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公开(公告)号:FR2840615A1
公开(公告)日:2003-12-12
申请号:FR0207085
申请日:2002-06-10
Applicant: OREAL
Inventor: FERRARI VERONIQUE , RICHARD HERVE , MONDET JEAN
Abstract: New polymer (I) comprises at least two polyorganosiloxane blocks, at least one of which has at least two hydrogen-bonding groups and at least one of which has at least one solar filter or antiradical group, is new. (I) is soluble in a silicone oil at 25-250degreesC and is capable of gelling the silicone oil. New polymer (I) comprises at least two motifs, each containing at least one polyorganosiloxane radical comprising 1-1000 siloxane units in the main chain or as a graft, where: (a) at least one motif comprises at least two hydrogen-bonding groups selected from ester, amide, sulfonamide, carbamate, thiocarbamate, urea, thiourea, oxamido, guanidino and biguanidino groups, provided that at least two groups are not ester groups; and (b) at least one motif comprises at least one group capable of acting as a solar filter or antiradical agent covalently bonded in the polymer chain and/or laterally and/or terminally; provided that the hydrogen bonding groups are not exclusively oxamido groups when the solar filter group is an oxamide group. (I) is soluble in a silicone oil at 25-250degreesC and is capable of gelling the silicone oil. Independent claims are also included for: (1) cosmetic or dermatological composition comprising an oil phase containing a silicone oil gelled with (I); (2) cosmetic treatment to protect the skin and natural or sensitized hair against UV radiation by applying a cosmetic composition containing (I); (3) protecting a cosmetic composition containing a light-sensitive ingredient against UV radiation by incorporating 0.25-3 wt.% (I) into the composition.
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公开(公告)号:DE60003452D1
公开(公告)日:2003-07-24
申请号:DE60003452
申请日:2000-09-29
Applicant: OREAL
Inventor: XU JINZHU , RICHARD HERVE
IPC: A61K8/55 , A61K8/00 , A61K8/58 , A61K8/63 , A61K8/895 , A61K31/695 , A61P17/16 , A61P39/06 , A61Q1/00 , A61Q1/02 , A61Q1/04 , A61Q1/10 , A61Q1/12 , A61Q5/00 , A61Q5/02 , A61Q5/12 , A61Q17/04 , A61Q19/00 , A61Q19/08 , C07F7/08 , C07F7/21 , C08G77/38 , A61K7/42
Abstract: The invention concerns novel silicon compounds derived from ascorbic acid consisting of a silicon-containing chain or of silanes, comprising at least a radical A of formula (I) wherein: at least one of the radicals L is a divalent radical for fixing A on the silicon chain. The invention further concerns methods for preparing said compounds, compositions, in particular cosmetic or pharmaceutical, containing them, and their use as antioxidant and/or anti-free radical agent, particularly for treating oxidant stress, for treating the effects of exposure to the sun and for preventing ageing.
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公开(公告)号:DE60001677D1
公开(公告)日:2003-04-24
申请号:DE60001677
申请日:2000-02-03
Applicant: OREAL
Inventor: RICHARD HERVE , LUPPI BERNADETTE
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公开(公告)号:FR2830188A1
公开(公告)日:2003-04-04
申请号:FR0112523
申请日:2001-09-28
Applicant: OREAL
Inventor: RICHARD HERVE
IPC: A61K8/00 , A61K8/20 , A61K8/22 , A61K8/33 , A61K8/40 , A61K8/41 , A61K8/42 , A61K8/49 , A61K8/58 , A61K8/66 , A61Q5/10 , C07F7/08 , D06P3/08 , A61K7/13
Abstract: Silylated p-phenylenediamine or p-aminophenol derivatives (I) are new. Compounds of formula (I) and their salts are new: A = OH or NH2; R1, R2 = H, 1-8C alkyl, 1-6C hydroxyalkyl or YB, or NR1R2 is a 4- to 7-membered heterocycle optionally substituted with 1-3C alkyl, OH, NH2 or ZB; R3, R4 = H, 1-4C alkyl, 1-4C alkoxy, halo or ZB; Y = a 1-8C (un)saturated hydrocarbon chain optionally interrupted with O, S or NR; Z = Y, OY or (NR)Y; R = H or 1-4C alkyl; B = SiR5R6R7; R5-R7 = 1-4C alkyl or phenyl; provided that R1 and R2 are H when A is OH and that at least one of R1-R4 is YB or ZB. Independent claims are also included for: (1) an oxidation dye composition comprising a developer of formula (I); (2) a method for dyeing keratinic fibers, comprising applying the composition of (1) and developing the color with an oxidizing agent; (3) a kit comprising a compartment containing the composition of (1) and a compartment containing an oxidizing composition; (4) a colored product produced by oxidizing the composition of (1).
