公开(公告)号：ZA200205591B

公开(公告)日：2003-10-03

申请号：ZA200205591

申请日：2002-07-12

Applicant: BASF AG

Inventor： BASSLER PETER ,  HEFNER WERNER ,  REHFINGER ALWIN ,  RIEBER NORBERT ,  RUDOLF PETER ,  TELES JOAQUIM HENRIQUE ,  WENZEL ANNE

IPC: B01D3/00 ,  C07B61/00 ,  C07C5/42 ,  C07C11/06 ,  C07D301/12 ,  C07D301/32 ,  C07D303/04 ,  C07D

Abstract: A mixture (M1) comprising an alkene and oxygen is worked up by a process in which (i) oxygen is removed from the mixture (M1) by a nondistillative method to give a mixture (M2) and (ii) the alkene is separated off from the mixture (M2) by distillation.

公开(公告)号：DE59906684D1

公开(公告)日：2003-09-25

申请号：DE59906684

申请日：1999-02-23

Applicant: BASF AG

Inventor： VOIT GUIDO ,  FISCHER ROLF ,  BASSLER PETER ,  ANSMANN ANDREAS ,  LUYKEN HERMANN ,  MERGER MARTIN ,  OHLBACH FRANK ,  REHFINGER ALWIN

IPC: B01J23/78 ,  B01J23/889 ,  C07B61/00 ,  C07C209/48 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24

Abstract: A material useful as catalyst for the hydrogenation of alpha, omega-dinitriles comprises (a) iron or a compound based on iron or mixtures thereof, (b) from 0.001 to 0.3% by weight based on (a) of a promoter based on 2, 3, 4 or 5 elements selected from the group consisting of aluminum, silicon, zirconium, titanium and vanadium, (c) from 0 to 0.3% by weight based on (a) of a compound based on an alkali and/or alkaline earth metal, and also (d) from 0.001 to 1% by weight based on (a) of manganese.

公开(公告)号：BR0113770A

公开(公告)日：2003-07-29

申请号：BR0113770

申请日：2001-09-11

Applicant: BASF AG

Inventor： MUELLER ULRICH ,  TELES JOAQUIM HENRIQUE ,  WENZEL ANNE ,  HARDER WOLFGANG ,  RUDOLF PETER ,  REHFINGER ALWIN ,  BASSLER PETER ,  RIEBER NORBERT

IPC: B01J29/89 ,  B01J29/90 ,  C07D301/12

Abstract: A process for regenerating a zeolite catalyst comprises thermal treatment of the catalyst at above 120° C. in the presence of a gas stream comprising hydrogen.

公开(公告)号：CA2421866A1

公开(公告)日：2003-03-10

申请号：CA2421866

申请日：2001-09-06

Applicant: BASF AG

Inventor： BASSLER PETER ,  MULLER ULRICH ,  REHFINGER ALWIN ,  RIEBER NORBERT ,  TELES JOAQUIM HENRIQUE ,  HARDER WOLFGANG ,  RUDOLF PETER ,  WENZEL ANNE

IPC: B01J29/89 ,  B01J29/90 ,  B01J38/62 ,  C07D301/12

Abstract: The invention relates to a method for producing an epoxide in the presence o f a zeolite catalyst, whereby (i) an alkene is reacted with a hydroperoxide in the presence of the catalyst in order to obtain the epoxide, and at least on e alkali metal salt is supplied to the reaction in at least one educt flow. Th e inventive method is characterised in that (ii) the supply of the at least on e alkali metal salt is cut off during the reaction, and the supply of hydroperoxide and alkene is continued.

公开(公告)号：DE10135296A1

公开(公告)日：2003-01-30

申请号：DE10135296

申请日：2001-07-19

Applicant: BASF AG

Inventor： TELES JOAQUIM HENRIQUE ,  REHFINGER ALWIN ,  WENZEL ANNE ,  RUDOLF PETER ,  RIEBER NORBERT ,  BASLER PETER

IPC: C07D301/12 ,  C07D301/19

Abstract: The invention relates to a method for producing propylene oxide, comprising at least the following steps: (a) propene is reacted with a hydroperoxide in a solvent in the presence of a zeolite catalyst, in order to obtain a mixture (G0), said mixture (G0) containing propylene oxide, solvent, non-reacted propene, non-reacted hydroperoxide and oxygen; (b) the propylene oxide is separated from the mixture (G0) in such a way that a mixture (G1) is obtained which comprises non-reacted propene and oxygen; (c) the mixture (G1) is brought into contact with a liquid medium containing at least solvent, in order to obtain the mixtures (G2) and (G3), said mixture (G3) containing a part of the non-reacted propene and oxygen, and said mixture (G2) containing the solvent and the rest of the propene, the separated mixture (G3) of non-reacted propene and oxygen having a ratio of oxygen to propene which renders the mixture (G3) non-inflammable, and the mixture (G2) supplying at least one reaction between the propene and the hydroperoxide.

