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公开(公告)号:AT485287T
公开(公告)日:2010-11-15
申请号:AT08718289
申请日:2008-03-27
Applicant: BASF SE
Inventor: STROEFER ECKHARD , LANG NEVEN , SIEGERT MARKUS , HASSE HANS
IPC: C07D323/06
Abstract: A process for preparing trioxane from trioxymethylene glycol dimethyl ether (POMDMEn=3) by converting trioxymethylene glycol dimethyl ether in the presence of an acidic catalyst and subsequent distillative workup of the reaction mixture, comprising the steps of: a) feeding trioxymethylene glycol dimethyl ether (POMDMEn=3) or a mixture comprising trioxymethylene glycol dimethyl ether into a reactor and converting it in the presence of an acidic catalyst to a mixture a comprising trioxane, formaldehyde, water, methylene glycol (MG), polyoxymethylene glycols (MGn>1), methanol, hemiformals (HF), methylal (POMDMEn=1) and polyoxymethylene glycol dimethyl ethers (POMDMEn>1); b) distillatively separating the reaction mixture a into a low boiler fraction b1 comprising formaldehyde, water, methylene glycol, methanol, hemiformal (HFn=1), methylal and dioxymethylene glycol dimethyl ether (POMDMEn=2), and a high boiler fraction b2 comprising trioxane, polyoxymethylene glycols (MGn>1), hemiformals (HFn>1) and polyoxymethylene glycol dimethyl ethers (POMDMEn>2); c) distillatively separating the high boiler fraction b2 into a low boiler fraction c1 comprising trioxane, and a high boiler fraction c2 comprising polyoxymethylene glycols (MGn>1), hemiformals (HFn>1) and polyoxymethylene glycol dimethyl ethers (POMDMEn>2).
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公开(公告)号:DE502006007542D1
公开(公告)日:2010-09-09
申请号:DE502006007542
申请日:2006-06-12
Applicant: BASF SE
Inventor: STROEFER ECKHARD , SCHELLING HEINER , HASSE HANS , BLAGOV SERGEJ
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公开(公告)号:DE50214172D1
公开(公告)日:2010-03-04
申请号:DE50214172
申请日:2002-11-19
Applicant: BASF SE
Inventor: WOELFERT ANDREAS , MUELLER CHRISTIAN , STROEFER ECKHARD , PFEFFINGER JOACHIM , WEBER MARKUS , KNOESCHE CARSTEN
IPC: C07C263/10 , B01J12/00 , C07C265/14
Abstract: The invention relates to a method for producing isocyanates by reacting primary amines with phosgene in the gaseous phase. Said method is characterized in that the reaction of amine and phosgene occurs in a reaction channel, the internal dimensions of which have a width/height ratio of at least 2/1.
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公开(公告)号:DE502007002349D1
公开(公告)日:2010-01-28
申请号:DE502007002349
申请日:2007-06-11
Applicant: BASF SE
Inventor: SIEGERT MARKUS , LANG NEVEN , STROEFER ECKHARD , SIGWART CHRISTOPH
IPC: C07D323/06
Abstract: An integrated process for preparing trioxane from formaldehyde.
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公开(公告)号:AT455094T
公开(公告)日:2010-01-15
申请号:AT02795066
申请日:2002-11-19
Applicant: BASF SE
Inventor: WOELFERT ANDREAS , MUELLER CHRISTIAN , STROEFER ECKHARD , PFEFFINGER JOACHIM , WEBER MARKUS , KNOESCHE CARSTEN
IPC: C07C263/10 , B01J12/00 , C07C265/14
Abstract: The invention relates to a method for producing isocyanates by reacting primary amines with phosgene in the gaseous phase. Said method is characterized in that the reaction of amine and phosgene occurs in a reaction channel, the internal dimensions of which have a width/height ratio of at least 2/1.
