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公开(公告)号:DE19524618A1
公开(公告)日:1997-01-09
申请号:DE19524618
申请日:1995-07-06
Applicant: BASF AG
Inventor: HENKELMANN JOCHEM DR , HEIDER MARC DR , RUEHL THOMAS DR
IPC: B01J31/02 , C07B61/00 , C07D233/56 , C07D233/58 , C07D235/06 , C07D249/08 , C07D521/00
Abstract: Prepn. of N-alkenyl azoles of formula (I) is by reaction of azoles (II) with alkenyl carboxylic acid esters (III) at 0-180 degC/0.01-10 bar. The novel feature being that the reaction is in presence of a base and a quat. salt. X = CHR or N; R and R = H or 1-8C alkyl R -R = H; 1-40C alkyl; 2-40C alkenyl; 3-20C cycloalkyl; 4-20C alkylcycloalkyl or cycloalkyl-alkyl; or aryl or 7-20C alkaryl or aralkyl each opt substd up to 5 times by 1-8C alkyl or alkoxy or halogen; or R +R , R +R or R +R together form a 2-10C alkylene chain opt. substd. up to 6 times by 1-8C alkyl; and R = H; 1-40C alkyl; 3-20C cycloalkyl; 4-20C alkyl-cycloalkyl; aryl or 7-20C aralkyl, each opt. substd. up to 3 times by 1-8C alkyl; or 7-20C alkaryl.
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公开(公告)号:DE19513840A1
公开(公告)日:1996-10-17
申请号:DE19513840
申请日:1995-04-12
Applicant: BASF AG
Inventor: RUEHL THOMAS DR , HENKELMANN JOCHEM DR , HEIDER MARC DR , HOFMANN PETER PROF DR
IPC: B01J31/24 , C07B61/00 , C07C45/68 , C07C45/69 , C07C47/222 , C07C47/232 , C07C49/207 , C07C49/217 , C07C67/347 , C07C69/606 , C07C69/612 , C07C253/30 , H04L25/03 , C07C49/24 , C07B37/02 , C07C2/02 , C07C29/44 , C07C33/042 , C07C253/08 , C07C255/06
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公开(公告)号:DE4426003A1
公开(公告)日:1996-01-25
申请号:DE4426003
申请日:1994-07-22
Applicant: BASF AG
Inventor: RATH HANS PETER DR , MACH HELMUT DR , SCHWAHN HARALD DR , MUELLER HANS-JOACHIM DR , REIF WOLFGANG DR , RUEHL THOMAS DR
IPC: C10L1/192 , C08F8/12 , C08F8/32 , C08F255/00 , C08F290/00 , C08F290/02 , C10G75/00 , C10L1/14 , C10L1/18 , C10L1/195 , C10L1/197 , C10L1/198 , C10L1/22 , C10L1/236 , C10L1/238 , C10L10/00 , C10L10/08 , C10M129/90 , C10M133/54 , C10M145/04 , C10M145/06 , C10M149/04 , C10N20/04 , C10N30/04 , C10N40/25 , C10N60/02 , C08F8/00 , C07D521/00 , C10M107/22 , C10M145/02
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公开(公告)号:DE4313922A1
公开(公告)日:1994-11-03
申请号:DE4313922
申请日:1993-04-28
Applicant: BASF AG
Inventor: HEIDER MARC DR , RUEHL THOMAS DR , HENKELMANN JOCHEM DR
IPC: B01J31/20 , B01J31/22 , B01J31/24 , C07B61/00 , C07C67/04 , C07C67/055 , C07C69/01 , C07C69/24 , C07C69/78
Abstract: Vinyl carboxylates are prepared by reacting a carboxylic acid with acetylene in the presence of a platinum metal complex catalyst which contains, as ligands, carbon monoxide or a nitrile (I), a tertiary nitrogen base (2), a tertiary phosphorus compound having C- and/or O-organic radicals (III), or mixtures of these compounds. The process products are used as monomers or comonomers for polymer dispersions.
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