Absorbent containing cyclic amines for removing acid gases

    公开(公告)号:AU2010209661B2

    公开(公告)日:2015-09-17

    申请号:AU2010209661

    申请日:2010-02-01

    Applicant: BASF SE

    Abstract: The invention relates to an absorbent for removing acid gases from a fluid flow, comprising an aqueous solution A) of at least one cyclic amine compound having exclusively tertiary amine groups and/or sterically hindered secondary amine groups, and B) of at least one cyclic amine compound having at least one sterically unhindered secondary amine group. The absorbent comprises, for example, an aqueous solution of A) 1-hydroxyethyl-piperidine and/or triethylenediamine and B) piperazine. The absorbent is suited especially for separating carbon dioxide from flue gases and meets the following criteria: (i) sufficient capacity at low CO

    ABSORBENT CONTAINING CYCLIC AMINES FOR REMOVING ACID GASES

    公开(公告)号:CA2750460C

    公开(公告)日:2017-01-24

    申请号:CA2750460

    申请日:2010-02-01

    Applicant: BASF SE

    Abstract: The invention relates to an absorbent for removing acid gases from a fluid flow, comprising an aqueous solution A) of at least one cyclic amine compound having exclusively tertiary amine groups and/or sterically hindered secondary amine groups, and B) of at least one cyclic amine compound having at least one sterically unhindered secondary amine group. The absorbent comprises, for example, an aqueous solution of A) 1-hydroxyethyl-piperidine and/or triethylenediamine and B) piperazine. The absorbent is suited especially for separating carbon dioxide from flue gases and meets the following criteria: (i) sufficient capacity at low CO2 partial pressures; (ii) sufficiently fast absorption speed at low CO2 partial pressures; (iii) stability toward oxygen; (iv) low vapor pressure in order to reduce solvent losses; and (v) low energy requirement for regenerating the absorbent.

    PROCESS FOR PREPARING 2-(2-TERT-BUTYLAMINOETHOXY)ETHANOL (TERT-BUTYLAMINODIGLYCOL, TBADG)

    公开(公告)号:CA2798971A1

    公开(公告)日:2011-11-24

    申请号:CA2798971

    申请日:2011-05-18

    Applicant: BASF SE

    Abstract: The invention relates to a method for producing 2-(2-tert.-butylamino-ethoxy)-ethanol (tert.-butylaminodiglycol, TBADG) by reacting diethylene glycol (DG) with tert.-butylamine (TBA) in the presence of hydrogen and a copper-containing catalyst, the reaction being carried out at a temperature ranging from 160 to 220ºC in the presence of a copper- and alumina-containing catalyst, wherein the catalytically active mass of the catalyst, prior to the reduction thereof using hydrogen, contains 20 to 75% by weight of alumina (Al2O3), 20 to 75% by weight of oxygen-containing copper compounds, calculated as CuO, and = 5% by weight of oxygen-containing nickel compounds, calculated as NiO.

    PROCESS FOR PREPARING 2-(2-TERT-BUTYLAMINOETHOXY)ETHANOL (TERT-BUTYLAMINODIGLYCOL, TBADG)

    公开(公告)号:CA2798971C

    公开(公告)日:2018-07-24

    申请号:CA2798971

    申请日:2011-05-18

    Applicant: BASF SE

    Abstract: The invention relates to a method for producing 2-(2-tert.-butylamino-ethoxy)-ethanol (tert.-butylaminodiglycol, TBADG) by reacting diethylene glycol (DG) with tert.-butylamine (TBA) in the presence of hydrogen and a copper-containing catalyst, the reaction being carried out at a temperature ranging from 160 to 220°C in the presence of a copper- and alumina-containing catalyst, wherein the catalytically active mass of the catalyst, prior to the reduction thereof using hydrogen, contains 20 to 75% by weight of alumina (A12O3), 20 to 75% by weight of oxygen-containing copper compounds, calculated as CuO, and

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