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公开(公告)号:CZ296358B6
公开(公告)日:2006-02-15
申请号:CZ20003436
申请日:1999-03-18
Applicant: BASF AG
Inventor: BREINER URLIKE , JULIUS MANFRED , NEUBERG RAINER , WEISS ROBERT , WILMS AXEL , HU HARRY Y
Abstract: Zpusob výroby polyamidu spocívá v tom, ze se polymerizace výchozích monomeru nebo výchozích oligomeru provádí za prítomnosti alespon jedné slouceninyvzorce (I), ve kterém znací R funkcní skupinu R.sup.8.n., která nese 1 az 4 stejné nebo rozdílné amidotvorné skupiny R.sup.7.n.; R.sup.1.n. je H, C.sub.1.n. az C.sub.20.n.-alkyl, cykloalkyl, benzyl, OR.sup.6.n., kde znací R.sup.6.n. H, C.sub.1.n. azC.sub.20.n.-alkyl, cykloalkyl, benzyl; R.sup.2.n., R.sup.3.n., R.sup.4.n., R.sup.5.n. jsou nezávisle na sobe C.sub.1.n. az C.sub.20.n.-alkyl; n je prirozené císlo vetsí nez 1, pricemz piperidinové deriváty vázané na R jsou se zretelem na substituenty, to znamená R.sup.1.n., R.sup.2.n., R.sup.3.n., R.sup.4.n. a R.sup.5.n., rozdílné nebo stejné. Takto vyrobené polyamidy se pouzívají k výrobe nití, vláken, fólií, plosných útvaru a tvarových teles.
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公开(公告)号:CO5570708A2
公开(公告)日:2005-10-31
申请号:CO05049747
申请日:2005-05-23
Applicant: BASF AG
Inventor: HUNGER HANS-HARALD , WEISS ROBERT
Abstract: 1.- Procedimiento para la obtención de una poliamida que contiene pigmentos de dióxido de titanio, caracterizado porque se dispersan pigmentos de dióxido de titanio en una mezcla de partida que contiene agua y caprolactama mediante un dispositivo,cuyo dispositivo presenta: una cámara de dispersión, un rotor discoidal dispuesto en esta cámara de dispersión, un estator con orificios radiales, que está dispuesto en la cámara de dispersión en conexión con el rotor, una entrada de producto en cada lado del rotor, cuyas dos entradas tienen, preferentemente, cada vez una sección de canal axial tal, que las dos corrientes de producto sean reunidas en la región del borde exterior del disco rotor, y una salida de producto en el borde exterior de la zona de dispersión de la cámara de dispersión,en donde los pigmentos de dióxido de titanio son alimentados por una de las entradas de producto mencionadas y la mezcla de partida, que contiene agua y caprolactama, es alimentada por la otra de la entradas de producto en la cámara de dispersión, obteniéndose una mezcla de producto, que contiene agua, caprolactama y el pigmento de dióxido de titanio usado por vía de la salida de producto,yla mezcla de producto es polimerizada en una poliamida que contiene pigmentos de dióxido de titanio.2.- Procedimiento según la reivindicación 1, en donde la mezcla de partida contiene adicionalmente un dispersante.3.- Procedimiento según la reivindicación 1 o la reivindicación 2, en donde se elimina agua de la mezcla de producto antes o durante la polimerización.
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公开(公告)号:PL367209A1
公开(公告)日:2005-02-21
申请号:PL36720902
申请日:2002-05-17
Applicant: BASF AG
Inventor: WEISS ROBERT , NEUBERG RAINER , WILMS AXEL , KLOSTERMANN RAINER , RICHTER KONRAD
Abstract: Polymeric material (I) comprising a) a polymer (II) having amide groups recurring in the polymer main chain and b) from 0.01 to 5% by weight, based on this polymer, of a titanium dioxide (III) having a median particle size d50 of up to 150 nm, and fibers, sheet materials and moldings comprising such a polymeric material.
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公开(公告)号:AU2003274041A1
公开(公告)日:2004-05-13
申请号:AU2003274041
申请日:2003-10-18
Applicant: BASF AG
Inventor: PLACHETTA CHRISTOPH , HECKMANN MANFRED , HUNGER HANS-HARALD , WEISS ROBERT
Abstract: Disclosed is a method for producing a polyamide containing titanium dioxide pigments. Said method is characterized by the fact that titanium dioxide pigments are dispersed in an initial mixture containing water and caprolactam by means of a device comprising a dispersion chamber, a disk-shaped rotor that is disposed inside said dispersion chamber, a stator that is provided with radial openings, is arranged within the dispersion zone of the dispersion chamber, and is connected to the rotor, a substance inlet located on each side of the rotor, preferably with a respective axial duct section such that the two flows of substance are combined in the peripheral edge area of the rotor disk, and a product outlet which is placed on the outer edge of the dispersion zone of the dispersion chamber, by feeding the titanium dioxide pigments to the dispersion chamber through one of said substance inlets while feeding the initial mixture containing water and caprolactam to the dispersion chamber through the other of said substance inlets, whereby a product mixture containing water, caprolactam, and the used titanium dioxide pigment is obtained via the product outlet, and the product mixture is polymerized so as to obtain a polyamide containing titanium dioxide pigments. Also disclosed are polyamides obtained according to the inventive method and the use of such polyamides as a masterbatch.
