75.
    发明专利
    未知

    公开(公告)号:DE3540119A1

    公开(公告)日:1987-05-14

    申请号:DE3540119

    申请日:1985-11-13

    Applicant: BASF AG

    Abstract: A process for the preparation of modified polyphenylene ethers by grafting a maleimide of the formula (I) in which R1, R2 and R3 are H, alkyl, cycloalkyl, alkenyl, optionally substituted aryl or branched alkyl groups, in particular N-phenylmaleimide, onto polyphenylene ethers, which optionally contain polymers of vinylaromatic compounds, and modified polyphenylene ether resins comprising from 99 to 90 parts by weight of polyphenylene ether, from 0 to 1000 parts by weight of vinylaromatic polymer and from 0.1 to 10 parts by weight of graft-polymerised maleimide of the formula (I).

    76.
    发明专利
    未知

    公开(公告)号:DE3540118A1

    公开(公告)日:1987-05-14

    申请号:DE3540118

    申请日:1985-11-13

    Applicant: BASF AG

    Abstract: A process for the preparation of modified polyphenylene ether resins by grafting fumaric acid, preferably at from 270 DEG to 350 DEG C., onto polyphenylene ethers which are mixed with vinylaromatic polymers, and modified polyphenylene ether resins consisting of from 4.95 to 95 parts by weight of polyphenylene ether, from 95 to 4.95 parts by weight of vinylaromatic polymer and from 0.05 to 10 parts by weight of grafted fumaric acid.

    Production of moulded articles
    79.
    发明专利

    公开(公告)号:GB1017494A

    公开(公告)日:1966-01-19

    申请号:GB4093862

    申请日:1962-10-30

    Applicant: BASF AG

    Abstract: A process for the polymerization of lactams having seven or more ring members with simultaneous moulding of the resultant polymer, wherein the lactams are polymerized in hollow moulds by heating said moulds to the polymerization temperature of the lactams, the reaction taking place in the presence of alkaline catalysts comprises melting the lactam at temperatures below polymerization temperature and then introducing the melt together with the alkaline catalyst into the hollow mould by means of conveying equipment. Specified lactams are e -caprolactam, oenantholactam, caprylolactam and laurolactam. Specified catalysts are the alkali metals and hydroxides, carbonates, alcoholates and lactamates thereof. Specified activators are carboxylic acid halides and esters, lactones, inorganic acid halides and esters, substituted ureas, urethanes and guanidines, sulphonic acid halides and esters, phosphoric acid halides and esters, isocyanates, carbodiimides and ketones. The example describes the polymerization of e -caprolactam in an injection cylinder in the presence of potassium and 1 : 6-bis-(caprolactam-N-carbamido)-hexane.

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