질소산화물 이용 암모니아 제조방법
    71.
    发明授权
    질소산화물 이용 암모니아 제조방법 有权
    使用氮氧化物的氨氮制造方法

    公开(公告)号:KR101392825B1

    公开(公告)日:2014-05-08

    申请号:KR1020120139545

    申请日:2012-12-04

    CPC classification number: C01C1/08 C01C1/02

    Abstract: Provided is a method for synthesizing ammonia from a nitrogen oxide, which is an air pollutant, and water vapor using a gas separation membrane. The method of the present invention comprises: a step of supplying hydrocarbon based fuel gas, while maintaining the temperature of 500°C to 700°C in a device for producing ammonia in which an inner space is divided into a first space and a second space by a gas separation membrane, which is a border, to allow one side of the gas separation membrane to contact with the first space; a step of supplying water vapor (H_2O) and nitrogen (N_2) gas with the pressure of 1 to 10 atm to allow the other side of the gas separation membrane to contact the second space; a step of obtaining synthesis gas which is a reaction product generated in the first space; and a step of obtaining ammonia which is produced in the second space. The method for producing ammonia of the present invention can produce ammonia from water vapor and nitrogen oxide without electric energy supplied from outside and has an advantage of reforming hydrocarbon based fuel gas at the same time.

    Abstract translation: 提供了从作为空气污染物的氮氧化物和使用气体分离膜的水蒸气合成氨的方法。 本发明的方法包括:在将内部空间分成第一空间和第二空间的生产氨的装置中同时保持500℃至700℃的温度的同时供给烃类燃料气体的步骤 通过作为边界的气体分离膜,允许气体分离膜的一侧与第一空间接触; 以1〜10atm的压力供给水蒸汽(H_2O)和氮(N_2)气体以使气体分离膜的另一侧接触第二空间的步骤; 获得作为在第一空间中产生的反应产物的合成气的步骤; 以及获得在第二空间中产生的氨的步骤。 本发明的氨的制造方法可以从水蒸汽和氮氧化物生成氨,而不从外部供给电能,同时具有重整烃系燃料气体的优点。

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