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71.发明授权1-아릴-1-(알파-(트리아졸릴)알킬)-1-실라시클로알칸및이들의제조방법 失效1-ARYL-1-£2-（TRIAZOL-1-YL）ALKYL | -1-SILACYCLOALKANE及其制备方法
公开(公告)号：KR1019950011359B1
公开(公告)日：1995-10-02
申请号：KR1019930002239
申请日：1993-02-18
Applicant: 한국과학기술연구원
IPC: C07F7/10
CPC classification number: C07F7/0812
Abstract: 1-Aryl-1-[alpha-triazoly)alkyl -1-silacycloalkane of formula (I) is prepared by reacting 1-aryl-1-[alpha-(chloro)alkyl -1-silacycloalkane of formula (II) and trazol natrium salts in the solvent of dimethylform amide at 15-45 deg.C for 3-8 hrs. In the formulas, R1 is phenyl derivatives having substd. gp. at 4- or 2,4- position; R2 is H or methyl; n is 4 or 5. The obtd cpd. is useful for mycosis of plants.
Abstract translation: 通过使式（II）的1-芳基-1- [α-（氯）烷基-1-硅杂环烷烃）和草酸钠（I）的1-芳基-1- [α-三唑烷基]烷基-1-硅杂环烷烃 二甲基甲酰胺溶剂中的盐在15-45℃下反应3-8小时。 在该式中，R 1是具有取代基的苯基衍生物。 GP。 在4-或2,4-位; R2是H或甲基; n为4或5。 对植物的真菌病有用。
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公开(公告)号：KR1019950006726B1
公开(公告)日：1995-06-21
申请号：KR1019910022586
申请日：1991-12-10
Applicant: 한국과학기술연구원
Abstract: Polycarboxylane of formula (I) is prepared by a thermal redistribution reaction polysilamethylenosilane of formula (II) under the pressure of 1-30 atm. at 350-600≦̸C. In (II), R2 = methyl or phenyl; R3 = methyl or bonds of Si and Si; x, y, z, n and m = constant; parts a, b, and c are dechlorinated dechlorinated 2,4,6-trisilaheptane, dimethylchlorosilane and trichlorosilane, respectively.
Abstract translation: 式（I）的聚羧烷通过式（II）的热重分布反应多亚烷基硅烷在1-30atm的压力下制备。 在350-600＆nlE; C。 在（II）中，R 2 =甲基或苯基; R3 =甲基或Si和Si的键; x，y，z，n和m =常数; 部分a，b和c分别为脱氯脱氯2,4,6-三甲基庚烷，二甲基氯硅烷和三氯硅烷。
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Patent Agency Ranking
公开(公告)号：KR1019950004177B1
公开(公告)日：1995-04-27
申请号：KR1019920016148
申请日：1992-09-04
Applicant: 한국과학기술연구원
IPC: C07F7/12
Abstract: The tris silyl alkkanes of formula (III) and (IV) are prepared by the hydrogen-siliconation reaction of tris silyl alkanes of formula (I) and (II), and an organic compound of formula CH2=CH-R2 having carbon and carbon double bond or an cyclohexene having an unsaturated gp. within the ring in the presence of a catalyst i.e. chloroplatinic acid, silica/platinum, tributyl aminie, Pd, Rh or Ni. In the formules, X is Cl or OR1; R1 is C1-4 alkyl; 22 is phenyl, CH2Cl, CF3, CN, CH2CN, phenyl-CH2Cl or cyclohex-3-enyl. The tris silyl alkanes as a silicon bonding agent is used in the prodn. of plastic complex materials.
Abstract translation: 通过式（I）和（II）的三甲硅烷基烷烃和具有碳和碳的式CH 2 = CH-R 2的有机化合物的氢 - 硅化反应制备式（III）和（IV）的三甲硅烷基烷烃 双键或具有不饱和gp的环己烯。 在催化剂存在下，即氯铂酸，二氧化硅/铂，三丁基氨基，Pd，Rh或Ni。 在配方中，X为Cl或OR1; R1是C1-4烷基; 22是苯基，CH 2 Cl，CF 3，CN，CH 2 CN，苯基-CH 2 Cl或环己-3-烯基。 作为硅键合剂的三甲硅烷基烷烃用于生产。 的塑料复合材料。
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公开(公告)号：KR1019950004175B1
公开(公告)日：1995-04-27
申请号：KR1019920012997
申请日：1992-07-21
Applicant: 한국과학기술연구원
IPC: C07F7/12
Abstract: The tris silyl alkanes of formula (I), (II), (III) and (IV) are prepared by directly reacting a mixture of an organic compound of formula (V) having trichloromethyl gp., and a hydrogen chloride or its generating alkyl chloride of formula R'Cl with a silicon in the presence of copper catalyst at 200˜360 deg.C. The tris silyl alkanes of formula (I), (II), (III) and (IV) have each three dichlorosilyl gps., two dichlorosilyl gps. and one trichlorosilyl gp., one dichlorosilyl gp. and two trichlorosilyl gps., and three trichlorosilyl gps. In the formulas, R is H, methy; R1 is H, C1-4 alkyl or chloroethyl. The tris silyl alkanes is used as a starting material in the prodn. of a silicon compound having an organic functional gp.
Abstract translation: 式（I），（II），（III）和（IV）的三甲硅烷基烷烃通过使具有三氯甲基gp的式（Ⅴ）的有机化合物和氯化氢或其产生的烷基 在铜催化剂存在下，在200〜360℃下，用式R'Cl的氯化物与硅反应。 式（I），（II），（III）和（IV）的三甲硅烷基烷烃具有三个二氯甲硅烷基gps，两个二氯甲硅烷基gps。 和一个三氯甲硅烷基gp，一个二氯甲硅烷基gp。 和两个三氯甲硅烷基gps。 在该式中，R为H，甲基; R1是H，C1-4烷基或氯乙基。 三甲硅烷基烷烃用作产品中的起始原料。 具有有机功能性gp的硅化合物。
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