公开(公告)号：JPS6430157A

公开(公告)日：1989-02-01

申请号：JP18515087

申请日：1987-07-24

Applicant: BRIDGESTONE CORP

Inventor： MASUDA YOSHITOMO ,  OGAWA MASAO ,  KAWAGOE TAKAHIRO ,  SHINODA ISAMU ,  HARADA TOYORO

IPC: H01M6/16 ,  H01M2/02 ,  H01M4/02 ,  H01M4/13 ,  H01M10/05

Abstract: PURPOSE:To keep the close contact of contents within a container to improve the cycle life and self discharge performance of a battery by closely accommodating contents containing a positive electrode material, a negative electrode material, and an electrolyte in a battery container, sealing a case and a cover, and repeatedly sealing a battery according to the volume change within the battery. CONSTITUTION:Contents containing a positive electrode 4, a negative electrode 6, and an electrolyte are closely accommodated in a battery container comprising a case 2 and a cover 3, and the case 2 and the cover 3 are sealed to form a battery. The battery is repeatedly sealed according to the volume variation of the contents in the container 1 to keep the close contact of contents within the container 1. A lithium alloy is used as a negative electrode 6, and the alloying of lithium is advanced within the battery. Since the volume in the contents is decreased with the advance of lithium alloying, the inner volume of the battery is decreased 1-40% by the second and the following sealing processes to shorten reaction time for alloying lithium and a metal to be alloyed with lithium. The charge-discharge cycle life of the battery is increased and the self discharge performance is also improved.

公开(公告)号：JPS6326955A

公开(公告)日：1988-02-04

申请号：JP16956886

申请日：1986-07-18

Applicant: BRIDGESTONE CORP

Inventor： OGAWA MASAO ,  FUSE TADASHI ,  MASUDA YOSHITOMO ,  OFUKU EIJI ,  KITA TOSHIO

IPC: H01M4/137 ,  H01M4/60 ,  H01M10/052

Abstract: PURPOSE:To obtain a battery having good performance such as low internal resistance and long cycle life by using polyaniline, to which electrochemical reduction treatment is applied in nonaqueous electrolyte, in a positive electrode as positive active material. CONSTITUTION:When polyaniline is produced in electrochemical process, usually aqueous solution is used. If this polyaniline is used as it is in a nonaqueous electrolyte battery as positive active material, the internal resistance of the battery is high and the performance such as cycle life is not good. By previously applying electrochemical reduction treatment to polyaniline in nonaqueous solution and controlling the reduction potential to 2.0-3.0 V (V.S Li /Li), the internal resistance of the battery using this polyaniline as the positive active material is reduced and the cycle life is increased.

公开(公告)号：JPS6325984A

公开(公告)日：1988-02-03

申请号：JP16782786

申请日：1986-07-18

Applicant: BRIDGESTONE CORP

Inventor： MASUDA YOSHITOMO ,  FUSE TADASHI ,  OGAWA MASAO ,  OFUKU EIJI ,  KITA TOSHIO

IPC: H01L51/42 ,  H01L31/04

Abstract: PURPOSE:To facilitate the checking of the charged state and the discharged state of a power source and to reduce the space for the power source, in the combination power source of a solar battery and a secondary battery, by using conductive macromolecular material, desirably polyaniline, for at least one electrode of the secondary battery. CONSTITUTION:In a power source, wherein a solar battery and a secondary battery are combined, conductive macromolecular material is used for the electrodes of the secondary battery. In this battery, doping and un-doping reactions are generally utilized for electrode reaction. Therefore, the battery voltage and the doping state, i.e., the battery voltage and the battery capacity, are in corresponding relationship. Even if irradiation conditions on the solar battery are changed into any state, the charged or discharged state of the secondary battery can be checked based on the voltage. Above all, the secondary battery, in which polyaniline is used for the electrodes, is desirable by the following reasons: polyaniline has a large capacity per active material, repetition property of charge and discharge is excellent; polyaniline has oxidation resisting property to some extent; and the battery is advantageous in handling work.

