公开(公告)号：JPH10101584A

公开(公告)日：1998-04-21

申请号：JP16264597

申请日：1997-06-19

Applicant: BASF AG

Inventor： RUEHL THOMAS DR ,  BREITSCHEIDEL BORIS DR ,  HENKELMANN JOCHEM DR ,  REIF WOLFGANG DR ,  MENIG HELMUT DR ,  WEIGUNY SABINE

IPC: B01J23/46 ,  B01J35/10 ,  C07B35/02 ,  C07B61/00 ,  C07C29/141 ,  C07C29/149 ,  C07C29/20 ,  C07C31/12 ,  C07C31/125 ,  C07C31/135 ,  C07C31/20 ,  C07C35/08 ,  C07C35/21 ,  C07C209/72 ,  C07C211/35 ,  C07C211/36

Abstract: PROBLEM TO BE SOLVED: To enable the reaction of organic substances in far much higher reaction yield or almost quantitatively with a low metal-content catalyst, by using a specific carrier-supported ruthenium catalyst. SOLUTION: In the presence of (A) a catalyst that is prepared by depositing (A1 ) ruthenium only or together with (A2 ) another metal in groups IB, VIIB or VIIIB on a carrier (A3 ) where the average pore size and BET specific surface area are >=50nm and /g, respectively, the content of A1 is 0.01-30wt.% based on the whole catalyst weight and the surface area ratio of A1 /A3 of

公开(公告)号：JPH1053539A

公开(公告)日：1998-02-24

申请号：JP12283197

申请日：1997-04-28

Applicant: BASF AG

Inventor： RUEHL THOMAS DR ,  BREITSCHEIDEL BORIS DR ,  BROECKER FRANZ-JOSEF DR ,  REIF WOLFGANG DR ,  HENKELMANN JOCHEM DR ,  BRAUCH KARL HEINZ ,  HENNE ANDREAS DR

IPC: B01J23/46 ,  C07B35/02 ,  C07B61/00 ,  C07C29/132 ,  C07C29/141 ,  C07C29/149 ,  C07C29/20 ,  C07C35/08 ,  C07C209/72 ,  C07C211/40 ,  C08F8/04

Abstract: PROBLEM TO BE SOLVED: To provide a method for reacting an organic compound by which the reaction of the organic compound is performed in extremely high yield or nearly complete conversion by using a specific catalyst. SOLUTION: All organic compound of a monomer and a polymer, especially an organic compound having a treatable group by hydrogen such as C-C double bond and C-C triple bond are reacted in the presence of a uniform ruthenium compound or a mixture of two or more kinds thereof deposited on a carrier in situ in the method for reacting an organic compound. The reaction is preferably hydrogenation, dehydrogenation, hydrogenolysis, amination hydrogenation or dehalogenation. The catalyst is the supported catalyst obtained by subjecting a solution of the ruthenium compound or two or more kinds thereof to pass through in the carrier or on the carrier to form the uniform ruthenium compound or mixture of two or more compound thereof deposited on the carrier. The smallest amount of a byproduct or a degrading product is formed during the hydrogenation and the reaction is performed without separation, after- treatment and recycle of the catalyst in the method.

公开(公告)号：EP0813906A3

公开(公告)日：1998-11-18

申请号：EP97109944

申请日：1997-06-18

Applicant: BASF AG

Inventor： RUEHL THOMAS DR ,  BREITSCHEIDEL BORIS DR ,  HENKELMANN JOCHEN DR ,  REIF WOLFGANG DR ,  MENIG HELMUT DR ,  WEIGUNY SABINE DR

IPC: B01J23/46 ,  B01J35/10 ,  C07B35/02 ,  C07B61/00 ,  C07C29/141 ,  C07C29/149 ,  C07C29/20 ,  C07C31/12 ,  C07C31/125 ,  C07C31/135 ,  C07C31/20 ,  C07C35/08 ,  C07C35/21 ,  C07C209/72 ,  C07C211/35 ,  C07C211/36

