1.
    发明专利
    未知

    公开(公告)号:DE59306333D1

    公开(公告)日:1997-06-05

    申请号:DE59306333

    申请日:1993-12-11

    Applicant: BASF AG

    Abstract: Process for the preparation of alpha -tocopherol or tocopheryl acetate by cyclocondensation of trimethylhydroquinone with phytol or isophytol in the presence of an acidic catalyst and of a solvent, optionally followed by acetylation, the process being characterised in that the cyclocondensation and the optional sequent acetylation steps are carried out in liquid or supercritical carbon dioxide as solvent.

    2.
    发明专利
    未知

    公开(公告)号:DE3874357D1

    公开(公告)日:1992-10-15

    申请号:DE3874357

    申请日:1988-01-22

    Applicant: BASF AG

    Abstract: Prodn. of 2-aryl alcohols of formula (I) is effected by reacting an arene of formula (II) with an alkylene oxide of formula (III) in the presence of a Friedel-Crafts catalyst (IV) and a tetraalkyl titanate (V) at -20 to +40 deg.C, opt. in a solvent: R1-R3=H, 1-20C alkyl, 5-7C cycloalkyl, aryl, 7-12C aralkyl or 7-12C alkaryl, or two adjacent R1 gps. are linked to form a 5- or 6-membered ring; n=0-4. (II) is selected from indane, tetralin and their alkyl-substd. derivs. (IV) is AlCl3. (V) is a tetra(1-6C alkyl) titanate.

    4.
    发明专利
    未知

    公开(公告)号:DE3700808A1

    公开(公告)日:1988-07-28

    申请号:DE3700808

    申请日:1987-01-14

    Applicant: BASF AG

    Abstract: Polyaryl ether ketones are prepared by reacting aromatic dihydroxy compounds with aromatic dihalogen compounds in polar aprotic solvents in the presence of alkali metal carbonates, in particular by reacting aromatic dihydroxy compounds I (I) or ring-substituted C1-C8-alkyl, C1-C8-alkoxy, aryl, chlorine or fluorine derivatives thereof, n and m each being 0 or 1, with aromatic dihalogen compounds (II) or ring-substituted C1-C8-alkyl, C1-C8-alkoxy, aryl, chlorine or fluorine derivatives thereof, r and s each being 0 or 1, A being oxygen or a chemical bond and X being chlorine or fluorine.

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