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    1.
    发明专利
    未知

    公开(公告)号：FI20095079A0

    公开(公告)日：2009-01-29

    申请号：FI20095079

    申请日：2009-01-29

    Applicant: STORA ENSO OYJ ,  VALTION TEKNILLINEN

    Inventor： HARLIN ALI ,  PENTTINEN TAPANI ,  RAESAENEN JARI ,  AALTONEN OLLI

    Abstract: The invention relates to a method of producing olefinic monomers for the production of a polymer. The invention particularly relates to the production of tall oil-based biopolymers, such as polyolefins. In the stages of the method bio oil, with a content of over 50% of fatty acids of tall oil and no more than 25% of resin acids of tall oil, and hydrogen gas are fed into a catalyst bed (7); the oil is catalytically deoxygenated in the bed by hydrogen; the flow exiting the bed is cooled down and divided into a hydrocarbon-bearing liquid phase (10) and a gas phase; and the hydrocarbon-bearing liquid (13) is subjected to steam cracking (4) to provide a product containing polymerizing olefins. The deoxygenation in the bed can be followed by a catalytic cracking or, with a suitable catalyst, the deoxygenation and cracking can be simultaneous. The separated hydrogen-bearing gas phase can be circulated in the process.

    METHODS OF DEOXYGENATING BIO-BASED MATERIAL AND PRODUCTION OF BIO-BASED TEREPHTALIC ACID AND OLEFINIC MONOMERS
    4.
    发明公开
    METHODS OF DEOXYGENATING BIO-BASED MATERIAL AND PRODUCTION OF BIO-BASED TEREPHTALIC ACID AND OLEFINIC MONOMERS 有权
    生物基材料的方法脱氧和生物基苯二甲酸和烯烃单体的处理

    公开(公告)号：EP2984154A4

    公开(公告)日：2016-11-09

    申请号：EP14782419

    申请日：2014-04-08

    Applicant: STORA ENSO OYJ

    Inventor： RÄSÄNEN JARI ,  HARLIN ALI ,  AALTONEN OLLI ,  LINNEKOSKI JUHA ,  ANTHONYKUTTY JINTO

    IPC: C10G3/00 ,  C07C4/06 ,  C07C51/16 ,  C07C51/265 ,  C08G63/183 ,  C10G9/36

    CPC classification number: C10G3/50 ,  C07C4/06 ,  C07C51/16 ,  C07C51/265 ,  C10G3/46 ,  C10G3/49 ,  C10G9/36 ,  C10G2300/1014 ,  Y02P30/20 ,  C07C63/06

    Abstract: The present invention relates to a method of deoxygenating tall oil pitch, yielding aliphatic and aromatic hydrocarbons. The invention even comprises turning the aliphates into polymerizable olefins by steam cracking, and turning the aromates into polymerizable terephthalic acid by oxygenation and, as necessary, rearrangement. The monomers can be used for the production of polymers of partially or completely biologic origin. According to the invention, tall oil pitch is first heated to turn it into liquid, which is then fed into a catalyst bed and catalytically deoxygenated with hydrogen. The deoxygenation catalyst is preferably a Ni—Mo catalyst and, in addition, a cracking catalyst can be used, such as an acidic zeolite catalyst. The deoxygenated product stream is cooled down so as to obtain a liquid, which is distilled for separation of the aliphatic and aromatic hydrocarbons for use in the production of the respective monomers and finally polymers.

    Abstract translation: 本发明涉及脱氧妥尔油沥青，得到脂肪族和芳香族烃的方法。 本发明什至包括由蒸汽裂化转动脂肪酸盐进入聚合烯烃，和由氧合转动芳香族化合物为聚合性对苯二甲酸和，根据需要，重排。 单体可用于生产部分或完全呼叫生物来源的聚合物的。 。根据本发明，妥尔油沥青首先加热把它变成液体，所有这一切都被送入催化剂床并用氢气催化脱氧。 脱氧催化剂优选是Ni-Mo催化剂，此外，一个裂化催化剂可被使用，如寻求酸性沸石催化剂。 脱氧产物流被冷却，以便获得液体，所有这一切都被蒸馏为脂肪族的分离和芳族烃用于生产单体respectivement的和最后的聚合物。

    TREATMENT OF FIBRES TO ENDURE PROCESSING
    8.
    发明公开
    TREATMENT OF FIBRES TO ENDURE PROCESSING 有权
    百德冯·弗兰德·弗雷尔·赫尔赫特VERARBEITUNGSBESTÄNDIGKEIT

    公开(公告)号：EP2408822A4

    公开(公告)日：2013-11-27

    申请号：EP10753173

    申请日：2010-03-18

    Applicant: STORA ENSO OYJ

    Inventor： RAESAENEN JARI ,  PENTTINEN TAPANI ,  HARLIN ALI ,  HILTUNEN JAAKKO ,  WIKBERG HANNE ,  TAMMELIN TEKLA

    IPC: C08B3/14 ,  C08B3/20 ,  D21H17/14 ,  D21H21/14

    CPC classification number: C08B3/20 ,  C08B3/14 ,  D21H11/20 ,  D21H17/14 ,  D21H21/14 ,  D21H27/10

    Abstract: The invention relates to a method of treating chemical pulp fibers by a polymerizing hydroxy acid, the fibers thus obtained and the products refined from them. In the method, the hydroxy acid reacts with the reactive groups of the fibers in the presence of a catalyst, forming ester bonds. The following units of the same hydroxy acid are oligomerized and/or polymerized to these grafted acid residues. The fibers thus treated and the products refined thereof endure better processing stages that include drawing and stretching than untreated fibers.

    Abstract translation: 本发明涉及一种通过聚合羟基酸处理化学纸浆纤维的方法，由此获得的纤维和从其中精制的产品。 在该方法中，羟基酸在催化剂存在下与纤维的反应性基团反应，形成酯键。 以下单元的相同羟基酸被低聚和/或聚合到这些接枝的酸残基上。 如此处理的纤维和其精制产品具有比未处理的纤维更好的加工阶段，包括拉伸和拉伸。

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