公开(公告)号：WO1997014721A1

公开(公告)日：1997-04-24

申请号：PCT/US1996016471

申请日：1996-10-15

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： EASTMAN CHEMICAL COMPANY ,  WONDERS, Alan, George ,  MOORE, Glenn, Edward ,  FORD, Randal, Ray ,  DAILY, Jeffrey, Daniel ,  DOOLEY, Kenneth, Alan ,  GARCIA, Jesus, Jose

IPC: C08F02/34

CPC classification number: B01J8/388 ,  B01J8/005 ,  C08F210/16 ,  Y10S526/901 ,  C08F2/34 ,  C08F210/14 ,  C08F2500/24

Abstract: Disclosed is a method for controlling or reducing the amount of powder fines present in a polyethylene fluidized bed reactor. The method uses hydrocarbons that are inert with respect to the polymerization reaction, as well as using reactive olefins. The reduction of powder fines provides significant operating benefits in the fluid bed process, including reduced formation of powder agglomerates in the reactor and reduced fouling of equipment in the recycle gas stream.

Abstract translation: 公开了一种控制或减少存在于聚乙烯流化床反应器中的粉末的量的方法。 该方法使用在聚合反应中为惰性的烃，以及使用反应性烯烃。 粉末细粉的减少在流化床方法中提供了显着的操作益处，包括在反应器中减少粉末附聚物的形成并减少了循环气流中设备的结垢。

公开(公告)号：WO1997013799A1

公开(公告)日：1997-04-17

申请号：PCT/US1996015667

申请日：1996-09-30

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： EASTMAN CHEMICAL COMPANY ,  SUBLETT, Bobby, Jones

IPC: C08G63/199

CPC classification number: C08J5/18 ,  C08G63/189 ,  C08G63/199 ,  C08J2367/02 ,  Y10T428/249921 ,  Y10T428/29

Abstract: Disclosed are orientable, heat setable, semi-crystalline copolyesters which have high glass transition temperatures. These copolyesters have high heat distortion temperatures along with excellent molding and film properties which makes them useful in packaging materials and molded parts. These copolyesters have repeat units from 100 mol % 1,4-cyclohexanedimethanol, 1-99 mol % terephthalic acid and 99-1 mol % naphthalene dicarboxylic acid.

Abstract translation: 公开了具有高玻璃化转变温度的可取向的，可热固化的半结晶共聚酯。 这些共聚酯具有高的热变形温度以及优异的成型和薄膜性能，使得它们可用于包装材料和模制部件。 这些共聚酯具有100摩尔％1,4-环己烷二甲醇，1-99摩尔％对苯二甲酸和99-1摩尔％萘二甲酸的重复单元。

公开(公告)号：WO1996039378A1

公开(公告)日：1996-12-12

申请号：PCT/US1996008943

申请日：1996-06-05

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： EASTMAN CHEMICAL COMPANY ,  LUTZ, Gary, Paul ,  ZIMA, George, Chester ,  DICKASON, William, Charles

IPC: C07C303/00

CPC classification number: C07C231/12 ,  C07C303/22 ,  C07C303/32 ,  Y02P20/582 ,  C07C309/42

Abstract: This invention relates to a process for preparing amido ester compounds. The proces involves (I) forming a mixture in a reactor of a phenol derivative and an amido-carboxylic acid at a temperature which ensures at least partial solubility of the phenol derivative and the amido-carboxylic acid, and (II) adding a carboxylic anhydride incrementally to the mixture formed in Step (I) while distilling a by-product carboxylic acid from the reactor. The amido esters are useful as bleach activators.

Abstract translation: 本发明涉及一种制备酰胺酯化合物的方法。 方法涉及（I）在确保苯酚衍生物和酰氨基 - 羧酸至少部分溶解的温度下，在苯酚衍生物和酰氨基羧酸的反应器中形成混合物，和（II）加入羧酸酐 在步骤（I）中形成的混合物中，同时从反应器中蒸馏出副产物羧酸。 酰胺酯可用作漂白活化剂。

公开(公告)号：WO1996028246A1

公开(公告)日：1996-09-19

申请号：PCT/US1996002466

申请日：1996-02-23

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： EASTMAN CHEMICAL COMPANY ,  HASELTINE, Douglas, Mark ,  YOUNT, Thomas, Lloyd ,  RYANS, Jimmy, Lee

IPC: B01J03/00

CPC classification number: B01J3/006 ,  C08G63/785

Abstract: The present invention discloses a polymerization system having at least two reaction chambers wherein vacuum is used to remove vapors therefrom comprising a single vacuum system for supplying vacuum in increasing amounts to successive reaction chambers. Also disclosed is a polymerization process having at least first and second reaction chambers in which the pressure is decreased successively from said first chamber to a final chamber, said process comprising the steps of: maintaining a vacuum in said final chamber by removing final chamber vapors therefrom via a final chamber ejector connected thereto by a vacuum line; directing discharge from said final chamber ejector into a first chamber precondenser to produce first chamber non-condensed materials and condensed first chamber ejector motive fluid; directing said first chamber ejector non-condensed materials from said first chamber precondenser to a second ejector connected thereto by a vacuum line; directing discharge from said second ejector into a second condenser to produce second condenser non-condensed materials and condensed second ejector motive fluid; wherein said second condenser is connected to a vacuum pump.

