44 ,  C08G73/04 ,  C08J9/04 ,  C08L1/02 ,  C08L77/12 ,  C08L101/16 ,  C09D175/12 ,  C09J177/12 ,  D21H19/30

    CPC classification number: C08G69/44 ,  C08G18/606 ,  Y02W30/43

    Abstract: The invention concerns biologically degradable polyester amides P1 obtainable through reaction of a mixture consisting essentially of the following: (a1) a mixture consisting essentially of: 35-95 mol % adipic acid or ester-forming derivatives thereof or mixtures thereof, 5-65 mol % terephthalic acid or ester-forming derivatives thereof or mixtures thereof, and 0-5 mol % a compound containing sulphonate groups (the sum of the individual molar percentages is 100); (a2) a mixture consisting essentially of: (a21) 99.5-0.5 mol % a dihydroxy compound chosen from the group comprising C2-C6 alkane diols and C5-C10 cycloalkane diols, (a22) 0.5-99.5 mol % an amino C2-C12 alkanol or an amino-C5-C10 cycloalkanol, (a23) 0-50 mol % a diamino C1-C8 alkane; and (a24) 0-50 mol % a 2,2`-bisoxazoline of general formula (I), in which R is a single bond, a (CH2)q-alkylene group in which q = 2, 3 or 4, or a phenylene group (the sum of the individual molar percentages is 100 and the molar ratio of a1 to a2 is in the range 0.4:1 - 1.5:1). The polyester amides P1 will have a molecular weight (Mn) in the range 4000-40,000 g/mol, a viscosity number in the range 30-350 g/ml (measured in o-dichlorobenzene/phenol (weight ratio 50/50) at a concentration of 0.5 wt.% polyester amide P1 at a temperature of 25 DEG C) and a melting point in the range 50-220 DEG C; and a quantity of a compound D equivalent to 0-5 mol % of the molar quantity of components (a1) must also be used for the production of the polyester amides P1, said compound D having at least three groups capable of ester formation. The invention also concerns other biologically degradable polymers and thermoplastic moulding materials, processes for manufacturing the same, the use thereof for producing biologically degradable moulded articles and adhesives, and biologically degradable moulded articles, foams and blends with starch which can be obtained from the polymers or moulding materials according to the invention.

    Abstract translation: 可生物降解的聚酯酰胺通过基本上由混合物反应P1获得（a1）的基本上35由〜95摩尔％的己二酸或它们的酯形成性衍生物或者它们的混合物，5〜65摩尔％的对苯二甲酸或其酯形成性衍生物的混合物 或其混合物，和0〜5摩尔％磺酸酯化合物的，单独的摩尔百分比的总和为100摩尔％，和（a2）从99.5基本上由（A21）〜0.5摩尔的混合物 - （A22）0.5选自C2-C6烷二醇和C5-C10-环烷二醇的组中选择的二羟基化合物，的％至99.5摩尔％的氨基C2-C12链烷醇或氨基-C5的 C10-环烷醇，以及（A23）0〜50摩尔％的二氨基C1-C8烷烃，（A24）0〜50摩尔％通式（I）的2,2'-二恶唑啉，其中R <1 >一个单键，（CH 2）●亚烷基其中q = 2，3或4，或亚苯基，其中装置 各个摩尔百分比的总和为100摩尔％，并且其中的（a1）至（A2）的范围为0.4的摩尔比：1至1.5：1种选择，条件是该聚酯酰胺P1的分子量 （Mn）的范围为4000至40,000克/摩尔，在30至350范围内的粘度数克/毫升（在以0.5重量％的浓度的邻二氯苯/苯酚（50/50重量比）进行测定。 - ％聚酯酰胺P1在25℃的温度），并在50至220℃的范围内的熔点，并与一个从0〜5摩尔％基于组分的摩尔量进一步的条件（A1 ），与能够对聚酯酰胺的制备酯的形成至少三个基团的化合物D P1中使用的以及其它可生物降解的聚合物和热塑性模塑组合物，涉及它们的制备方法，它们用于制备可生物降解的模制品和粘合剂，生物可降解的成型品使用， 泡沫和从本发明的聚合物或模塑组合物获得的淀粉混合物。

    7.
    发明专利
    未知

    公开(公告)号：AT184032T

    公开(公告)日：1999-09-15

    申请号：AT96941636

    申请日：1996-12-02

    Applicant: BASF AG

    Inventor： HORN PETER ,  HESSE ANTON ,  RATH HANS PETER ,  GREIF NORBERT ,  PARTUSCH GEORG ,  BAUMANN EDWIN ,  LARBIG HARALD ,  HECKMANN WALTER ,  BECKER JOHANNES

    IPC: C08J5/04 ,  C08G18/06 ,  C08G18/28 ,  C08G18/66 ,  C08G101/00 ,  C08J5/24 ,  C08J9/00 ,  C08J9/04 ,  C08K5/3415 ,  C08L75/04

    Abstract: The invention relates to a process for preparing self-releasing, compact or cellular moulded bodies optionally containing reinforcing agents and made of polyisocyanate polyaddition products by reacting a) organic and/or modified organic polyisocyanates with b) at least one compound with at least two reactive hydrogen atoms and a molecular weight of 500 to 9,000 and optionally c) chain extension and/or cross-linking agents in the presence of d) alkyl and/or alkenyl succinic acid monoamides, -monoamides, poly(alkyl succinic acid)- and/or poly(alkenyl succinic acid)-polyamides, -polyimides, -monoamide monoimides, -polyamide imides, -amide polyimides and- polyamide polyimides or mixtures thereof as internal mould release agents, and also in the presence or absence of e) catalysts, f) blowing agents, g) reinforcing agents, h) auxiliary agents, in an open or closed moulding tool, optionally under compression. The invention also relates to the use of alkyl- and/or alkenyl succinic acid amides and/or imides (d) as internal mould release agents for the preparation of moulded bodies made of polyisocyanate polyaddition products.

    9.
    发明专利
    未知

    公开(公告)号：DE59503552D1

    公开(公告)日：1998-10-15

    申请号：DE59503552

    申请日：1995-06-27

    Applicant: BASF AG

    Inventor： WARZELHAN VOLKER ,  SCHORNICK GUNNAR ,  BAUMANN EDWIN ,  SEELIGER URSULA ,  YAMAMOTO MOTONORI ,  RAMLOW GERHARD

    IPC: C08G18/60 ,  C08G69/44 ,  C08G73/04 ,  C08J9/04 ,  C08L1/02 ,  C08L77/12 ,  C08L101/16 ,  C09D175/12 ,  C09J177/12 ,  D21H19/30

    Abstract: Biodegradable polyesteramides as defined in the specification are obtained by reacting a mixture consisting essentially ofa1) a mixture consisting essentially of35 to 95 mol % of adipic acid or ester-forming derivatives thereof,5 to 65 mol % of terephthalic acid or ester-forming derivatives thereof, and0 to 5 mol % of a compound containing sulfonate groups,a2) a mixture consisting essentially of95.5 to 0.5 mol % of a dihydroxy compound,0.5 to 99.5 mol % of an amino-C2-C12-alkanol or an amino-C5-C10-cycloalkanol,0 to 50 mol % of a diamino-C1-C8-alkane, and0 to 50 mol % of a 2,2'-bisoxazoline of the formula I wherein R1 is as set forth in the specification, anda3) 0 to 5 mol %, based on a1), of a compound D as set forth in the specification;and other biodegradable polymers and thermoplastic molding compositions, their manufacture and their use for producing biodegradable moldings, adhesives, foams, and coatings.

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