公开(公告)号：AU2013311886A1

公开(公告)日：2015-03-19

申请号：AU2013311886

申请日：2013-08-19

Applicant: BASF SE

Inventor： KATZ TORSTEN ,  BARTLING KARSTEN

IPC: B01D53/14

Abstract: A method for separating acid gases from an aqueous flow of fluid is described, according to which method a) the aqueous flow of fluid is brought into contact in an absorption area with an absorbent which contains at least one amine, wherein a deacidified flow of fluid and an absorbent charged with acid gases are obtained; b) the deacidified flow of fluid is brought into contact in a washing area with an aqueous washing fluid in order to transfer, at least partially, carried amine into the washing fluid, wherein a deaminated, deacidified flow of fluid and an amine-charged washing fluid are obtained; c) the deaminated, deacidified flow of fluid is cooled downstream of the washing area, wherein an absorber top condensate is condensed out of the deaminated, deacidified flow of fluid; d) the charged absorbent is guided into a desorption area in which the acid gases are at least partially released, wherein a regenerated absorbent and desorbed acid gases are obtained; e) the regenerated absorbents are guided back into the absorption area in order to form an absorbent cycle; f) the amine-charged washing fluid and the absorber top condensate are introduced into the absorbent cycle; and g) the desorbed acid gases are guided through a reinforcement area and the acid gases coming out of the top of the reinforcement area are cooled, in order to condense a desorber top condensate out of the acid gases, which desorber top condensate is partially guided back into the reinforcement area and is partially guided out of the method. The method allows an efficient retention of amines from the treated flows of fluid while maintaining the water balance of the acid gas removal installation.

公开(公告)号：ES2511049T3

公开(公告)日：2014-10-22

申请号：ES10710018

申请日：2010-03-18

Applicant: BASF SE

Inventor： TRUKHAN NATALIA ,  MÜLLER ULRICH ,  MELDER JOHANN-PETER ,  BRUGHMANS STEVEN ,  KATZ TORSTEN

IPC: B01D53/02

Abstract: Procedimiento para la separación al menos de un gas ácido de una mezcla de gases, que contiene el al menos un gas ácido, que contiene la etapa (a) poner en contacto la mezcla de gases con un material de estructura organometálico poroso, en el que el material de estructura adsorbe el al menos un gas ácido y en el que el material de estructura contiene al menos un compuesto orgánico al menos bidentado unido por coordinación a al menos un ion metálico, en el que el material de estructura organometálico poroso está impregnado con una amina adecuada para el lavado de gases y en el que la proporción de amina se encuentra en el intervalo de 1 mmol a 100 mmol por g de material de estructura.

公开(公告)号：AU2013225124A1

公开(公告)日：2014-09-25

申请号：AU2013225124

申请日：2013-02-26

Applicant: BASF SE

Inventor： KATZ TORSTEN ,  RIEMANN CHRISTIAN ,  SIEDER GEORG

IPC: B01D53/14

Abstract: A process for removing acid gases from a water vapour-containing fluid stream (1) comprises a) providing an absorption liquid (16) which is incompletely miscible with water; b) treating the fluid stream (1) in an absorption zone (3) with the absorption liquid (16) to obtain an acid gas-depleted treated fluid stream (4) and an acid gas-loaded absorption liquid (7); c) directing the treated fluid stream (4) to a rehydration zone (5) and treating the fluid stream (4) with an aqueous liquid (22) to volatilize at least part of the aqueous liquid; d) regenerating (12) the loaded absorption liquid (9, 11) to expel the acid gases (17) at least in part and obtain a regenerated absorption liquid (13), and directing the regenerated absorption liquid (13, 14, 16) to step b); and e) separating (8), from the absorption liquid (7), an aqueous liquid (22) that has condensed in the absorption zone (3), and directing the aqueous liquid (22) to step c). The process allows for an efficient removal of water accumulated in the absorption liquid system.

公开(公告)号：AU2013224898A1

公开(公告)日：2014-09-25

申请号：AU2013224898

申请日：2013-03-01

Applicant: RES TRIANGLE INST ,  BASF SE

Inventor： KATZ TORSTEN ,  RIEMANN CHRISTIAN ,  BARTLING KARSTEN ,  RIGBY SEAN TAYLOR ,  COLEMAN LUKE JAMES IVOR ,  LAIL MARTY ALAN

IPC: B01D53/14 ,  B01D53/50 ,  C01B17/60

Abstract: A process for removing sulphur oxides from a fluid stream,such as flue gas, that comprises a) providing a non-aqueous absorption liquid containing at least one hydrophobic amine, the non-aqueous absorption liquid being incompletely miscible with water; b) treating the fluid stream in an absorption zone with the non-aqueous absorption liquid to transfer at least part of the sulphur oxides into the non-aqueous absorption liquid and to form a sulphur oxide-hydrophobic amine-complex; c)causing the non-aqueous absorption liquid to be in liquid-liquid contact with an aqueous liquid where by at least part of the sulphur oxide-hydrophobic amine-complex is hydrolyzed to release the hydrophobic amine and sulphurous hydrolysis products, and at least part of the sulphurous hydrolysis products is transferred into the aqueous liquid; d)separating the aqueous liquid from the non-aqueous absorption liquid. The process mitigates absorbent degradation problems caused by sulphur dioxide and oxygen in flue gas.