CPC classification number: C07C29/149 ,  B01J23/462 ,  C07C29/141 ,  C07C29/20 ,  C07C209/72 ,  C07C2601/14 ,  C07C31/12 ,  C07C31/20 ,  C07C35/08 ,  C07C35/21 ,  C07C211/35 ,  C07C211/37

Abstract: Verfahren zur Umsetzung einer organischen Verbindung in Gegenwart eines Katalysators, der als Aktivmetall Ruthenium alleine oder zusammen mit mindestens einem Metall der I., VII. oder VIII. Nebengruppe des Periodensystems, aufgebracht auf einem Träger, umfaßt, wobei der Träger einen mittleren Porendurchmesser von mindestens 50 nm und eine Oberfläche BET von höchstens 30 m
2 /g aufweist und die Menge des Aktivmetalls 0,01 bis 30 Gew.-%, bezogen auf das Gesamtgewicht des Katalysators, beträgt, wobei das Verhältnis der Oberflächen des Aktivmetalls und des Katalysatorträgers

Abstract translation: 有机化合物在含有0.01-30％（重量）钌（Ru）作为活性金属，催化剂的存在下与亚基反应可能一起I，VII或VIII族金属（多个）上的支撑（I）与以平均孔径 至少50nm并且不大于30μm<2> /克，其中活性金属表面以支撑表面的比小于0:05的BET表面的（PD）。 因此要求作为以上是支持的催化剂。

公开(公告)号：EP0813906A2

公开(公告)日：1997-12-29

申请号：EP97109944

申请日：1997-06-18

Applicant: BASF AG

Inventor： RUEHL THOMAS DR ,  BREITSCHEIDEL BORIS DR ,  HENKELMANN JOCHEN DR ,  REIF WOLFGANG DR ,  MENIG HELMUT DR ,  WEIGUNY SABINE DR

IPC: B01J23/46 ,  B01J35/10 ,  C07B35/02 ,  C07B61/00 ,  C07C29/141 ,  C07C29/149 ,  C07C29/20 ,  C07C31/12 ,  C07C31/125 ,  C07C31/135 ,  C07C31/20 ,  C07C35/08 ,  C07C35/21 ,  C07C209/72 ,  C07C211/35 ,  C07C211/36

CPC classification number: C07C29/149 ,  B01J23/462 ,  C07C29/141 ,  C07C29/20 ,  C07C209/72 ,  C07C2601/14 ,  C07C31/12 ,  C07C31/20 ,  C07C35/08 ,  C07C35/21 ,  C07C211/35 ,  C07C211/37

Abstract: Verfahren zur Umsetzung einer organischen Verbindung in Gegenwart eines Katalysators, der als Aktivmetall Ruthenium alleine oder zusammen mit mindestens einem Metall der I., VII. oder VIII. Nebengruppe des Periodensystems, aufgebracht auf einem Träger, umfaßt, wobei der Träger einen mittleren Porendurchmesser von mindestens 50 nm und eine Oberfläche BET von höchstens 30 m /g aufweist und die Menge des Aktivmetalls 0,01 bis 30 Gew.-%, bezogen auf das Gesamtgewicht des Katalysators, beträgt, wobei das Verhältnis der Oberflächen des Aktivmetalls und des Katalysatorträgers

Abstract translation: 一种用于在催化剂的存在下单独或与子组中的至少一种金属I，VII，或VIII。周期表的子群施加到载体，其中所述载体具有的平均孔直径一起包含作为活性金属钌的有机化合物反应过程中的至少 具有50纳米和至多30微米的BET表面积<2> / g，并且活性金属的量为0.01至30重量％，基于催化剂的总重量计，活性金属的表面的比率，该催化剂载体 <0.05，催化剂被限定为这样。

