公开(公告)号：JP2002293843A

公开(公告)日：2002-10-09

申请号：JP2001099525

申请日：2001-03-30

Applicant: JSR CORP

Inventor： OSHIMA NOBORU ,  HAYASHI TOSHIHITO ,  KAIZU MITSUTAKA

IPC: G02B1/04 ,  C08F210/00 ,  C08F232/04 ,  C08K3/22 ,  C08K5/541 ,  C08L23/00 ,  C08L45/00

Abstract: PROBLEM TO BE SOLVED: To provide a cycloolefinic copolymer which is crosslinkable and capable of giving excellent properties in heat resistance, transparency, chemical resistance, solvent resistance, bonding and adhesion, its composite material, these erosslinked materials and optical materials using them. SOLUTION: The cycloolefinic copolymer obtained by addition polymerization of a cycloolefin having specific crosslinkable functional groups and other cycloolefins, providing the weight average molecular weight of 3,000-1,500,000, the composite material prepared by compounding this copolymer with a specific metal oxide, these crosslinked materials and the optical materials using them are obtained.

公开(公告)号：JP2002284820A

公开(公告)日：2002-10-03

申请号：JP2001084644

申请日：2001-03-23

Applicant: JSR CORP

Inventor： SAKABE NOBUYUKI ,  IMAMURA TAKASHI ,  OSHIMA NOBORU

IPC: C08F4/80 ,  C08F4/70 ,  C08F6/08 ,  C08F32/00

Abstract: PROBLEM TO BE SOLVED: To efficiently eliminate the catalyst from a cycloolefin addition (co)polymer prepared by the addition polymerization of a specific cycloolefin compound in the presence of an addition polymerization catalyst containing a nickel or cobalt compound. SOLUTION: A specific cycloolefin compound alone or together with an α-olefin monomer copolymerizable therewith is subjected to addition polymerization in the presence of an addition polymerization catalyst containing a nickel compound and/or a cobalt compound to give a cyeloolefin addition (co)polymer having a glass transition point higher than of 200 deg.C. A solution of the (co)polymer is treated with an organic acid and water and then, if necessary, with a 1-12C alcohol compound; then, the catalyst component is removed by transferring it from the solution to an aqueous solution (aqueous phase).

公开(公告)号：JP2002226661A

公开(公告)日：2002-08-14

申请号：JP2001021743

申请日：2001-01-30

Applicant: JSR CORP

Inventor： SAWADA KATSUTOSHI ,  OSHIMA NOBORU ,  MARUYAMA YOICHIRO

IPC: C08J3/24 ,  C08K3/22 ,  C08K3/36 ,  C08K5/05 ,  C08K5/09 ,  C08K5/5415 ,  C08K5/57 ,  C08L45/00 ,  C08L65/00 ,  C08L83/00

Abstract: PROBLEM TO BE SOLVED: To provide a cyclic olefinic polymer or its composition having an alkoxysilane functional group, excellent in heat resistance, optical properties, solvent resistance, adhesive properties to metals and inorganic materials, and suitable as an optical material, a coating agent and a binder, and to provide a crosslinked object of the same obtained by forming a siloxane linkage. SOLUTION: The cyclic olefinic polymer composition is obtained by formulating a specific tin compound to a cyclic olefinic polymer having an alkoxysilane functional group or to a composition including the cyclic olefinic polymer. The crosslinked object and the method of producing the same comprise using the composition and crosslinking it by forming a siloxane linkage.

公开(公告)号：JP2002114826A

公开(公告)日：2002-04-16

申请号：JP2000305148

申请日：2000-10-04

Applicant: JSR CORP

Inventor： OSHIMA NOBORU ,  MARUYAMA YOICHIRO ,  OKITA KENZO ,  SAWADA KATSUTOSHI

IPC: G02F1/1333 ,  C08F232/00 ,  C08K3/00 ,  C08K3/22 ,  C08K3/36 ,  C08K5/00 ,  C08L45/00

Abstract: PROBLEM TO BE SOLVED: To provide a optically transparent, heat-resistant, adhesive and crosslinkable optical material having excellent solvent resistance and provide a liquid crystal display substrate material produced by using the optical material. SOLUTION: The optically transparent material contains a cycloolefin copolymer containing (a) a repeating unit derived from a specific cycloolefin and (b) a repeating unit having an alkoxysilyl group or aryloxysilyl group derived from specific other cycloolefin or hydrolyzed condensed residue of the above groups and the liquid crystal display substrate material contains the optically transparent material. Preferably, the repeating unit (a) contains a specific amount of a repeating unit having a norbornene substituted with a 3-8C alkyl group as a structural unit and/or a specific amount of a repeating unit containing ester group or imide group as at least one of the substituent group of the cycloolefin. The ratio of the repeating unit (a) to (b) is preferably within a specific range.

