公开(公告)号：WO2004024668A3

公开(公告)日：2004-10-14

申请号：PCT/EP0308831

申请日：2003-08-08

Applicant: BASF AG ,  FUNKE FRANK ,  HILL THOMAS ,  VON WATZDORF JOBST RUEDIGER ,  MATTMANN WOLFGANG ,  HARDER WOLFGANG ,  HENKES ERHARD ,  LITTMANN GERD ,  JULIUS MANFRED

Inventor： FUNKE FRANK ,  HILL THOMAS ,  VON WATZDORF JOBST RUEDIGER ,  MATTMANN WOLFGANG ,  HARDER WOLFGANG ,  HENKES ERHARD ,  LITTMANN GERD ,  JULIUS MANFRED

IPC: C07C209/86 ,  B01D3/14 ,  C07C209/84 ,  C07C211/36

CPC classification number: B01D3/141 ,  B01D3/146 ,  C07C209/84 ,  Y10S203/20 ,  C07C211/36

Abstract: The invention relates to a method for obtaining 3-aminomethyl-3,5,5-trimethyl cyclohexylamine (isophorone diamine, IPDA) with a cis/trans isomer ratio of at least 73/27 by fractional distillation. Said method comprises the following steps: a) preparation of IPDA with a cis/trans isomer ratio /=73/27 and iv) an IPDA fraction with a cis/trans isomer ratio

Abstract translation: 本发明涉及一种用于具有顺式/反式异构体中的至少73/27通过分馏，其包括以下步骤比率回收3-氨基甲基-3,5,5-三甲基环己胺（异佛尔酮二胺，IPDA）：a）提供 具有IPDA顺/反异构体比率<73/27; b）将IPDA送入蒸馏塔的中间区域具有内部和在一定温度下在该蒸馏塔中蒸馏IPDA。 为5〜300℃，为10〜2000毫巴的压力; c）任选地进一步纯化由步骤b）通过在至少一个另外的塔中蒸馏得到IPDA; 其中，所述步骤b）和c）需要在步骤a中使用的IPDA的分离）放置到至少五个级分IA）至iv）：IA）erunreinigungen低于一小部分的有机比例反式IPDA沸腾V，IB）的含水部分 一小部分比反式IPDA沸点杂质下，ii）除了顺式IPDA沸点杂质更高的馏分，iii）具有> = 73/27的顺/反异构体比率的IPDA馏分和iv）具有顺式的IPDA馏分 式/反式异构体比率<= 66/34。

公开(公告)号：WO2005028416A2

公开(公告)日：2005-03-31

申请号：PCT/EP2004010765

申请日：2004-09-24

Applicant: BASF AG ,  REUTEMANN WERNER ,  WAMBSGANSS ROLF ,  POPLOW FRANK ,  WEBER THEODOR ,  ROSS KARL-HEINZ ,  JULIUS MANFRED

Inventor： REUTEMANN WERNER ,  WAMBSGANSS ROLF ,  POPLOW FRANK ,  WEBER THEODOR ,  ROSS KARL-HEINZ ,  JULIUS MANFRED

IPC: C07C209/16 ,  C07C211/04 ,  C07C209/00

CPC classification number: C07C209/16 ,  C07C211/04

Abstract: The invention relates to a method for the production of metylamines by means of gas phase reaction from methanol and ammonia as educts in the presence of a heterogeneous catalyst at a pressure in the region of 15 - 30 bars. Said educts are vaporised in one or several heat exchangers (1, 2, 3) in order to overheat an educt gas flow and are subsequently guided to a reactor (4). The educts can be mixed in the inlets of one of the heat exchangers (1, 2, 3) or at one remaining position in a heat exchanger (1, 2, 3). A product gas flow containing monomethylamine, dimethylamine and trimethylamine, in addition to reaction auxiliary products, is removed from the reactor (4). In order to regulate the reactor admission temperature of the educts to a temperature in the region of 360 DEG C - 370 DEG C, the educt gas flow or the product gas flow is guided partially or completely through an adjustable valve (5) enabling the pressure and the condensation temperature to be varied.

Abstract translation: 本发明涉及一种用于在15〜30巴范围内的制备Metylaminen的由甲醇和氨作为原料在非均相催化剂的存在下的气相反应在压力下进行。 起始材料在一个或多个热交换器（1,2，3）蒸发至过热的进料气流，然后提供一个反应器（4），其中所述进料在反应物的混合到热交换器中的一个（1，2，3），或 热交换器（1,2,3）中的任何位置都可以发生。 从反应器（4）中取出一甲胺，二甲胺和三甲胺以及含产物气流的反应副产物。 为了控制反应物的反应器入口温度的温度在360℃至370℃，进料气流或产品气流的压力的变化，从而冷凝温度通过可调节的阀（5）的一部分或全部通过。