公开(公告)号：JPS62184779A

公开(公告)日：1987-08-13

申请号：JP2473086

申请日：1986-02-06

Applicant: BRIDGESTONE CORP

Inventor： OFUKU EIJI ,  FUSE TADASHI ,  OGAWA MASAO ,  MASUDA YOSHITOMO ,  FUJIO RYOTA

IPC: H01M10/44

Abstract: PURPOSE:To lengthen the life, especially the float life of a secondary battery in which an organic conductive polymer such as polyaniline is used in a positive electrode and/or a negative electrode by charging a battery at such voltage or less that a charge current value at a point where 100 hours has been passed from the start of constant voltage charge is 1 muA per 1 mAh of discharge capacity. CONSTITUTION:When a secondary battery in which organic conductive polymer is used as a positive and/or negative active materials is charged, the battery is charged at such voltage or less that a charge current value at a point where 100 hours has been passed from the start of constant voltage charge is 1 muA per 1 mAh of discharge capacity. By charging the battery at voltage equivalent to 1 muA, perferably 0.5 muA, per 1 mAh of discharge capacity, the float life, cycle life, and especially the self discharge of the secondary battery using organic conductive polymer in active material are improved to a level which is practically no problem.

公开(公告)号：JPS6293861A

公开(公告)日：1987-04-30

申请号：JP23204785

申请日：1985-10-17

Applicant: BRIDGESTONE CORP

Inventor： MASUDA YOSHITOMO ,  FUSE TADASHI ,  OGAWA MASAO ,  OFUKU EIJI ,  FUJIO RYOTA

IPC: H01M4/134 ,  H01M4/40 ,  H01M4/46 ,  H01M4/66

Abstract: PURPOSE:To reduce internal resistance in the negative electrode, improve a degree of coulomb efficiency and achieve the promotion of miniaturization and lightweightiness, by setting an aluminum porous body, having an interconnecting pore whose porosity is more than the specified value and at least its surface is alloyed with lithium or an aluminum-indium alloyed porous body down to a negative electrode active material. CONSTITUTION:As the negative pole, an interconnecting porous lithium-aluminum alloyed porous body of more than 50% in porosity or a lithium-aluminum-indium alloyed porous body or an interconnecting porous aluminum porous body whose surface is alloyed with lithium at the least, or an aluminum-indium alloyed porous body is used. With this constitution, internal resistance is low, a degree of coulomb efficiency is increased, and thus such a secondary battery that never forms dendrite is securable. In this connection, if porosity is lower than 50% no change has resulted from the conventional coulomb efficiency so that this aim is unattainable.

公开(公告)号：JPS6168864A

公开(公告)日：1986-04-09

申请号：JP18886684

申请日：1984-09-11

Applicant: Bridgestone Corp

Inventor： MASUDA YOSHITOMO ,  TOYOSAWA SHINICHI ,  OGAWA MASAO ,  NAKAJIMA TADASHI ,  MIYAZAKI TADAAKI ,  KAWAGOE TAKAHIRO ,  FUJIO RYOTA

IPC: H01M10/052 ,  H01M4/60

CPC classification number: H01M10/05 ,  H01M4/60

Abstract: PURPOSE:To obtain a battery having light weight, large discharge capacity, and long cycle life by using polyaniline as a positive electrode and either one of aluminum, zinc, aluminium-lithium alloy, and zinc-lithium alloy as a negative electrode. CONSTITUTION:Polyaniline is used as positive active material, and either one of aluminum, zinc, zluminium-lithium alloy, and zinc-lithium alloy is used as negative material, and a salt containing lithium ion is used as electrolyte. For example, a battery is made by using polyaniline obtained by electrolytically polymerizing aniline in hydrochloric acid solution as a positive electrode, and an aluminum piece as a negative electrode, and a polypropylene porous film as a separator. Propylene carbonate solution containing one molar LiClO4 is used as electrolyte. This battery provides high power, flat discharge voltage, high charge-discharge efficiency, and long cycle life.

Abstract translation: 目的：通过使用聚苯胺作为正极和铝，锌，铝 - 锂合金和锌 - 锂合金中的任一种作为负极，获得重量轻，放电容量大，循环寿命长的电池。 构成：使用聚苯胺作为正极活性物质，使用铝，锌，锌 - 锂合金和锌 - 锂合金中的任一种作为负极材料，并且使用含锂的锂离子作为电解质。 例如，使用通过在盐酸溶液中将苯胺电解聚合作为正极而获得的聚苯胺，作为负极的铝片，以及作为隔膜的聚丙烯多孔膜制成电池。 使用含有1摩尔LiClO 4的碳酸亚丙酯溶液作为电解质。 该电池提供高功率，平放电压，充放电效率高，循环寿命长。

公开(公告)号：JPS60262355A

公开(公告)日：1985-12-25

申请号：JP11780784

申请日：1984-06-08

Applicant: BRIDGESTONE CORP

Inventor： NAKAJIMA TADASHI ,  MASUDA YOSHITOMO ,  OGAWA MASAO ,  TOYOSAWA SHINICHI ,  MIYAZAKI TADAAKI ,  KAWAGOE TAKAHIRO ,  FUJIO RIYOUTA