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公开(公告)号:FR2827510A1
公开(公告)日:2003-01-24
申请号:FR0109634
申请日:2001-07-18
Applicant: OREAL
Inventor: RICHARD HERVE
IPC: C07D453/02 , A61K8/00 , A61K8/04 , A61K8/29 , A61K8/33 , A61K8/35 , A61K8/37 , A61K8/46 , A61K8/49 , A61K8/58 , A61Q1/00 , A61Q5/00 , A61Q17/04 , C07C49/67 , C07C49/675 , C07C311/13 , C07F7/08 , C09K3/00 , A61K7/42 , A61K7/02
Abstract: New insoluble aryl vinylene ketone type UV radiation filtering compounds of two specified formulae are presented in the form of particles with average size 10 nm to 5 micro m, and used to protect a material sensitive to UV radiation, in particular solar radiation or to prepare medicaments designed to prevent the adverse effect of UV radiation. New insoluble aryl vinylene ketone type UV radiation filtering compounds are of formula (I) or (II), and are presented in the form of particles with average size 10 nm to 5 micro m. n = 1, 2; A in (I) and (II), when n is 1 = formulae (a)-(d); A in (I), when n is 2 = formulae (e)-(h); R4 = OH, halogen, 1-6C alkyl or alkoxy optionally containing a silicon atom, 1-5C alkoxycarbonyl, 1-6C alkylsulfonamide optionally containing a silicon atom, aminoacid; R1 = H, OH; R2 = H, 1-6C alkyl optionally containing a silicon atom, cyano, 1-6C alkylsulfonyl, phenylsulfonyl; R3 = 1-6C alkyl optionally containing a silicon atom, phenyl capable of forming a bicycle and optionally substituted by one or two R4, with R2 a 2-10C mono- bi- or tricyclic hydrocarbon residue optionally interrupted by one or more nitrogen or oxygen or sulfur atoms and capable of containing another carbonyl and optionally substituted with a 1-8C alkylsulfonamide optionally containing a silicon atom or an aminoacid; p = 0-4; q = 0, 1; when n is 1 R2 and R3 do not form a camphor nucleus. Independent claims are included for a non-therapeutic method of protecting the skin or hair against UV radiation by applying the claimed composition or a claimed compound and for a non-therapeutic procedure for controlling variation in the color of the skin caused by UV radiation by applying the claimed composition or a claimed compound.
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66.
公开(公告)号:FR2816842A1
公开(公告)日:2002-05-24
申请号:FR0014897
申请日:2000-11-17
Applicant: OREAL
Inventor: RICHARD HERVE , CANDAU DIDIER , FORESTIER SERGE
Abstract: Insoluble organic particulate compound gives good protection against UV-A and UV-B radiation. Insoluble organic particulate compounds of size 10 nm - 5 mu is of formulas (I), (II) and (III). Y = O, S or NR2; Z = N or CH; R1 = OH, halo, 1-8C alkyl or alkoxy; m = 0-2; n = 1-4; p and q = 0 or 1; R2 = H, benzyl or 1-8C alkyl; A = group (a)-(o); R3 = halo, OH or 1-4C alkyl; R4 = H, 1-4C alkyl; c = 0-4; d = 0-3; e = 0, 1; and f = 0-2. An Independent claim is included for compositions comprising these compounds.