公开(公告)号：IN525CH2000A

公开(公告)日：2007-03-02

申请号：IN525CH2000

申请日：2001-10-13

Applicant: BASF AG

Inventor： BREINER ULRIKE ,  JULIUS MANFRED ,  NEUBERG RAINER ,  WEISS ROBERT ,  WILMS AXEL ,  HU HARRY Y

IPC: C08G69/00 ,  C08G69/04 ,  C08G69/16 ,  C08G69/28 ,  C08G69/48 ,  C08K5/3435

Abstract: A process for preparing polyamides comprises polymerizing starting monomers or starting oligomers in the presence of at least one compound of the formula (I)whereR is a functional group R which bears 1-4 identical or different amide-forming groups R ,R is H, C1-C20-alkyl, cycloalkyl, benzyl or OR , where R is H, C1-C20-alkyl, cycloalkyl or benzyl,R , R , R and R are independently C1-C10-alkyl,n is a natural number greater than 1, andthe piperidine derivatives attached to R are identical or different with regard to the substituents, meaning R , R , R , R and R .The polyamides are useful for preparing filaments, fibers, films, sheetlike structures and moldings.

公开(公告)号：BG64908B1

公开(公告)日：2006-08-31

申请号：BG10478900

申请日：2000-09-20

Applicant: BASF AG

Inventor： BREINER ULRIKE ,  JULIUS MANFRED ,  NEUBERG RAINER ,  WEISS ROBERT ,  WILMS AXEL ,  HU HARRY

IPC: C08G69/00 ,  C08G69/04 ,  C08G69/16 ,  C08G69/28 ,  C08G69/48 ,  C08K5/3435

Abstract: The invention relates to a method for producing polyamides, characterized in that the polymerization of starting monomers or starting oligomers is carried out in the presence of at least one compoundof formula where R is a functional group R8 which has 1 to 4 identical or different amide-forming groups R7; R1 is H, C1-C20 alkyl, cycloalkyl, benzyl, OR6 where R6 is H, C1-C20 alkyl, cycloalkyl, benzyl; R2, R3, R4, R5 independently of each other are C1-C10 alkyl; n is a natural number greater than 1, and the piperidine derivatives linked to R are identical to or different from the substituents,that is R1, R2, R3, R4 and R5. Said polyamides can be used to produce thread, fibres, films, flat structures and moulded bodies.

公开(公告)号：MY121277A

公开(公告)日：2006-01-28

申请号：MYPI9702410

申请日：1997-05-31

Applicant: BASF AG

Inventor： KRAUSE ALFRED ,  RUST HARALD ,  SIEGEL HARDO ,  JULIUS MANFRED ,  WITZEL TOM ,  SIEGEL WOLFGANG

IPC: C07D211/58 ,  C07D211/56 ,  C07D221/20

Abstract: A PROCESS FOR PURIFYING CRUDE PIPERIDINES OF THE FORMULA I WHERE RL TO R4 ARE CI-C6-ALKYL, OR RL AND R2 AND/OR R3 AND R4 TOGETHER ARE A CH2-CHAIN OF 2 TO 5 CARBONS, WHICH COMPRISES, IN A FIRST STEP, REMOVING HIGH-BOILING SUBSTANCES AND, IF PRESENT, WATER FROM THE CRUDE PIPERIDINES BY DISTILLATION; IN A SECOND STEP, ADDING FROM 0.01 TO 5 % BY WEIGHT, BASED ON THE PRODUCT OF THE FIRST STEP, AS A REDUCING AGENT; AND, IN A THIRD STEP, ISOLATING THE PIPERIDINES BY DISTILLATION.

公开(公告)号：CA2257094C

公开(公告)日：2005-11-22

申请号：CA2257094

申请日：1997-05-28

Applicant: BASF AG

Inventor： SIEGEL WOLFGANG ,  WITZEL TOM ,  JULIUS MANFRED ,  SIEGEL HARDO ,  RUST HARALD ,  KRAUSE ALFRED

IPC: C07B63/04 ,  C07D211/58 ,  C07D211/72 ,  C07D221/20 ,  C08K5/3435

Abstract: A process for reducing the dimerisation of piperidine of formula (I) in which R1 to R4 are C1 to C6 alkyl, R1 and R2 and/or R3 and R4 together are a CH2 chain with 2 to 5 C atoms. Said process is characterised in that to the piperidine is added 0.001 to 0.2 wt% of a reducing agent of the formula MXH4-m Y m, in which M is an alkaline metal, NR4, where R are the same or different C1-C4 alkyl groups, or an equivalent of an alkaline earth metal or an equivalent zinc, X is boron or aluminium, Y is H or CN and m is 0 or 1. Also described is a mixture of piperidine (I), 0.001 to 0.2 wt% of a reducing agent and 1 to 1000 ppm of the dimer of the piperidine (I), and the production of HALS stabilisers therefrom.