IPC: H01M4/60

Abstract: PURPOSE:To minimize increase in the electric potential of the positive electrode relative to the amount of charging electricity and achieve improved voltage flatness during discharging by using a specific polyphenyleneimine compound as the positive active material. CONSTITUTION:A polyphenyleneimine compound represented by the general formula R-NH(C6N4NH)nR' (R and R' are a hydrogen atom, an alkyl, a phenyl, an alkyl-substituted phenyl or a naphthyl group.) is used as the positive active material. The polyphenyleneimine compound can be obtained, for example, by condensing phenylenediamine and mono- or di-benzene halide. For example, a secondary battery is constituted by using a popsitive electrode made of N,N'- diphenyl-paraphenylenediamine, a negative electrode made of metallic lithium and electrolyte prepared from LiClO4 and propylene carbonate.

公开(公告)号：JPS60212438A

公开(公告)日：1985-10-24

申请号：JP6829584

申请日：1984-04-05

Applicant: Bridgestone Corp

Inventor： FUKAHORI YOSHIHIDE ,  OGAWA MASAO ,  UTSUNOMIYA TADASHI ,  MATSUMURO YASUHIKO ,  SATOU KEISHI

IPC: C08K3/00 ,  B65G15/32 ,  C08L1/00 ,  C08L7/00 ,  C08L21/00 ,  C08L23/00 ,  C08L27/00 ,  C08L33/00 ,  C08L33/02 ,  C08L51/00 ,  C08L51/02 ,  C08L67/00 ,  C08L77/00 ,  C08L101/00 ,  C09K3/00

Abstract: PURPOSE: The titled material, obtained by incorporating an adhesion inhibitor with rubber or plastic in a specific proportion, and capable of preventing effectively the adhesion of adhesive material, e.g. oil sand.
CONSTITUTION: A transporting belt material obtained by incorporating 100pts.wt. rubber or plastic with 10W250pts.wt. adhesion inhibitor. An adhesion inhibitor capable of constantly bleeding on the surface of a belt after molding to cover always the surface, compatibilizing well with bitumen, reducing the cohesive force of the bitumen itself remarkably from that of the mixed phase and easily peeling the once adhered oil sand is used as the adhesion inhibitor, and the adhesion inhibitor, having 6.5W10.5 solubility parameter (SP) value, tackiness of a mixture at 1:1 weight ratio between adhesion inhibitor and the bitumen ≤0.35 that of the bitumen alone, capable of bleeding 0.03W15mg/cm
2 adhesion inhibitor from the sheet surface obtained by incorporating a basic formulation of 100pts. wt. NBR with 60pts.wt. carbon with 30pts.wt. above-mentioned adhesion inhibitor at 20°C for 24hr, and having ≥200°C boiling point under ordinary pressure is particularly preferred for the adhesion inhibitor.
COPYRIGHT: (C)1985,JPO&Japio

Abstract translation: 目的：通过将粘合抑制剂与橡胶或塑料以特定比例并入，并且能够有效地防止粘合剂材料例如粘合剂的粘合而获得的标题材料。 油砂。 构成：通过加入100pts.wt。 橡胶或塑料与10-250pts.wt。 粘附抑制剂。 一种粘合抑制剂，其能够在成型后在带表面上不断渗出，总是覆盖表面，与沥青良好相容，使沥青本身显着地与混合相的粘合力显着降低，容易剥离一次粘附的油砂 用作粘合抑制剂和粘附抑制剂，具有6.5-10.5溶解度参数（SP）值，粘合抑制剂与沥青之间的1:1重量比的混合物的粘合性<= 0.35单独的沥青，能够渗出 0.03-15mg / cm 2粘合抑制剂从通过掺入100pts的基本配方而获得的片材表面。 重量 NBR与60pts.wt 碳含量30pts.wt。 上述粘合抑制剂在20℃下进行24小时，并且在常压下具有> = 200℃的沸点对于粘合抑制剂是特别优选的。

公开(公告)号：JPS60210644A

公开(公告)日：1985-10-23

申请号：JP6674984

申请日：1984-04-05

Applicant: Bridgestone Corp

Inventor： UTSUNOMIYA TADASHI ,  MATSUMURO YASUHIKO ,  SATOU KEISHI ,  FUKAHORI YOSHIHIDE ,  OGAWA MASAO

IPC: C08K9/00 ,  B65G15/30 ,  C08K9/08 ,  C08K9/10 ,  C08L1/00 ,  C08L7/00 ,  C08L21/00 ,  C08L23/00 ,  C08L27/00 ,  C08L33/00 ,  C08L33/02 ,  C08L51/00 ,  C08L51/02 ,  C08L67/00 ,  C08L77/00 ,  C08L101/00 ,  C09K3/00