公开(公告)号：DE19626659A1

公开(公告)日：1998-01-08

申请号：DE19626659

申请日：1996-07-03

Applicant: BASF AG

Inventor： MASSONNE KLEMENS DR ,  BECKER RAINER DR ,  REIF WOLFGANG DR ,  NEUHAUSER HORST DR ,  GIESELER ANDREAS DR ,  MUNDINGER KLAUS DR

IPC: C07D307/88 ,  C07D307/89

Abstract: The invention concerns a process for preparing phthalides of general formula (I) in which R , R , R and R , independently of each, other mean hydrogen, C1-C4 alkyl or C1-C4 alkoxy, by the catalytic hydrogenation of phthalic acid anhydrides of general formula (II), in which the groups R , R , R and R have the above meanings, in a solvent, the phthalide (I), which is produced as a reaction product during the catalytic hydrogenation process, being used as solvent.

公开(公告)号：DE19616822A1

公开(公告)日：1997-10-30

申请号：DE19616822

申请日：1996-04-26

Applicant: BASF AG

Inventor： RUEHL THOMAS DR ,  BREITSCHEIDEL BORIS DR ,  BROECKER FRANZ-JOSEF DR ,  REIF WOLFGANG DR ,  HENKELMANN JOCHEM DR ,  BRAUCH KARL HEINZ ,  HENNE ANDREAS DR

IPC: B01J23/46 ,  C07B35/02 ,  C07C29/141 ,  C07C29/149 ,  C07C29/20 ,  C07C209/72 ,  C08F8/04 ,  C07C211/35 ,  C07C35/08 ,  C07C35/21 ,  C07C211/36 ,  C07C213/08 ,  C07C215/42

Abstract: Reacting an organic compound (I) in the presence of a catalyst, in which the catalyst comprises a homogeneous ruthenium compound or a mixture of two or more such compounds, deposited in situ on a support. Also claimed is a supported catalyst which is obtained by deposition of Ru compound(s) as above, by passing a solution of Ru compound(s) through or over a support.

公开(公告)号：DE4423346A1

公开(公告)日：1996-01-11

申请号：DE4423346

申请日：1994-07-04

Applicant: BASF AG

Inventor： REIF WOLFGANG DR ,  HESSE MICHAEL DR ,  ZIMMERMANN HORST DR ,  LINGK HEINZ

IPC: B01J23/72 ,  B01J23/76 ,  C07C209/48 ,  C07C209/60 ,  C07C211/09 ,  C07C211/00 ,  C07C209/00

Abstract: A catalyst (C) consisting of 85-100 wt.% copper oxide and zirconium oxide and 15-0 wt.% metal oxides of groups Ib to VIIb and VIII of the Periodic Table is new. Also claimed is the prepn. of amines by reaction of nitrile with ammonia, or prim. or sec. amine at 80-250 degrees C and 1-400 bar with hydrogen and a catalyst (C). Pref. prepn. of NR1R2-CH2R3 (I) comprises reaction of R3CN with NHR1R2. R1, R2 = H, 1-20C alkyl, 3-12C cycloalkyl, aryl, 7-20C aralkyl, 7-20C alkylaryl; R3 = 1-200C alkyl, 3-12C cycloalkyl, 1-20C alkyl (substd. with NH2, NHMe, NMe2 and/or OH), 2-30C alkoxyalkyl, (CH2-CHR5-O)nR4, aryl, 7-20C aralkyl or 7-20C alkylaryl; n = 2-30; R4 = H, 1-4C alkyl; R5 = H or Me.