公开(公告)号：PL2391437T3

公开(公告)日：2014-01-31

申请号：PL10703826

申请日：2010-01-27

Applicant: BASF SE

Inventor： VORBERG GERALD ,  KATZ TORSTEN ,  SIEDER GEORG ,  RIEMANN CHRISTIAN ,  WAGNER RUPERT ,  LICHTFERS UTE ,  DENGLER ERIKA

IPC: B01D53/14 ,  B01D53/52 ,  B01D53/62

公开(公告)号：ES2428236T3

公开(公告)日：2013-11-06

申请号：ES10703826

申请日：2010-01-27

Applicant: BASF SE

Inventor： VORBERG GERALD ,  KATZ TORSTEN ,  SIEDER GEORG ,  RIEMANN CHRISTIAN ,  WAGNER RUPERT ,  LICHTFERS UTE ,  DENGLER ERIKA

IPC: B01D53/14 ,  B01D53/52 ,  B01D53/62

Abstract: Agente de absorción para la eliminación de gases ácidos a partir de una corriente de fluido, que comprende unadisolución acuosa a) al menos una sal metálica de un ácido aminocarboxílico, y b) al menos un promotor ácido, que es seleccionado entre ácidos fosfónicos orgánicos y ésteres parcialesde los mismos, situándose la proporción molar de b) respecto a a) en el intervalo de 0,0005 a 1,0.

公开(公告)号：ES2425429T3

公开(公告)日：2013-10-15

申请号：ES10721454

申请日：2010-05-12

Applicant: BASF SE

Inventor： VORBERG GERALD ,  KATZ TORSTEN ,  SIEDER GEORG ,  RIEMANN CHRISTIAN ,  DENGLER ERIKA

IPC: B01D53/14

Abstract: Medio de absorción para eliminar gases ácidos de una corriente fluida que comprende una solución acuosa a) de al menos una amina y b) de al menos un ácido fosfónico orgánico, en cuyo caso la proporción molar de b) a a) se encuentra en el intervalo de 0,0005 a 0,1.

公开(公告)号：CA2866105A1

公开(公告)日：2013-09-06

申请号：CA2866105

申请日：2013-03-01

Applicant: BASF SE ,  RES TRIANGLE INST

Inventor： KATZ TORSTEN ,  RIEMANN CHRISTIAN ,  BARTLING KARSTEN ,  RIGBY SEAN TAYLOR ,  COLEMAN LUKE JAMES IVOR ,  LAIL MARTY ALAN

IPC: B01D53/14 ,  B01D53/50 ,  C01B17/60

Abstract: A process for removing sulphur oxides from a fluid stream,such as flue gas, that comprises a) providing a non-aqueous absorption liquid containing at least one hydrophobic amine, the non-aqueous absorption liquid being incompletely miscible with water; b) treating the fluid stream in an absorption zone with the non-aqueous absorption liquid to transfer at least part of the sulphur oxides into the non-aqueous absorption liquid and to form a sulphur oxide-hydrophobic amine-complex; c)causing the non-aqueous absorption liquid to be in liquid-liquid contact with an aqueous liquid where by at least part of the sulphur oxide-hydrophobic amine-complex is hydrolyzed to release the hydrophobic amine and sulphurous hydrolysis products, and at least part of the sulphurous hydrolysis products is transferred into the aqueous liquid; d)separating the aqueous liquid from the non-aqueous absorption liquid. The process mitigates absorbent degradation problems caused by sulphur dioxide and oxygen in flue gas.

公开(公告)号：CA2866090A1

公开(公告)日：2013-09-06

申请号：CA2866090

申请日：2013-02-26

Applicant: BASF SE

Inventor： KATZ TORSTEN ,  RIEMANN CHRISTIAN ,  SIEDER GEORG

IPC: B01D53/14

Abstract: A process for removing acid gases from a water vapour-containing fluid stream (1) comprises a) providing an absorption liquid (16) which is incompletely miscible with water; b) treating the fluid stream (1) in an absorption zone (3) with the absorption liquid (16) to obtain an acid gas-depleted treated fluid stream (4) and an acid gas-loaded absorption liquid (7); c) directing the treated fluid stream (4) to a rehydration zone (5) and treating the fluid stream (4) with an aqueous liquid (22) to volatilize at least part of the aqueous liquid; d) regenerating (12) the loaded absorption liquid (9, 11) to expel the acid gases (17) at least in part and obtain a regenerated absorption liquid (13), and directing the regenerated absorption liquid (13, 14, 16) to step b); and e) separating (8), from the absorption liquid (7), an aqueous liquid (22) that has condensed in the absorption zone (3), and directing the aqueous liquid (22) to step c). The process allows for an efficient removal of water accumulated in the absorption liquid system.

公开(公告)号：ZA201201509B

公开(公告)日：2013-05-29

申请号：ZA201201509

申请日：2012-02-29

Applicant: BASF SE

Inventor： RIEMANN CHRISTIAN ,  KATZ TORSTEN ,  SIEDER GEORG ,  VORBERG GERALD ,  DENGLER ERIKA

IPC: B01D20060101

Abstract: An absorption medium for removing acid gases from a fluid stream comprises an aqueous solution (A) of an alkali metal salt of an N,N-di-C1-C4-alkylaminocarboxylic acid and (B) N-hydroxyethylpiperazine. The absorption medium has a low vapor pressure and an increased resistance to oxygen. Preferred fluid streams are combustion exhaust gases or biogas.