Abstract: PURPOSE: A resin material which can form a conveyor belt excellent in an effect of preventing adhesion of a sticky material, containing a specified microencapsulated adhesion-preventing agent.
CONSTITUTION: An adhesion-preventing agent having the following properties: (i) an SP value of 6.5W10.5, (ii) a b.p. (atmospheric) ≥200°C, (iii) the adhesive force (25°C) of its blend with bitumen (1:1 by weight) is below 0.35 time that of bitumen itself, and (iv) the amount of bleeding (20°C×24hr) to the surface of a sheet- like sample (NBR 100pts.wt., HAF carbon 60pts.wt., and adhesion-preventing agent 30pts.wt.) is 0.03W15mg/cm
2 , preferably, an organic carboxylic acid ester having the above property, e.g., butyl oleate, is coated with gelatin, polyvinyl alcohol, or the like to form microcapsules. These microcapsules are added to a rubber material or a plastic material to obtain a material for conveyor belts.
COPYRIGHT: (C)1985,JPO&Japio

Abstract translation: 目的：一种可形成输送带的树脂材料，该输送带具有防止含有特定的微胶囊化粘合防止剂的粘性材料粘合的效果。 构成：具有以下性质的防粘连剂：（i）SP值为6.5-10.5，（ii）b.p. （大气压）> = 200℃，（iii）其与沥青（1：1重量比）的混合物的粘合力（25℃）低于沥青本身的0.35倍，和（iv） 片状样品（NBR 100pts.wt。，HAF碳60pts.wt。，防粘连剂30pts.wt。）表面出血（20℃×24小时）为0.03-15mg / cm 2， 优选具有上述性质的有机羧酸酯，例如油酸丁酯，用明胶，聚乙烯醇等涂覆以形成微胶囊。 将这些微胶囊加入到橡胶材料或塑料材料中以获得用于输送带的材料。

公开(公告)号：JPS59113043A

公开(公告)日：1984-06-29

申请号：JP22012682

申请日：1982-12-17

Applicant: Bridgestone Corp

Inventor： FUKAHORI YOSHIHIDE ,  OGAWA MASAO ,  FUJIO RIYOUTA

IPC: C08L7/00 ,  B65G15/30 ,  C08K5/20 ,  C08L21/00 ,  C08L23/00 ,  C08L33/00 ,  C08L33/02 ,  C08L101/00

Abstract: PURPOSE: A material for a belt having low adhesion, capable of preventing adherent materials such as oil sand, etc. from attaching to it without applying an anti-block agent to it, obtained by blending rubber with a specific ratio of a specified organic fatty acid amide.
CONSTITUTION: 100pts.wt. natural or synthetic rubber is blended with 2W60 pts.wt., preferably 3W50pts.wt. 5W26C organic fatty acid amide (preferably 10W 20C organic fatty acid amide) (e.g., lauric acid amidestearic acid amide, oleic acid amide, etc.), preferably further 5W100pts.wt. α,β-ethylenic unsaturated carboxylic acid [preferably (meth)acrylic acid], 3W150pts.wt. bivalent metallic compound (preferably zinc oxide), 0.2W20pts.wt. organic peroxide (e.g., dicumyl peroxide, etc.) and ≥0.1pt.wt. aromatic secondary amine compound (e.g., N- isopropyl-N'-phenyl-p-phenylenediamine, etc.), to give the desired composition.
EFFECT: Reduction in cost of transportation, prevention of fire, etc. are attained.
COPYRIGHT: (C)1984,JPO&Japio

Abstract translation: 目的：将具有低特定比例的特定有机脂肪的橡胶混合得到的具有低附着力的能够防止粘附材料如油砂等的材料，而不对其施加防粘连剂 酸酰胺。 组成：100pts.wt。 天然或合成橡胶与2-60重量份，优选3-50pts.wt。 5-26C有机脂肪酸酰胺（优选10-20C有机脂肪酸酰胺）（例如月桂酸月季戊酸酰胺，油酸酰胺等），优选进一步为5-100pts.wt。 α，β-烯属不饱和羧酸[优选（甲基）丙烯酸]，3-150pts.wt。 二价金属化合物（优选氧化锌），0.2〜20pts.wt。 有机过氧化物（例如过氧化二异丙苯等）和> = 0.1pt.wt。 芳族仲胺化合物（例如N-异丙基-N'-苯基 - 对苯二胺等），得到所需组成。 效果：降低运输成本，防止火灾等。