公开(公告)号：ES2169418T3

公开(公告)日：2002-07-01

申请号：ES97940102

申请日：1997-08-21

Applicant: BASF AG

Inventor： LUYKEN HERMANN ,  VOIT GUIDO ,  BASSLER PETER ,  REHFINGER ALWIN ,  FISCHER ROLF

IPC: B01J27/187 ,  C07B61/00 ,  C07C209/48 ,  C07C209/84 ,  C07C211/12 ,  C07C253/30 ,  C07C253/34 ,  C07C255/24

Abstract: A process for coproduction of 6-aminocapronitrile and hexamethylenediamine starting from adiponitrile comprises(1) partially hydrogenating adiponitrile in the presence of a catalyst to obtain a mixture comprising 6-aminocapronitrile, hexamethylenediamine and adiponitrile,(2) removing 6-aminocapronitrile and hexamethylenediamine from the mixture,(3) adding to the portion comprising essentially adiponitrile from 0.01 to 10% by weight of an acid, based on adiponitrile, or an acidic ion exchanger and removing the adiponitrile from the mixture, and(4) recycling the adiponitrile into step (1).

公开(公告)号：DE59802794D1

公开(公告)日：2002-02-28

申请号：DE59802794

申请日：1998-01-30

Applicant: BASF AG

Inventor： LUYKEN HERMANN ,  BASSLER PETER ,  REHFINGER ALWIN

IPC: C07C209/82 ,  C07C209/86 ,  C07C211/09 ,  C07C211/12 ,  C07C249/02 ,  C07C251/08 ,  C07C251/12 ,  C07C253/34 ,  C07C255/04 ,  C07C255/24 ,  C07D223/04

Abstract: A process for distillative separation of part or all of an imine (III) from a mixture (II) comprising an amine (I) and said imine (III) comprises adding to the distillation mixture a compound (IV) which is inert toward said amine (I) under distillation conditions and whose boiling point is above the boiling point of said amine (I) under said distillation conditions to obtain, after the distillation, a mixture (VI) comprising essentially said compound (IV).

公开(公告)号：DE10001401A1

公开(公告)日：2001-07-19

申请号：DE10001401

申请日：2000-01-14

Applicant: BASF AG

Inventor： TELES JOAQUIM HENRIQUE ,  REHFINGER ALWIN ,  BASLER PETER ,  RIEBER NORBERT ,  HEFNER WERNER ,  WENZEL ANNE ,  RUDOLF PETER

IPC: B01D3/00 ,  C07B61/00 ,  C07C5/42 ,  C07C11/06 ,  C07D301/12 ,  C07D301/32 ,  C07D303/04 ,  C07C7/148 ,  C07C7/04 ,  C07C11/00 ,  C07D301/19

Abstract: A mixture (M1) comprising an alkene and oxygen is worked up by a process in which (i) oxygen is removed from the mixture (M1) by a nondistillative method to give a mixture (M2) and (ii) the alkene is separated off from the mixture (M2) by distillation.

公开(公告)号：BR9912284A

公开(公告)日：2001-04-17

申请号：BR9912284

申请日：1999-07-02

Applicant: BASF AG

Inventor： LUYKEN HERMANN ,  OHLBACH FRANK ,  ANSMANN ANDREAS ,  BASSLER PETER ,  FISCHER ROLF ,  MELDER JOHANN-PETER ,  MERGER MARTIN ,  REHFINGER ALWIN ,  VOIT GUIDO ,  ACHHAMMER G NTHER

IPC: C07B61/00 ,  C07C209/48 ,  C07C209/84 ,  C07C209/86 ,  C07C211/12 ,  C07C253/30 ,  C07C253/34 ,  C07C255/24

Abstract: The invention relates to a method for simultaneous production of 6-aminocapronitrile and hexamethylenediamine from adipodinitrile, comprising the following steps: a) hydrogenating adipodinitrile in the presence of a catalyst containing an element of the VIII subgroup thereby obtaining a mixture containing 6-aminocapronitrile, hexamethylenediamine, adipodinitrile and high boilers; b) distillative separation of hexamethylenediamine from the mixture containing 6-aminocapronitrile, hexamethylenediamine, adipodinitrile and high boilers or c1) distillative separating 6-aminocapronitrile and subsequently d1) distillative separation of adipodinitrile or c2) simultaneous distillative separation of 6-aminocapronitrile and adipodinitrile into separate fractions. The invention is characterized in that temperatures in the bottoms of the column in steps d1) or c2) are under 185 DEG C. The adipodinitrile thus obtained contains less impurities than for instance 1-amino-2-cyanocyclopentenes.

公开(公告)号：DE19936547A1

公开(公告)日：2001-02-15

申请号：DE19936547

申请日：1999-08-04

Applicant: BASF AG

Inventor： TELES JOAQUIM HENRIQUE ,  REHFINGER ALWIN ,  BASLER PETER ,  RIEBER NORBERT ,  WENZEL ANNE ,  WALCH ANDREAS ,  HARDER WOLFGANG

IPC: C07B61/00 ,  C07D301/12 ,  C07D303/04 ,  C07B33/00

Abstract: The invention concerns a method for reacting an organic compound with a hydroperoxide using at least a heterogeneous catalyst. Said method is characterised in that the pH and the temperature of the reaction medium are modified during the reaction.