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公开(公告)号:AT448859T
公开(公告)日:2009-12-15
申请号:AT05779042
申请日:2005-09-10
Applicant: BASF SE
Inventor: WOELFERT ANDREAS , KNOESCHE CARSTEN , PALLASCH HANS-JUERGEN , SESING MARTIN , STROEFER ECKHARD , POLKA HANS-MARTIN , HEILIG MANFRED
Abstract: The invention relates to a process for separating hydrogen chloride and phosgene, which comprises bringing a mixture of hydrogen chloride and phosgene into contact with an ionic liquid in which at least part of the hydrogen chloride is dissolved in a step a) and then separating off the hydrogen chloride dissolved in the ionic liquid in a step b).
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公开(公告)号:DE502004010159D1
公开(公告)日:2009-11-12
申请号:DE502004010159
申请日:2004-02-20
Applicant: BASF SE
Inventor: BRODHAGEN ANDREAS , SOHN MARTIN , NEVEJANS FILIP , STROEFER ECKHARD , WOELFERT ANDREAS , OEHLENSCHLAEGER STEFFEN
IPC: C07C263/10 , B01J19/24 , C07C265/14
Abstract: Production of polyisocyanates comprises mixing an amine with phosgene, reacting the amine with the phosgene in a tubular reactor, and passing the reactor effluent to a distillation column. Independent claims are also included for: (1) tubular reactor consisting of one or more horizontal and/or vertical segments connected together by sections whose diameter is smaller than that of the narrowest horizontal or vertical segment; (2) use of the above reactor for carrying out gas-liquid reactions; and (3) use of the above reactor for producing isocyanates by reacting primary amines with phosgene.
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公开(公告)号:DE502004009159D1
公开(公告)日:2009-04-23
申请号:DE502004009159
申请日:2004-03-03
Applicant: BASF SE
Inventor: STROEFER ECKHARD , LANG NEVEN , LICHTFERS UTE , STEINBRENNER ULRICH , HASSE HANS
Abstract: A method for separating a liquid mixture containing readily-volatile and sparingly-volatile components involves using a film evaporator with a heat-exchange surface which is coated with material which catalyses the formation of readily-volatile component(s) in the liquid film. A method for separating a liquid mixture containing (A) readily-volatile and (B) sparingly-volatile components in a film evaporator by (i) producing a continuous stream of a liquid starting mixture, (ii) producing a liquid film from the mixture and bringing it into contact with a heat-exchange surface of the evaporator, and (iii) partly evaporating the film to give two gas streams rich in (A) and (B) respectively. In this method, (iv) the heat-exchange surface is coated with a catalytic material and (v) a chemical reaction in which (A) is/are formed is catalysed in the liquid film. An independent claim is also included for a film evaporator with a heat-exchanger wall which is coated with catalytic material.
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公开(公告)号:ES2311284T3
公开(公告)日:2009-02-01
申请号:ES06763725
申请日:2006-06-14
Applicant: BASF SE
Inventor: FIENE MARTIN , BOHLING RALF , STROEFER ECKHARD , VOGEL HERBERT , MESRI FATIMA
IPC: C07C263/20 , C07C265/10
Abstract: Procedimiento para la elaboración de aductos de isocianato, que comprende los pasos: a) reacción de aductos de isocianato con amoniaco puro b) elaboración de productos de reacción formados en el paso a) c) recirculación de las aminas formadas en la producción de isocianato, no empleándose agua en el procedimiento.
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公开(公告)号:DE502006001408D1
公开(公告)日:2008-10-02
申请号:DE502006001408
申请日:2006-06-14
Applicant: BASF SE
Inventor: FIENE MARTIN , BOEHLING RALF , STROEFER ECKHARD , VOGEL HERBERT , MESRI FATIMA
IPC: C07C263/20 , C07C265/10
Abstract: The present invention provides a process for working up isocyanate adducts, comprising the steps of a) reacting the isocyanate adducts with pure ammonia, b) working up the reaction products obtained in step a), c) recycling the amines formed into the isocyanate production.
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