公开(公告)号：AU2003258591A1

公开(公告)日：2004-04-30

申请号：AU2003258591

申请日：2003-08-08

Applicant: BASF AG

Inventor： HENKES ERHARD ,  LITTMANN GERD ,  JULIUS MANFRED ,  FUNKE FRANK ,  HILL THOMAS ,  WATZDORF JOBST RUDIGER VON ,  MATTMANN WOLFGANG ,  HARDER WOLFGANG

IPC: C07C209/86 ,  B01D3/14 ,  C07C209/84 ,  C07C211/36 ,  C07C209/00

Abstract: Recovery of isophoronediamine (IPDA) comprises preparation of IPDA having a cis/trans isomer ratio of less than 73/27 and separation into at least 5 fractions by distillation including an IPDA fraction having a cis/trans ratio of greater than 73/27 and a fraction having a cis/trans ratio of less than 66/34. A process for the recovery of 3-aminomethyl-3,5,5-trimethylcyclohexylamine (isophoronediamine, IPDA) comprises; (a) preparation of IPDA having a cis/trans isomer ratio of less than 73/27; (b) introduction of IPDA to the middle region of a distillation column having inserts and distillation of IPDA at 5-300 degreesC and 10-2000 mbar; (c) optionally further purification of the IPDA from (b) by distillation in at least one further column whereby the IPDA from step (b) and (c) are separated into at least 5 fractions comprising an organic fraction (1a) containing impurities having a lower b. pt. than trans-IPDA, an aqueous fraction (1b) containing impurities having a lower b. pt. than trans-IPDA, a fraction (2) containing impurities having a higher b. pt. than cis-IPDA, an IPDA fraction (3) having a cis/trans ratio of greater than 73/27 and an IPDA fraction (4) having a cis/trans ratio of less than 66/34.

公开(公告)号：CZ292075B6

公开(公告)日：2003-07-16

申请号：CZ20002934

申请日：1999-02-12

Applicant: BASF AG

Inventor： ILG OTTO ,  BREINER ULRIKE ,  JULIUS MANFRED

IPC: C08G69/00 ,  C08G69/48 ,  C08K5/3435

Abstract: An inherently light- and heat-stabilized polyamide is prepared by polymerizing polyamide forming monomers in the presence of (a) an effective amount of at least one piperidine derivative of the general formula I: wherein Ri1 represents hydrogen, benzyl, or a alkyl containing 1 to 20 carbon atoms; Ri2 through Ri5 denote each hydrogen or the same or a different alkyl having 1 to 6 carbon atoms; X has n free valance bonding sites and represents an alkyl or substituted alkylene having from about 1 to about 30 carbon atoms or an arylene having from about 1 to about 20 carbon atoms w; m is 0 or 1; -C(O)-Ri6 represents a group that can form an amide bond together with an amine, and n is equal to 1, 2 or 3 and (b) an effective amount of at least one 4-amino-2,2,6,6-tetramethylpiperidine derivative of the general formula II: wherein Ri7 denotes hydrogen, benzyl, or a alkyl containing 1 to 20 carbon atoms. The inherently light- an heat-stabilized polyamide may be used to form articles such as, for example, fibers, carpets, yarns, and textile fabrics.

公开(公告)号：EG22326A

公开(公告)日：2002-12-31

申请号：EG28199

申请日：1999-03-18

Applicant: BASF AG

Inventor： JULIUS MANFRED

IPC: C08G69/00 ,  C08G69/04 ,  C08G69/16 ,  C08G69/28 ,  C08G69/48 ,  C08K5/3435

Abstract: A process for preparing polyamides comprises polymerizing starting monomers or starting oligomers in the presence of at least one compound of the formula (I)whereR is a functional group R which bears 1-4 identical or different amide-forming groups R ,R is H, C1-C20-alkyl, cycloalkyl, benzyl or OR , where R is H, C1-C20-alkyl, cycloalkyl or benzyl,R , R , R and R are independently C1-C10-alkyl,n is a natural number greater than 1, andthe piperidine derivatives attached to R are identical or different with regard to the substituents, meaning R , R , R , R and R .The polyamides are useful for preparing filaments, fibers, films, sheetlike structures and moldings.

公开(公告)号：SI1070093T1

公开(公告)日：2002-10-31

申请号：SI9930068

申请日：1999-03-18

Applicant: BASF AG

Inventor： BREINER ULRIKE ,  JULIUS MANFRED ,  NEUBERG RAINER ,  WEISS ROBERT ,  WILMS AXEL ,  HU HARRY Y

IPC: C08G69/00 ,  C08G69/04 ,  C08G69/16 ,  C08G69/28 ,  C08G69/48 ,  C08K5/3435

Abstract: A process for preparing polyamides comprises polymerizing starting monomers or starting oligomers in the presence of at least one compound of the formula (I)whereR is a functional group R which bears 1-4 identical or different amide-forming groups R ,R is H, C1-C20-alkyl, cycloalkyl, benzyl or OR , where R is H, C1-C20-alkyl, cycloalkyl or benzyl,R , R , R and R are independently C1-C10-alkyl,n is a natural number greater than 1, andthe piperidine derivatives attached to R are identical or different with regard to the substituents, meaning R , R , R , R and R .The polyamides are useful for preparing filaments, fibers, films, sheetlike structures and moldings.