公开(公告)号：JP2001181335A

公开(公告)日：2001-07-03

申请号：JP36762699

申请日：1999-12-24

Applicant: JSR CORP

Inventor： OSHIMA NOBORU ,  KATO HITOSHI

IPC: C08F36/06 ,  C08F4/70

Abstract: PROBLEM TO BE SOLVED: To provide a production method whereby high-melting-point crystalline 1,2-polybutadiene can be produced even at a high polymerization temperature. SOLUTION: In a method for producing crystalline 1,2-polybutadiene by conducting polymerization in the presence of a catalyst comprising a cobalt complex, an organoaluminumoxy compound, and an organoaluminum compound, the organoaluminumoxy compound is a modified one containing toluene- insolubles.

公开(公告)号：JP2010043268A

公开(公告)日：2010-02-25

申请号：JP2009210338

申请日：2009-09-11

Applicant: Jsr Corp ,  Jsr株式会社

Inventor： OSHIMA NOBORU ,  EHATA SATOSHI ,  OKITA KENZO ,  SAKABE NOBUYUKI ,  HAYASHI TOSHIHITO

IPC: C08F232/08 ,  C08F4/70 ,  C08K5/42 ,  C08K5/524 ,  C08L45/00

Abstract: PROBLEM TO BE SOLVED: To provide an additive copolymer of norbornene (bicyclo[2.2.1]hept-2-ene) and a cyclic olefin-based compound, which is excellent in heat resistance, transparency, adhesion or close fitting property to other members, low in linear expansion coefficient related to dimensional stability, and uniformly soluble to a general solvent to form a transparent solution. SOLUTION: The cyclic olefin-based additive copolymer includes 70-98 mol% of a specific structural unit (a) derived from norbornene; and 2-20 mol% of a specific structural unit (b) derived from a cyclic olefin-based compound containing silicon atom, in the total structural unit, and has a number-average molecular weight of 30,000-300,000. When the copolymer is dissolved in toluene or cyclohexane at 10 wt.% concentration at 25°C, the insoluble content is 0.1 wt.% or less, and the transmittance at wavelength 400 nm of the toluene or cyclohexane solution is 85% or more based on measurement by a quartz cell with optical path length of 1 cm. COPYRIGHT: (C)2010,JPO&INPIT

Abstract translation: 要解决的问题：提供降冰片烯（双环[2.2.1]庚-2-烯）和环烯烃系化合物的添加剂共聚物，其耐热性，透明性，粘合性或密合性优异 对其他成员，与尺寸稳定性有关的线性膨胀系数低，并且均匀溶于一般溶剂以形成透明溶液。 解决方案：环状烯烃类添加剂共聚物包含70-98mol％的衍生自降冰片烯的特定结构单元（a）; 和2-20摩尔％的衍生自含有硅原子的环状烯烃系化合物的特定结构单元（b）的总结构单元，数均分子量为30,000〜300,000。 当共聚物在25℃下以10重量％的浓度溶解在甲苯或环己烷中时，不溶成分为0.1重量％以下，甲苯或环己烷溶液的波长400nm的透射率为85％以上 通过光程长度为1cm的石英池进行测量。 版权所有（C）2010，JPO＆INPIT

公开(公告)号：JP2008045133A

公开(公告)日：2008-02-28

申请号：JP2007225060

申请日：2007-08-31

Applicant: Jsr Corp ,  Jsr株式会社

Inventor： KANAMORI TARO ,  KAWAHARA KOJI ,  HASHIGUCHI YUICHI ,  MARUYAMA YOICHIRO ,  OSHIMA NOBORU

IPC: C08J5/18 ,  C08F8/12 ,  C08F232/00 ,  C08F232/08 ,  C08J7/00 ,  C08K3/22 ,  C08K5/5415 ,  C08L45/00 ,  G02B1/04 ,  G02B1/10 ,  G02B1/11 ,  G02B1/115 ,  G02B5/02 ,  G02B5/30 ,  H01B5/14 ,  H01L51/50 ,  H05B33/02 ,  H05B33/04 ,  H05B33/14

Abstract: PROBLEM TO BE SOLVED: To provide a crosslinked resin film having an optical transparency, heat resistance, liquid crystal resistance, dimensional stability and adhesion which can be used as a substitute of a substrate glass in a liquid crystal display device and EL display device or a polarization film, surface protective film, retardation film, transparent conductive film, light diffusion film, film for EL display device, antireflection film or the like in these devices. SOLUTION: The film is obtained by molding a composition which contains a cyclic olefin addition type copolymer having a specific reactive silyl group, and if necessary, the organosilanes and metal oxides or the like, and then crosslinking the film with siloxane bond. COPYRIGHT: (C)2008,JPO&INPIT

Abstract translation: 解决的问题：提供一种可用作液晶显示装置和EL显示器中的基板玻璃的替代物的光学透明性，耐热性，耐液晶性，尺寸稳定性和粘附性的交联树脂膜 这些器件中的器件或偏振膜，表面保护膜，延迟膜，透明导电膜，光扩散膜，EL显示器件用膜，抗反射膜等。 解决方案：通过模制含有具有特定活性甲硅烷基的环状烯烃加成型共聚物，如有必要，有机硅烷和金属氧化物等，然后用硅氧烷键交联该膜的组合物，获得该膜。 版权所有（C）2008，JPO＆INPIT