公开(公告)号：ES2136225T3

公开(公告)日：1999-11-16

申请号：ES95109869

申请日：1995-06-24

Applicant: BASF AG

Inventor： REIF WOLFGANG DR ,  HESSE MICHAEL DR ,  ZIMMERMANN HORST DR ,  LINGK HEINZ

IPC: B01J23/72 ,  B01J23/76 ,  C07C209/48 ,  C07C209/60 ,  C07C211/09

Abstract: A catalyst (C) consisting of 85-100 wt.% copper oxide and zirconium oxide and 15-0 wt.% metal oxides of groups Ib to VIIb and VIII of the Periodic Table is new. Also claimed is the prepn. of amines by reaction of nitrile with ammonia, or prim. or sec. amine at 80-250 degrees C and 1-400 bar with hydrogen and a catalyst (C). Pref. prepn. of NR1R2-CH2R3 (I) comprises reaction of R3CN with NHR1R2. R1, R2 = H, 1-20C alkyl, 3-12C cycloalkyl, aryl, 7-20C aralkyl, 7-20C alkylaryl; R3 = 1-200C alkyl, 3-12C cycloalkyl, 1-20C alkyl (substd. with NH2, NHMe, NMe2 and/or OH), 2-30C alkoxyalkyl, (CH2-CHR5-O)nR4, aryl, 7-20C aralkyl or 7-20C alkylaryl; n = 2-30; R4 = H, 1-4C alkyl; R5 = H or Me.

公开(公告)号：DE59504667D1

公开(公告)日：1999-02-11

申请号：DE59504667

申请日：1995-07-13

Applicant: BASF AG

Inventor： RATH HANS PETER DR ,  MACH HELMUT DR ,  SCHWAHN HARALD DR ,  MUELLER HANS-JOACHIM DR ,  REIF WOLFGANG DR ,  RUEHL THOMAS DR

IPC: C10L1/192 ,  C08F8/12 ,  C08F8/32 ,  C08F255/00 ,  C08F290/00 ,  C08F290/02 ,  C10G75/00 ,  C10L1/14 ,  C10L1/18 ,  C10L1/195 ,  C10L1/197 ,  C10L1/198 ,  C10L1/22 ,  C10L1/236 ,  C10L1/238 ,  C10L10/00 ,  C10L10/08 ,  C10M129/90 ,  C10M133/54 ,  C10M145/04 ,  C10M145/06 ,  C10M149/04 ,  C10N20/04 ,  C10N30/04 ,  C10N40/25 ,  C10N60/02

公开(公告)号：DE4336247A1

公开(公告)日：1995-04-27

申请号：DE4336247

申请日：1993-10-22

Applicant: BASF AG

Inventor： STRECKER BEATE DR ,  OETTER GUENTER DR ,  OFTRING ALFRED DR ,  PERNER JOHANNES DR ,  BAUR RICHARD DR ,  SCHWENDEMANN VOLKER DR ,  KAHMEN MARTIN AUS DEM DR ,  REIF WOLFGANG DR

IPC: C11D1/72 ,  A01N25/30 ,  A61K47/18 ,  C07C231/02 ,  C07C233/18 ,  C07C233/20 ,  C09D17/00 ,  C09K8/035 ,  C09K8/28 ,  C09K23/00 ,  C09K23/42 ,  C11D1/52 ,  C23G5/00 ,  B01F17/42 ,  C09K7/02 ,  A61K7/48 ,  A61K7/06

Abstract: PCT No. PCT/EP94/03354 Sec. 371 Date Apr. 22, 1996 Sec. 102(e) Date Apr. 22, 1996 PCT Filed Oct. 12, 1994 PCT Pub. No. WO95/11225 PCT Pub. Date Apr. 27, 1995The use of endgroup-capped fatty amide alkoxylates IR1-CO-NH-(CH2)n-O-(AO)x-R2(I)where R1 is C5-C21-alkyl or -alkenyl, R2 is C1-C4-alkyl, A is C2-C4-alkylene, n is 2 or 3, and x has a value from 1 to 6, as nonionic surfactants or emulsifiers in detergents, cleaners or body care compositions, as surface-active substances for industrial applications in electroplating, in the photographic industry, in petroleum production, in the pharmaceutical industry, in plant feeding and in crop protection formulations, and as surface-active substances in the production of emulsions and pigment and plastic dispersions.