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公开(公告)号:WO2022112029A1
公开(公告)日:2022-06-02
申请号:PCT/EP2021/081614
申请日:2021-11-15
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: CAVALIERI, Claudio
IPC: C08L23/12
Abstract: The present disclosure relates to polyolefin compositions, in particular polypropylene compositions containing (a) 45 to 90%, of a propylene polymer optionally containing up to 7%wt of ethylene and having a melt flow rate (ISO 1133 230°C/2.16 kg) ranging from 0.5 to 5g/10'; (b) from 10 to 55% of a multicomponent recycled composition containing at least 70 % by weight, of a propylene polymer containing from 1 to 7% by weight of ethylene and from 5 to 30, by weight of a styrenic block copolymer (SBC). The polyolefin compositions according to the present disclosure find application in extrusion, thermoforming and blow molding applications particularly for manufacturing of bottles.
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公开(公告)号:WO2022090104A1
公开(公告)日:2022-05-05
申请号:PCT/EP2021/079446
申请日:2021-10-25
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: CAVALIERI, Claudio , TREOSSI, Mauro , CONSALVI, Marco
Abstract: The present disclosure relates to polyolefin compositions, in particular polypropylene compositions containing (a) recycled polypropylene, (b) a polyolefin elastomer (POE), (c) a specific polypropylene heterophasic composition and (d) a filler that can be used in injection molded articles. The polyolefin compositions according to the present disclosure find application in automotive field, and houseware such as suitcase and containers.
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公开(公告)号:WO2022017757A1
公开(公告)日:2022-01-27
申请号:PCT/EP2021/068169
申请日:2021-07-01
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: CAVALIERI, Claudio , DUREEV, Mikhail , GRAZZI, Michele
IPC: C08L23/14
Abstract: Heterophasic copolymers of propylene with a MFR2 (230°C/2.16 Kg) of from 3.0 to 12.0 g/10 min comprise: (a) from 55 to 75 wt. % of a component (A) being a copolymer of propylene with ethylene or a C4-C10 alpha-olefin, comprising from 0.5 to 2.0 wt. % of ethylene and/or C4-C10 alpha-olefin units and having a MFR2 (230°C/2.16 K g) ranging from 60 to 140 g/10 min; and (b) from 25 to 45 wt. % of a component (B) being a propylene-ethylene copolymer comprising 25 to 45 wt. % of ethylene units and having a value of the intrinsic viscosity of the fraction soluble in xylene at room temperature (XS-IV) ranging from 5 to 9 dl/g.
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公开(公告)号:WO2022002602A1
公开(公告)日:2022-01-06
申请号:PCT/EP2021/066331
申请日:2021-06-17
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: CAVALIERI, Claudio , GALVAN, Monica
IPC: C08L23/12 , C08L2205/03 , C08L2207/10 , C08L2207/20
Abstract: A polypropylene composition comprising (per cent by weight unless otherwise specified): (a) 65 to 85%, of a crystalline propylene polymer having an amount of isotactic pentads (mmmm), measured by 13C-MNR on the fraction insoluble in xylene at 25° C, higher than 97.0 molar% and a polydispersity index ranging from 3 to 15; (b) 5 to 25%, of an elastomeric copolymer of ethylene and propylene, the copolymer having an amount of recurring units deriving from ethylene ranging from 30 to 70%, preferably 35 to 60%, and being partially soluble in xylene at ambient temperature; the polymer fraction soluble in xylene at ambient temperature having an intrinsic viscosity value ranging from 3 to 10 dl/g; and (c) 5 to 25%, of recycled polyethylene (r-PE) having a melt flow rate (190°C/2.16 Kg) from 0.1 to 10 g/10 min, the whole composition having a value of melt flow rate (ISO 1133 230°C/2.16 kg) ranging from higher than 3.0 g/10min to 15 g/10min, the percentages of (a), (b) and (c) being referred to the sum of (a), (b) and (c).
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公开(公告)号:WO2020182435A1
公开(公告)日:2020-09-17
申请号:PCT/EP2020/054420
申请日:2020-02-20
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: CAVALIERI, Claudio , GALVAN, Monica , CIARAFONI, Marco
IPC: C08L23/08 , C08L23/10 , C08F210/16 , C08F110/06 , C08F210/06
Abstract: A polyolefin composition comprising: T1) 50-90 wt%, of a recycled polyolefin mixture; T2) 5-30 wt% of a polyolefin component containing: A) 5-35% by weight of a propylene homopolymer or a propylene ethylene copolymer; B) 25-50% by weight of a copolymer of ethylene and a Cs-Cs alpha-olefin comprising 0.1- 20% by weight of C3-Cs alpha-olefin units; and C) 30-60% by weight of a copolymer of ethylene and propylene comprising 25-75% by weight of ethylene units.
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公开(公告)号:WO2020148106A1
公开(公告)日:2020-07-23
申请号:PCT/EP2020/050157
申请日:2020-01-07
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: GALVAN, Monica , GRAZZI, Michele , CIARAFONI, Marco , CAVALIERI, Claudio
IPC: C08L23/08
Abstract: A polyolefin composition comprising: A) 5-35% by weight of a propylene ethylene copolymer; B) 20-50% by weight; of an ethylene homopolymer; and C) 30-60% by weight of a terpolymer of ethylene, propylene and 1-butene derived units.
