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公开(公告)号:CA2869516A1
公开(公告)日:2013-10-17
申请号:CA2869516
申请日:2013-04-12
Applicant: STORA ENSO OYJ
Inventor: HARLIN ALI , AALTONEN OLLI , LAITINEN ANTERO , RASANEN JARI , KYLLIAINEN OUTI
Abstract: The invention relates to a method of deoxygenation of tall oil as well as methods for the production of aliphatic hydrocarbons and polymerizable monomers from tall oil. Sulphurous crude tall oil (5) together with hydrogen gas (6) is fed into a reactor (1) comprising a catalyst bed (2, 3). The oil is catalytically deoxygenated by hydrogen in the bed by use of a sulfided metal catalyst, e.g. a Ni-MoS catalyst. The flow exiting the reactor is cooled down and a hydrocarbon-bearing liquid phase (10) is separated from a gas phase (18), followed by subjecting the liquid phase to distillation (14) for removal of useless aromatic hydrocarbons and then to steam cracking (4) to form a product containing olefins such as ethylene or propylene. By regulation of the deoxygenation temperature to be at least 270°C but less than 360°C the yield is rich in linear and cyclic aliphates that usefully turn to olefins in the steam cracking, while formation of napthalenes is reduced.
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公开(公告)号:ZA201200327B
公开(公告)日:2012-09-26
申请号:ZA201200327
申请日:2012-01-16
Applicant: STORA ENSO OYJ
Inventor: VEHVILAINEN MARIANNA , PELTOLA MAARIT , NOUSIAINEN PERTTI , KAMPPURI TAINA , HARLIN ALI
IPC: D21C20060101 , D21H20060101
Abstract: A process for treating cellulosic fibers comprises mechanically pre-treating the fibers followed by treating the fibers with an enzyme and thereafter mixing the fibers with a solution comprising an alkali metal hydroxide followed by mechanically treating the fibers to form microfibrillated cellulose. In this way it is possible to produce microfibrillated cellulose (MFC) in an improved and energy efficient way.
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公开(公告)号:CL2011001711A1
公开(公告)日:2012-03-16
申请号:CL2011001711
申请日:2011-07-14
Applicant: STORA ENSO OYJ
Inventor: PENTTINEN TAPANI , RÄSÄNEN JARI , AALTONEN OLLI , HARLIN ALI
Abstract: SE DESCRIBE UN MÉTODO PARA PRODUCIR MONÓMEROS OLEFÍRTICOS PARA LA PRODUCCIÓN DE UN POLÍMERO, QUE COMPRENDE LAS SIGUIENTES ETAPAS: - SE INTRODUCE BIOACEITE, CON UN CONTENIDO DE 95% A 98% EN PESO DE ÁCIDOS GRASOS DE ACEITE DE RESIRIA Y 2% A 5% EN PESO DE ÁCIDOS RESINOSOS DE ACEITE DE RESMA, E HIDRÓGENO GASEOSO EN EL LECHO DE CATALIZADOR (7); - EL ACEITE SE DESOXIGENA EN FORMA CATALÍTICA EN EL LECHO MEDIANTE LA APLICACIÓN DE HIDRÓGENO (7); - EL FLUJO DE SALIDA DEL LECHO (7) SE ENFRÍA Y DIVIDE EN UNA FASE LÍQUIDA QUE CONTIENE HIDROCARBUROS (10) Y UNA FASE GASEOSA; Y - EL LÍQUIDO QUE CONTIENE HIDROCARBUROS (13) SE SOMETE A UNA DESINTEGRACIÓN EN VAPOR (4) A FIN DE OBTENER UN PRODUCTO QUE CONTENGA OLEFINAS POLIMERIZANTES.
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公开(公告)号:SE533510C2
公开(公告)日:2010-10-12
申请号:SE0950534
申请日:2009-07-07
Applicant: STORA ENSO OYJ
Inventor: VEHVILAEINEN MARIANNA , KAMPPURI TAINA , PELTOLA MAARIT , HARLIN ALI , NOUSIAINEN PERTTI
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公开(公告)号:FI20095291A
公开(公告)日:2010-09-21
申请号:FI20095291
申请日:2009-03-20
Applicant: STORA ENSO OYJ
Inventor: RAESAENEN JARI , PENTTINEN TAPANI , HARLIN ALI , HILTUNEN JAAKKO , WIKBERG HANNE , TAMMELIN TEKLA
IPC: C08B20100101
Abstract: The invention relates to a method of treating chemical pulp fibers by a polymerizing hydroxy acid, the fibers thus obtained and the products refined from them. In the method, the hydroxy acid reacts with the reactive groups of the fibers in the presence of a catalyst, forming ester bonds. The following units of the same hydroxy acid are oligomerized and/or polymerized to these grafted acid residues. The fibers thus treated and the products refined thereof endure better processing stages that include drawing and stretching than untreated fibers.