公开(公告)号：JP2007197603A

公开(公告)日：2007-08-09

申请号：JP2006019021

申请日：2006-01-27

Applicant: Jsr Corp ,  Jsr株式会社

Inventor： OSHIMA NOBORU ,  MARUYAMA YOICHIRO ,  OKITA KENZO ,  TSUBOUCHI TAKASHI ,  IMAMURA TAKASHI

IPC: C08F32/04 ,  C08F4/70 ,  C08J5/18

Abstract: PROBLEM TO BE SOLVED: To provide a norbornene-based addition copolymer having excellent heat resistance, being excellent in transparency and toughness, melt-moldable and suitably used as an optical material; a process for producing the addition copolymer; and a film or sheet prepared by molding the addition copolymer. SOLUTION: The norbornene-based addition copolymer of the invention has a structural unit derived from bicyclo[2.2.1]hepta-2-ene and a structural unit derived from bicyclo[2.2.1]hepta-2-ene having a ≥6C alkyl substituent at a specific proportion. In a wide angle X-ray scattering (WAXS) pattern for the addition copolymer, 2θ of a lower angle peak of the measured two peaks is 10° or greater. COPYRIGHT: (C)2007,JPO&INPIT

Abstract translation: 要解决的问题：提供具有优异的耐热性，透明性和韧性优异的可降冰片烯类加成共聚物，可熔融模塑并适合用作光学材料; 一种生产加成共聚物的方法; 以及通过模制加成共聚物制备的薄膜或薄片。 解决方案：本发明的降冰片烯基加成共聚物具有衍生自双环[2.2.1]七-2-烯的结构单元和衍生自双环[2.2.1]庚-2-烯的结构单元，其具有 ≥6C烷基取代基。 在加成共聚物的广角X射线散射（WAXS）图案中，测得的两个峰的较低角度峰的2θ为10°或更大。 版权所有（C）2007，JPO＆INPIT

公开(公告)号：JP2006328174A

公开(公告)日：2006-12-07

申请号：JP2005152161

申请日：2005-05-25

Applicant: Jsr Corp ,  Jsr株式会社

Inventor： SAWADA KATSUTOSHI ,  OSHIMA NOBORU ,  TSUBOUCHI TAKASHI

IPC: C08L45/00 ,  C08K5/521

Abstract: PROBLEM TO BE SOLVED: To provide a cyclic olefin resin composition that retains desirable transparency, heat resistance and mechanical properties inherent in a specific cyclic olefin addition (co)polymer and exhibits excellent flame retardancy by compounding the cyclic olefin addition (co)polymer and a specific flame-retardant into a composite.
SOLUTION: The cyclic olefin resin composition comprises 100 pts.wt. of the cyclic olefin addition (co)polymer [I] obtained by addition polymerization of a monomer containing the specific cyclic olefin compound and 2-40 pts.wt. of the specific condensed phosphate ester compound [II].
COPYRIGHT: (C)2007,JPO&INPIT

Abstract translation: 要解决的问题：提供一种环状烯烃树脂组合物，其保持特定的环烯烃加成（共）聚合物中固有的期望的透明度，耐热性和机械性能，并且通过将环烯烃添加（共） 聚合物和具有特定阻燃性的复合材料。 解决方案：环烯烃树脂组合物包含100重量份 的通过含有特定的环状烯烃化合物的单体和2-40重量份的加成聚合获得的环烯烃加成（共）聚合物[I] 的特定缩合磷酸酯化合物[II]。 版权所有（C）2007，JPO＆INPIT

公开(公告)号：JP2006321912A

公开(公告)日：2006-11-30

申请号：JP2005146595

申请日：2005-05-19

Applicant: JSR CORP

Inventor： OSHIMA NOBORU ,  IMAMURA TAKASHI ,  OKITA KENZO

IPC: C08F4/70 ,  C08F32/00

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing a cycloolefin-based addition polymer, capable of producing at a high yield the cycloolefin-based addition polymer having little remaining catalyst amount in the polymer and weight-average molecular weight controlled in the range of 50,000-500,000, easy in molding a film or sheet by a solution casting method using an aromatic hydrocarbon solvent, excellent in heat resistance and optical properties. SOLUTION: The method for producing a cycloolefin-based addition polymer comprises addition polymerization of monomers comprising at least one cycloolefin-based compound to produce a cycloolefin-based addition polymer having 50,000-500,000 weight-average molecular weight in the presence of a multicomponent catalyst comprising a specific palladium compound, a phosphine compound and an ionic boron compound or ionic aluminium compound, and a compound having a cyclopentene ring. COPYRIGHT: (C)2007,JPO&INPIT