73.
    发明专利
    未知

    公开(公告)号:DE59501599D1

    公开(公告)日:1998-04-16

    申请号:DE59501599

    申请日:1995-11-17

    Applicant: BASF AG

    Abstract: Prepn. of propan-1,2-diol (I) comprises catalytic hydrogenation of glycerol at elevated temp. and pressure. Glycerol contg. up to 20 wt.% water and a catalyst (II) are used. (II) contains 40-70 wt.% Co, 10-20 wt.% Cu, 0-10 wt.% Mn and 0-10 wt.% Mo and opt. up to 10 wt.% inorg. polyacid and/or heteropolyacid.

    76.
    发明专利
    未知

    公开(公告)号:DE59106607D1

    公开(公告)日:1995-11-09

    申请号:DE59106607

    申请日:1991-03-21

    Applicant: BASF AG

    Abstract: Process for the preparation of 2,2-disubstituted pentane-1,5-diamines of the general formula I … … in which the substituents R and R , independently of one another, denote C1- to C10-alkyl, C2- to C10-alkenyl or together represent a C4- to C7-alkylene chain which is unsubstituted or substituted by one to five C1- to C4-alkyl groups, from 2,2-disubstituted 4-cyanobutanals of the general formula II … … in which the substituents R and R have the abovementioned meanings, by carrying out the reaction in two reaction spaces spatially separated from one another by …… a) reacting the 4-cyanobutanals of the formula II in a first reaction space with excess ammonia over acidic heterogeneous catalysts at temperatures of 20 to 150 DEG C and pressures of 15 to 500 bar and … b) hydrogenating the reaction products formed in a second reaction space with excess hydrogen in the presence of excess ammonia over cobalt-, nickel-, ruthenium- and/or other noble metal-containing catalysts, which may contain basic components or are arranged on basic or neutral supports at temperatures of 60 to 150 DEG C and pressures of 50 to 500 bar, and novel 2,2-disubstituted pentane-1,5-diamines of the general formula I' …… … in which the substituents R and R , independently of one another, denote C1- to C10-alkyl, C2- to C10-alkenyl or together represent a C4- to C7-alkylene chain which is unsubstituted or substituted by one to five C1- to C4-alkyl groups with the proviso that R and R do not simultaneously denote methyl.

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