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公开(公告)号:FI20095079A0
公开(公告)日:2009-01-29
申请号:FI20095079
申请日:2009-01-29
Applicant: STORA ENSO OYJ , VALTION TEKNILLINEN
Inventor: HARLIN ALI , PENTTINEN TAPANI , RAESAENEN JARI , AALTONEN OLLI
Abstract: The invention relates to a method of producing olefinic monomers for the production of a polymer. The invention particularly relates to the production of tall oil-based biopolymers, such as polyolefins. In the stages of the method bio oil, with a content of over 50% of fatty acids of tall oil and no more than 25% of resin acids of tall oil, and hydrogen gas are fed into a catalyst bed (7); the oil is catalytically deoxygenated in the bed by hydrogen; the flow exiting the bed is cooled down and divided into a hydrocarbon-bearing liquid phase (10) and a gas phase; and the hydrocarbon-bearing liquid (13) is subjected to steam cracking (4) to provide a product containing polymerizing olefins. The deoxygenation in the bed can be followed by a catalytic cracking or, with a suitable catalyst, the deoxygenation and cracking can be simultaneous. The separated hydrogen-bearing gas phase can be circulated in the process.
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公开(公告)号:FI20050225A
公开(公告)日:2006-08-26
申请号:FI20050225
申请日:2005-02-25
Applicant: STORA ENSO OYJ
Inventor: BACKFOLK KAJ , HEISKANEN ISTO , NEVALAINEN KIMMO , PENTTINEN TAPANI , PELTOLA MINNA , HARLIN ALI
Abstract: The invention relates to a method for priming a substrate by contacting the substrate with a primer fed from a primer source and depositing the primer on the substrate. Compared to other priming methods, the claimed priming gives better results because the deposition is carried out electrostatically.
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公开(公告)号:BRPI0908200B1
公开(公告)日:2021-09-08
申请号:BRPI0908200
申请日:2009-02-26
Applicant: STORA ENSO OYJ
Inventor: HARLIN ALI , HEISKANEN ISTO , BACKFOLK KAJ
Abstract: método para produzir partículas eletrostaticamente. a invenção se refere a um método para formar gotículas ou partículas de pelo menos uma substância compreendendo as etapas de provisão de um meio espumado, cujo meio espumado compreende dita substância, e formação de gotículas ou partículas de dita substância pelo menos parcialmente por processamento eletrostático. o uso de meio espumado em processamento eletrostático permite mais altas velocidades de produção e aumenta a uniformidade de uma camada de cobertura formada por eletrofiação ou eletronebulização das gotículas ou partículas sobre um substrato.
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公开(公告)号:CA2869516C
公开(公告)日:2020-09-15
申请号:CA2869516
申请日:2013-04-12
Applicant: STORA ENSO OYJ
Inventor: HARLIN ALI , AALTONEN OLLI , LAITINEN ANTERO , RASANEN JARI , KYLLIAINEN OUTI
Abstract: The invention relates to a method of deoxygenation of tall oil as well as methods for the production of aliphatic hydrocarbons and polymerizable monomers from tall oil. Sulphurous crude tall oil (5) together with hydrogen gas (6) is fed into a reactor (1) comprising a catalyst bed (2, 3). The oil is catalytically deoxygenated by hydrogen in the bed by use of a sulfided metal catalyst, e.g. a Ni-MoS catalyst. The flow exiting the reactor is cooled down and a hydrocarbon-bearing liquid phase (10) is separated from a gas phase (18), followed by subjecting the liquid phase to distillation (14) for removal of useless aromatic hydrocarbons and then to steam cracking (4) to form a product containing olefins such as ethylene or propylene. By regulation of the deoxygenation temperature to be at least 270°C but less than 360°C the yield is rich in linear and cyclic aliphates that usefully turn to olefins in the steam cracking, while formation of napthalenes is reduced.
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70.
公开(公告)号:BR112014025308B1
公开(公告)日:2020-02-04
申请号:BR112014025308
申请日:2013-04-12
Applicant: STORA ENSO OYJ
Inventor: AALTONEN OLLI , HARLIN ALI , KYLLIÄINE OUTI , LAITINEN ANTERO , RÄSÄNEM JARI
Abstract: métodos de desoxigenação de óleo de tall e produção de monómeros polimerizáveis a partir deste a invenção refere-se a um método de desoxigenação de óleo de tal, bem como a métodos para a produção de hidrocarbonetos alifáticos e monómeros polimerizáveis a partir de óleo de tall. óleo de tall bruto sulfuroso (5) juntamente com gás hidrogênio (6) é alimentado a um reator (1) compreendendo um leito catalisador (2, 3). 0 óleo é desoxigenado cataliticamente por hidrogênio no leito pelo uso de um catalisador metálico sulfetado, por exemplo, um catalisador de nimos. 0 fluxo que sai do reator é resfriado e uma fase líquida contendo hidrocarboneto (10) é separada de uma fase gasosa (18), a seguir a fase líquida é submetida a destilação (14) para a remoção de hidrocarbonetos aromáticos inúteis e então a craqueamento por vapor (4) para formar um produto contendo olefinas tais 15 como etileno ou propileno. pela regulação da temperatura de desoxigenação para pelo menos 270°c, mas abaixo de 360°c, o produto é rico em hidrocarbonetos alifáticos lineares ou cíclicos que de maneira útil se convertem em olefinas no craqueamento por vapor, enquanto que a formação de naftalenos é reduzida.
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