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公开(公告)号:WO2020114837A1
公开(公告)日:2020-06-11
申请号:PCT/EP2019/082595
申请日:2019-11-26
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: BRITA, Diego , CAVALIERI, Claudio
IPC: C08F110/06 , C08F4/654 , C08F4/646 , C08F4/651
Abstract: A process for the preparation of a propylene polymer containing a colouring agent in an amount ranging from 0.2 to 30 ppm referred to the weight of propylene polymer, comprising: a) providing a solid ZN catalyst component which comprises Mg, Ti, halogen and an internal electron donor compound, said Ti being in an amount ranging from 0.1 to 10% of the total weight of solid catalyst component; b) providing a colouring agent comprising at least a pigment; c) mixing the ZN catalyst particles and the colouring agent in a liquid hydrocarbon medium so as to obtain a slurry and d) feeding the slurry obtained in c) to a polymerization reactor and subjecting the reactor to polymerization conditions so as to produce the propylene polymer.
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公开(公告)号:WO2020038746A1
公开(公告)日:2020-02-27
申请号:PCT/EP2019/071524
申请日:2019-08-12
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: FERRARO, Gianpiero , VITALE, Gianni , PIEMONTESI, Fabrizio , GADDI, Benedetta , COLLINA, Gianni , MORINI, Giampiero , CATHELIN, Caroline , CIARAFONI, Marco , CAVALIERI, Claudio
IPC: C08F210/06 , C08F4/657 , C08F4/651
Abstract: A propylene ethylene copolymer characterized by the following features: - an ethylene content of between 1.0 and 4.0% by weight; - a molecular weight distribution (MWD), expressed in terms of Mw/Mn, of greater than 4.0; - a content of xylene soluble fraction (XS) and ethylene content (C2) that fulfills the following relationship: (C2x1.1)+1.25
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公开(公告)号:WO2019091887A1
公开(公告)日:2019-05-16
申请号:PCT/EP2018/080093
申请日:2018-11-05
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: DE PALO, Roberto , CAVALIERI, Claudio
IPC: C08L23/12
Abstract: A polyolefin composition comprising: T1) 70-95wt%, a polyolefin component containing: a1) from 30 wt% to 70 wt% of a propylene based polymer; and a2) from 30 wt% to 70 wt% of an ethylene based polymer; T2) 5-30 wt% of an heterophasic propylene ethylene copolymer.
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公开(公告)号:WO2018069127A1
公开(公告)日:2018-04-19
申请号:PCT/EP2017/075288
申请日:2017-10-05
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: MASSARI, Paola , FELISATI, Andrea , IZZI, Marco , CAVALIERI, Claudio , CIARAFONI, Marco , GUERRA, Silvia , PANTALEONI, Roberto , MALIZIA, Federica
IPC: C08L23/12
Abstract: A nucleated propylene polymer composition comprising: A) from 77 wt% to 91 wt%, of a propylene homopolymer having a fraction insoluble in xylene at 25 °C higher than 95 %; B) from 9 wt % to 23 wt%, of a copolymer of propylene with from 28.0 wt% to 42.0 wt% of ethylene derived units; the composition having an intrinsic viscosity of the fraction soluble in xylene at 25 °C comprised between 1.0 dl/g and 1.9 dl/g, a fraction soluble in xylene at 25 °C comprised between 9.0 wt% and 21.0 wt%, a total melt flow rate (Melt Flow Rate according to ISO 1133, condition L, i.e. 230°C and 2.16 kg load) comprised between 1.5 and 5 g/10 min and the value of the relation (I): 22.5+0.2*MFR-1.2*Xs+0.2*IV is higher than 5.9; wherein MFR is the melt flow rate of the nucleated composition (Melt Flow Rate according to ISO 1133, condition L, i.e. 230°C and 2.16 kg load); IV is the intrinsic viscosity of the fraction soluble in xylene at 25 °C; and Xs is the fraction soluble in xylene at 25°C; wherein the amount of A+B is equal to 100 wt% and wherein the nucleated agent is selected from the group consisting of aromatic or aliphatic carboxylic acids, aromatic metal phosphates, sorbitol derivatives and talc.
Abstract translation: 1.一种成核丙烯聚合物组合物,其包含:A)77重量%至91重量%的丙烯均聚物,其在25℃下具有不溶于二甲苯的部分,其含量高于95%; B)9重量%至23重量%的丙烯与28.0重量%至42.0重量%的乙烯衍生的单元的共聚物; 所述组合物在25℃下的可溶于二甲苯的部分的特性粘度为1.0dl / g至1.9dl / g,在25℃下可溶于二甲苯的部分为9.0wt%至21.0wt%, 总熔体流动速率(根据ISO 1133的熔体流动速率,条件L,即230℃和2.16kg载荷)为1.5至5g / 10min,并且关系式(I)的值为:22.5±0.2 * MFR- 1.2 * Xs + 0.2 * IV高于5.9; 其中MFR是成核组合物的熔体流动速率(根据ISO 1133的熔体流动速率,条件L,即230℃和2.16kg载荷); IV是在25℃可溶于二甲苯的部分的特性粘度; Xs是在25℃可溶于二甲苯的部分; 其中A + B的量等于100wt%,并且其中成核剂选自芳族或脂族羧酸,芳族金属磷酸盐,山梨糖醇衍生物和滑石。 p>
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