PROCESS FOR MAKING NITRILES
    77.
    发明公开
    PROCESS FOR MAKING NITRILES 有权
    制造硝酸盐的方法

    公开(公告)号:EP2582662A1

    公开(公告)日:2013-04-24

    申请号:EP11740747.8

    申请日:2011-06-16

    CPC classification number: C07C253/10 Y02P20/584 C07C255/04

    Abstract: A hydrocyanation reaction is used to react 1,3-butadiene with hydrogen cyanide in the presence of a catalyst to produce pentenenitrles, as well as reaction byproducts, such as methylglutaronitrile (MGN). The effluent from the hydrocyanation reaction is distilled in a particular manner to produce a pentenenitrile-enriched stream, a catalyst- enriched stream and a stream enriched in methylglutaronitrile (MGN). At least a portion of the catalyst enriched stream may be recycled to the hydrocyanation reaction, 3- pentenenitrile may be recovered and, optionally, further reacted with HCN to make adiponitrile (ADN).

    Abstract translation: 氢氰化反应用于在催化剂存在下使1,3-丁二烯与氰化氢反应生成戊烯腈以及反应副产物如甲基戊二腈(MGN)。 来自氢氰化反应的流出物以特定方式蒸馏以产生富含戊烯腈的物流,富含催化剂的物流和富含甲基戊二腈(MGN)的物流。 至少一部分富含催化剂的物流可以循环到氢氰化反应中,3-戊烯腈可以回收并且任选地与HCN进一步反应以制备己二腈(ADN)。

    PROCESS FOR MAKING NITRILES
    78.
    发明公开
    PROCESS FOR MAKING NITRILES 有权
    制造硝酸盐的方法

    公开(公告)号:EP2574190A1

    公开(公告)日:2013-04-03

    申请号:EP11729809.1

    申请日:2011-06-16

    CPC classification number: C07C253/10 Y02P20/584 C07C255/04

    Abstract: An improved multi-reaction zone process provides for improved nitrile product quality and yield. In a first reaction zone, 1,3-butadiene is reacted with hydrogen cyanide in the presence of a catalyst to produce pentenenitriles comprising 3- pentenenitrile and 2-methyl-3-butenenitrile. In a second reaction zone, 2-methyl-3- butenenitrile, recovered from the first reaction zone, is isomerized to 3-pentenenitrile. In an optional third reaction zone, 3-pentenenitrile recovered from the first and second reaction zones is reacted with hydrogen cyanide in the presence of a catalyst and a Lewis acid to produce adiponitrile. A portion of the first catalyst is purified and recycled. Zero valent nickel is added to the purified first catalyst before it is recycled.

    Abstract translation: 改进的多反应区工艺提供改进的腈产品质量和产量。 在第一反应区中,1,3-丁二烯在催化剂存在下与氰化氢反应,生成包含3-戊烯腈和2-甲基-3-丁烯腈的戊烯腈。 在第二反应区中,将从第一反应区回收的2-甲基-3-丁烯腈异构化为3-戊烯腈。 在任选的第三反应区中,从催化剂和路易斯酸存在下,将从第一和第二反应区回收的3-戊烯腈与氰化氢反应生成己二腈。 第一催化剂的一部分被净化并再循环。 在再循环之前,将零价镍加入纯化的第一催化剂中。

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