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公开(公告)号:FR2780975B1
公开(公告)日:2002-02-15
申请号:FR9808937
申请日:1998-07-10
Applicant: OREAL
Inventor: RICHARD HERVE , FORESTIER SERGE
IPC: A61K8/00 , A61K8/04 , A61K8/35 , A61K8/58 , A61K8/89 , A61K8/891 , A61K8/893 , A61K8/896 , A61Q1/00 , A61Q1/04 , A61Q1/06 , A61Q1/10 , A61Q1/12 , A61Q5/00 , A61Q5/02 , A61Q5/04 , A61Q5/08 , A61Q5/10 , A61Q17/04 , C07C45/86 , C07C49/84 , C07F7/08 , C07F7/21 , C08G77/14 , C08L83/07 , C08L83/08 , C09K3/00 , A61K7/42
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公开(公告)号:CA2010161C
公开(公告)日:2002-01-01
申请号:CA2010161
申请日:1990-02-15
Applicant: OREAL
Inventor: FORESTIER SERGE , LANG GERARD , RICHARD HERVE
IPC: A61K8/55 , A61K8/00 , A61K8/34 , A61K8/37 , A61K8/58 , A61K8/72 , A61K8/89 , A61K8/891 , A61K8/893 , A61K8/92 , A61Q1/00 , A61Q5/00 , A61Q5/02 , A61Q5/10 , A61Q17/04 , C07F7/08 , C08G77/14 , C08G77/22 , C08G77/38 , C08L83/04 , C08L83/06 , C08L83/08 , A61K7/075
Abstract: L'invention concerne l'utilisation en cosmétique de diorganopolysiloxanes à fonction benzal- malonate choisis dans le groupe constitué par (a) les composés de formule: (voir formule I) dans laquelle les symboles R, identiques ou différents, désignent des radicaux alkyle en C1-C10, phényle ou trifluoro-3,3,3 propyle, au moins 80% en nombre des radicaux R étant des radicaux méthyle, B, identiques ou différents, désignent les radicaux R ou le radical A, le symbole A étant un radical de formule: (voir formule II) dans laquelle R1 et R2 représentent un atome d'hydrogène, un radical hydroxyle, un radical trimétylsiloxy, un radical alkyle en C1-C6, un radical alcoxy en C1-C6 ou un groupement divalent Y de formule: (voir formule III) dans laquelle n est 0 ou 1, p est un nombre entier compris entre 1 et 10 inclus et R4 représente un atome d'hydrogène ou un radical alkyle en C1-C4, l'un des deux radicaux R1 et R2 représentant nécessairement le groupement Y, R3 représente un atome d'hydrogène, un radical alkyle en C1-C6 ou un radical alcoxy en C1-C6, r est un nombre choisi entre 0 et 200 inclusivement, s est un nombre choisi entre 0 et 50 inclusivement et si s est 0, au moins l'un dés deux symboles B désigne A; et (b) les composés de formule: ~ dans laquelle R et A ont les significations précitées, u est un nombre compris entre 1 et 20 inclus, et t est un nombre compris entre 0 et 20 inclus, t + u étant égal ou supérieur à 3. Les composés de formules (I) et (II) sont utiles notamment en tant qu'agents filtrant le rayonnement UV de longueurs d'onde comprises entre 280 et 360 nm.
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公开(公告)号:CA2388313A1
公开(公告)日:2001-05-03
申请号:CA2388313
申请日:2000-09-29
Applicant: OREAL
Inventor: RICHARD HERVE , XU JINZHU
IPC: A61K8/55 , A61K8/00 , A61K8/58 , A61K8/63 , A61K8/895 , A61K31/695 , A61P17/16 , A61P39/06 , A61Q1/00 , A61Q1/02 , A61Q1/04 , A61Q1/10 , A61Q1/12 , A61Q5/00 , A61Q5/02 , A61Q5/12 , A61Q17/04 , A61Q19/00 , A61Q19/08 , C07F7/08 , C07F7/21 , C08G77/38 , A61K7/42
Abstract: L'invention concerne des nouveaux composés siliciés dérivés de l'acide ascorbique, constitués d'une chaîne siliconée ou étant des silanes, comporta nt au moins un radical A de formule (I) dans laquelle au moins un des radicaux L est un radical divalent permettant l'accrochage de A sur la chaîne siliciée. L'invention concerne également des procédés pour la préparation de ces composés, les compositions notamment cosmétiques ou pharmaceutiques les comprenant, et leur utilisation en tant qu'agent antioxydant et/ou agent ant i- radicaux libres, en particulier pour traiter le stress oxydant, traiter les effets de l'exposition au soleil et prévenir le vieillissement.
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公开(公告)号:ES2146071T3
公开(公告)日:2000-07-16
申请号:ES97402316
申请日:1997-10-02
Applicant: OREAL
Inventor: LEDUC MADELEINE , RICHARD HERVE , LAGRANGE ALAIN
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