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公开(公告)号:CA2503287A1
公开(公告)日:2004-05-06
申请号:CA2503287
申请日:2003-10-18
Applicant: BASF AG
Inventor: PLACHETTA CHRISTOPH , HECKMANN MANFRED , HUENGER HANS-HARALD , WEISS ROBERT
Abstract: Disclosed is a method for producing a polyamide containing titanium dioxide pigments. Said method is characterized by the fact that titanium dioxide pigments are dispersed in an initial mixture containing water and caprolacta m by means of a device comprising a dispersion chamber, a disk-shaped rotor th at is disposed inside said dispersion chamber, a stator that is provided with radial openings, is arranged within the dispersion zone of the dispersion chamber, and is connected to the rotor, a substance inlet located on each si de of the rotor, preferably with a respective axial duct section such that the two flows of substance are combined in the peripheral edge area of the rotor disk, and a product outlet which is placed on the outer edge of the dispersi on zone of the dispersion chamber, by feeding the titanium dioxide pigments to the dispersion chamber through one of said substance inlets while feeding th e initial mixture containing water and caprolactam to the dispersion chamber through the other of said substance inlets, whereby a product mixture containing water, caprolactam, and the used titanium dioxide pigment is obtained via the product outlet, and the product mixture is polymerized so a s to obtain a polyamide containing titanium dioxide pigments. Also disclosed a re polyamides obtained according to the inventive method and the use of such polyamides as a masterbatch.
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公开(公告)号:SK14012003A3
公开(公告)日:2004-05-04
申请号:SK14012003
申请日:2002-05-17
Applicant: BASF AG
Inventor: WEISS ROBERT , NEUBERG RAINER , WILMS AXEL , KLOSTERMANN RAINER , RICHTER KONRAD
Abstract: Polymeric material (I) comprising a) a polymer (II) having amide groups recurring in the polymer main chain and b) from 0.01 to 5% by weight, based on this polymer, of a titanium dioxide (III) having a median particle size d50 of up to 150 nm, and fibers, sheet materials and moldings comprising such a polymeric material.
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公开(公告)号:ES2178419T3
公开(公告)日:2002-12-16
申请号:ES99916829
申请日:1999-03-18
Applicant: BASF AG
Inventor: DARDIN ULRIKE , JULIUS MANFRED , NEUBERG RAINER , WEISS ROBERT , WILMS AXEL , HU HARRY Y
Abstract: A process for preparing polyamides comprises polymerizing starting monomers or starting oligomers in the presence of at least one compound of the formula (I)whereR is a functional group R which bears 1-4 identical or different amide-forming groups R ,R is H, C1-C20-alkyl, cycloalkyl, benzyl or OR , where R is H, C1-C20-alkyl, cycloalkyl or benzyl,R , R , R and R are independently C1-C10-alkyl,n is a natural number greater than 1, andthe piperidine derivatives attached to R are identical or different with regard to the substituents, meaning R , R , R , R and R .The polyamides are useful for preparing filaments, fibers, films, sheetlike structures and moldings.
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公开(公告)号:MX211540B
公开(公告)日:2002-11-21
申请号:MXPA00008864
申请日:2000-09-11
Applicant: BASF AG
Inventor: BREINER ULRIKE , JULIUS MANFRED , NEUBERG RAINER , WEISS ROBERT , WILMS AXEL , HU HARRY Y
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公开(公告)号:PT1070093E
公开(公告)日:2002-10-31
申请号:PT99916829
申请日:1999-03-18
Applicant: BASF AG
Inventor: JULIUS MANFRED , NEUBERG RAINER , WEISS ROBERT , WILMS AXEL , HU HARRY Y , DARDIN ULRIKE
Abstract: A process for preparing polyamides comprises polymerizing starting monomers or starting oligomers in the presence of at least one compound of the formula (I)whereR is a functional group R which bears 1-4 identical or different amide-forming groups R ,R is H, C1-C20-alkyl, cycloalkyl, benzyl or OR , where R is H, C1-C20-alkyl, cycloalkyl or benzyl,R , R , R and R are independently C1-C10-alkyl,n is a natural number greater than 1, andthe piperidine derivatives attached to R are identical or different with regard to the substituents, meaning R , R , R , R and R .The polyamides are useful for preparing filaments, fibers, films, sheetlike structures and moldings.
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公开(公告)号:ES2161467T3
公开(公告)日:2001-12-01
申请号:ES97927075
申请日:1997-05-28
Applicant: BASF AG
Inventor: WEBER MARTIN , HORN PETER , WEISS ROBERT , HECKMANN WALTER , HINGMANN ROLAND
IPC: C08K3/04 , C08K5/49 , C08K7/00 , C08K7/22 , C08K7/24 , C08L25/00 , C08J5/18 , C08L25/06 , C08L71/12 , D01F1/07 , D01F6/56 , D01F6/88
Abstract: Flame-retardant, thermoplastic molding materials containingA) at least one polyphenylene ether,B) at least one vinylaromatic polymer andC) at least one flameproofing agent,compriseD) an amount of expandable graphite which increases the resistance of the molding material to drippingand are used for the production of flame-retardant moldings, fibers and films.
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