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公开(公告)号:DE59306333D1
公开(公告)日:1997-06-05
申请号:DE59306333
申请日:1993-12-11
Applicant: BASF AG
Inventor: LOWACK RAINER DR , MEYER JOACHIM DR , EGGERSDORFER MANFRED DR , GRAFEN PAUL DR
IPC: C07B61/00 , C07D311/72
Abstract: Process for the preparation of alpha -tocopherol or tocopheryl acetate by cyclocondensation of trimethylhydroquinone with phytol or isophytol in the presence of an acidic catalyst and of a solvent, optionally followed by acetylation, the process being characterised in that the cyclocondensation and the optional sequent acetylation steps are carried out in liquid or supercritical carbon dioxide as solvent.
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公开(公告)号:DE3874357D1
公开(公告)日:1992-10-15
申请号:DE3874357
申请日:1988-01-22
Applicant: BASF AG
Inventor: ECKHARDT HEINZ DR , EGGERSDORFER MANFRED DR
IPC: B01J31/26 , B01J31/00 , C07B61/00 , C07C27/00 , C07C29/132 , C07C29/36 , C07C33/18 , C07C33/20 , C07C33/34 , C07C67/00
Abstract: Prodn. of 2-aryl alcohols of formula (I) is effected by reacting an arene of formula (II) with an alkylene oxide of formula (III) in the presence of a Friedel-Crafts catalyst (IV) and a tetraalkyl titanate (V) at -20 to +40 deg.C, opt. in a solvent: R1-R3=H, 1-20C alkyl, 5-7C cycloalkyl, aryl, 7-12C aralkyl or 7-12C alkaryl, or two adjacent R1 gps. are linked to form a 5- or 6-membered ring; n=0-4. (II) is selected from indane, tetralin and their alkyl-substd. derivs. (IV) is AlCl3. (V) is a tetra(1-6C alkyl) titanate.
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公开(公告)号:DE58900975D1
公开(公告)日:1992-04-23
申请号:DE58900975
申请日:1989-04-29
Applicant: BASF AG
Inventor: BECKER RAINER DR , ECKHARDT HEINZ DR , EGGERSDORFER MANFRED DR , SCHINDLER GERHARD , JANSEN KLAAS
Abstract: 1-tert-Butoxy- omega -alkenes of the general formula I CH2=CH-CH2)nO-C(CH3)3 (I) wherein n is an integer from 4 to 10, their preparation and their use for imparting fragrance properties to perfumes or to products to be perfumed, or for improving or modifying the fragrance properties of the said perfumes or products, and scent compositions containing these compounds.
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公开(公告)号:DE3700808A1
公开(公告)日:1988-07-28
申请号:DE3700808
申请日:1987-01-14
Applicant: BASF AG
Inventor: HEINZ GERHARD DR , KOCH JUERGEN DR , EGGERSDORFER MANFRED DR , HENKELMANN JOCHEM DR
Abstract: Polyaryl ether ketones are prepared by reacting aromatic dihydroxy compounds with aromatic dihalogen compounds in polar aprotic solvents in the presence of alkali metal carbonates, in particular by reacting aromatic dihydroxy compounds I (I) or ring-substituted C1-C8-alkyl, C1-C8-alkoxy, aryl, chlorine or fluorine derivatives thereof, n and m each being 0 or 1, with aromatic dihalogen compounds (II) or ring-substituted C1-C8-alkyl, C1-C8-alkoxy, aryl, chlorine or fluorine derivatives thereof, r and s each being 0 or 1, A being oxygen or a chemical bond and X being chlorine or fluorine.
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公开(公告)号:DE3603662A1
公开(公告)日:1987-08-13
申请号:DE3603662
申请日:1986-02-06
Applicant: BASF AG
Inventor: HIMMELE WALTER DR , BRENNER KARL , EGGERSDORFER MANFRED DR , HALBRITTER KLAUS DR
IPC: B01J23/00 , C07B61/00 , C07D317/26 , C07D319/06 , C07D321/06 , C07D319/08 , C07D321/10 , C07D321/12
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公开(公告)号:DE3404336A1
公开(公告)日:1985-08-08
申请号:DE3404336
申请日:1984-02-08
Applicant: BASF AG
Inventor: FRITZ GERHARD DR , EGGERSDORFER MANFRED DR , SIEGEL HARDO DR
IPC: C07D333/24 , C07C67/30 , C07C69/612 , C07D213/55 , C07D215/14 , C07C67/343
Abstract: Esters of optically active 2-arylalkanoic acids I I where Ar is an isocyclic or heterocyclic aryl radical and R1 and R2 are each C1-C4-alkyl, are prepared by subjecting an optically active ester II II where X is Cl, Br or -O-SO2-Y and Y is Cl or a hydrocarbon radical, to a Friedel-Crafts reaction with an aromatic compound ArH (III).
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公开(公告)号:AT54131T
公开(公告)日:1990-07-15
申请号:AT87117865
申请日:1987-12-03
Applicant: BASF AG
Inventor: HENKELMANN JOCHEM DR , EGGERSDORFER MANFRED DR , GROSCH WALTER DR , SCHUHMACHER ALFRED DR , SIEGEL HARDO DR
IPC: B01J27/125 , C07B61/00 , C07C45/00 , C07C45/46 , C07C51/00 , C07C51/083 , C07C51/373 , C07C65/34 , C07C67/00
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公开(公告)号:DE3815044A1
公开(公告)日:1989-11-16
申请号:DE3815044
申请日:1988-05-04
Applicant: BASF AG
Inventor: BECKER RAINER DR , ECKHARDT HEINZ DR , EGGERSDORFER MANFRED DR , SCHINDLER GERHARD , JANSEN KLAAS
Abstract: 1-tert-Butoxy- omega -alkenes of the general formula I CH2=CH-CH2)nO-C(CH3)3 (I) wherein n is an integer from 4 to 10, their preparation and their use for imparting fragrance properties to perfumes or to products to be perfumed, or for improving or modifying the fragrance properties of the said perfumes or products, and scent compositions containing these compounds.
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公开(公告)号:DE3800083A1
公开(公告)日:1989-07-13
申请号:DE3800083
申请日:1988-01-05
Applicant: BASF AG
Inventor: FRANZ LOTHAR DR , EGGERSDORFER MANFRED DR , VOGES DIETER DR
IPC: C07D233/34 , B01J27/02 , C07B61/00 , C07D233/32 , C07D239/10 , C07D247/02
Abstract: A process for the preparation of cyclic N,N'-dimethylureas by catalytic hydrogenation of cyclic ureas which carry hydroxyl groups in the alpha -position to the two nitrogen atoms.
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公开(公告)号:DE3641793A1
公开(公告)日:1988-06-16
申请号:DE3641793
申请日:1986-12-06
Applicant: BASF AG
Inventor: HENKELMANN JOCHEM DR , EGGERSDORFER MANFRED DR , GROSCH WALTER DR , SCHUHMACHER ALFRED DR , SIEGEL HARDO DR
IPC: B01J27/125 , C07B61/00 , C07C45/00 , C07C45/46 , C07C51/00 , C07C51/083 , C07C51/373 , C07C65/34 , C07C67/00
Abstract: Alkyl-substituted aromatic ketones are prepared by reacting alkylbenzenes with carboxylic anhydrides in the presence of a Friedel-Crafts catalyst by performing the reaction in the presence of a tertiary amine or diamine.
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