Abstract translation: 本发明公开了一种具有至少两个反应室的聚合系统，其中使用真空来除去其中的蒸气，其中包括单个真空系统，用于以递增的量向连续的反应室提供真空。 还公开了一种具有至少第一和第二反应室的聚合方法，其中压力从所述第一室连续降低到最终室，所述方法包括以下步骤：通过从其中除去最终室蒸气来保持所述最终室中的真空度 通过真空管线连接到其的最终室喷射器; 引导从所述最终室喷射器排出到第一室预冷凝器中以产生第一室非冷凝材料和冷凝的第一室喷射器运动流体; 将所述第一室喷射器非冷凝材料从所述第一腔室预冷凝器引导到由真空管线连接到其的第二喷射器; 将所述第二喷射器排放到第二冷凝器中以产生第二冷凝器非冷凝材料和冷凝的第二喷射器运动流体; 其中所述第二冷凝器连接到真空泵。

公开(公告)号：WO1996026224A1

公开(公告)日：1996-08-29

申请号：PCT/US1996001557

申请日：1996-02-09

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： EASTMAN CHEMICAL COMPANY ,  WEBSTER, Dean, Charles ,  SU, Chih-Herng, James ,  FOSTER, Charles, Howard

IPC: C08F08/32

CPC classification number: C08G71/04 ,  C08F8/32 ,  Y10T428/31507 ,  Y10T428/31551 ,  C08F20/00

Abstract: Provided are curable copolymers having 1,3-dioxolan-2-one-4-yl groups incorporated therein. The copolymers are useful as binders in coating compositions and can be cured with primary amine cross-linking compounds to form a continuous polyurethane coating.

Abstract translation: 提供了其中并入有1,3-二氧戊环-2-酮-4-基的可固化共聚物。 共聚物可用作涂料组合物中的粘合剂，并且可以用伯胺交联化合物固化以形成连续的聚氨酯涂层。

公开(公告)号：WO1996020961A1

公开(公告)日：1996-07-11

申请号：PCT/US1995016563

申请日：1995-12-15

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： EASTMAN CHEMICAL COMPANY ,  EDGAR, Kevin, Joseph

IPC: C08B03/00

CPC classification number: C08B3/02 ,  C08B3/00 ,  C08B3/06 ,  C08B3/08

Abstract: The present invention relates to a process for preparing cellulose esters having a total DS/AGU of 0.1 to 3.0, said process consisting of contacting the following: (i) a cellulose material, (ii) a solubilizing amount of a solvent system comprising a carboxamide diluent or a urea-based diluent, (iii) an acylating reagent, and (iv) an insoluble sulfonic acid resin catalyst.

Abstract translation: 本发明涉及一种制备总DS / AGU为0.1至3.0的纤维素酯的方法，所述方法包括以下步骤：（i）纤维素材料，（ii）增溶量的包含甲酰胺的溶剂体系 稀释剂或脲基稀释剂，（iii）酰化试剂，和（iv）不溶性磺酸树脂催化剂。

公开(公告)号：WO1996019517A1

公开(公告)日：1996-06-27

申请号：PCT/US1995016439

申请日：1995-12-15

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： EASTMAN CHEMICAL COMPANY ,  WEAVER, Max, Allen ,  MILLS, David, Earl ,  TANNER, James, Thomas, III ,  FLEISCHER, Jean, Carroll ,  PRUETT, Wayne, Payton ,  MOODY, Leslie, Shane

IPC: C08G63/688

CPC classification number: C08G69/42 ,  C08G63/189 ,  C08G63/6886

Abstract: This invention relates to polymer compositions containing naphtalenedicarboxylic acid residues and having reduced fluorescence due to the presence of aromatic thioether compounds. More specifically, the polymer compositions contain poly(ethylene 2,6-naphthalene dicarboxylate) and 0.1 to 5 mole percent of an aromatic thioether compound. The polymers are useful for packaging applications where clarity and/or aesthetic appeal is important.

Abstract translation: 本发明涉及含有萘二甲酸残基并且由于存在芳族硫醚化合物而具有降低的荧光的聚合物组合物。 更具体地，聚合物组合物含有聚（2,6-萘二甲酸乙二醇酯）和0.1至5摩尔％的芳族硫醚化合物。 聚合物对于在清晰度和/或美学吸引力很重要的包装应用中是有用的。

公开(公告)号：WO1996017001A1

公开(公告)日：1996-06-06

申请号：PCT/US1995015026

申请日：1995-11-13

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： EASTMAN CHEMICAL COMPANY ,  MATAYABAS, James, Christopher, Jr. ,  MACKENZIE, Peter, B. ,  HYATT, John, Anthony

IPC: C08G65/20

CPC classification number: C08G65/14 ,  C08G65/20 ,  C08G65/322

Abstract: Disclosed are novel polyether compounds obtained by the reaction of polymerisation of 3,4-epoxy-1-butene in the presence of tetrahydrofuran, an acidic catalyst and a nucleophilic initiator compound. The polyether compounds comprise m units of residue (1), n units of residue (2), and p units of residue (3) wherein (i) residues (1), (2) and (3) have the structures (1), (2): -O-CH2-CH=CH-CH2-, and (3): -O-CH2-CH2-CH2-CH2-, (ii) the total value of m+n+p is 5 to 70; (iii) the value of n/(m+n+p) is in the range of 0.2 to 0.4, i.e., residue (2) constitutes from 20 to 40 mole percent of the total moles of residues (1), (2) and (3); and (iv) at least 98 percent of the terminal groups have the structure (4) or (5): HO-CH2-CH=CH-CH2-.

Abstract translation: 公开了通过在四氢呋喃，酸性催化剂和亲核引发剂化合物的存在下3,4-环氧-1-丁烯的聚合反应获得的新型聚醚化合物。 聚醚化合物包括m个残基（1），n个残基（2）单元和p个残基（3）单元，其中（i）残基（1），（2）和（3）具有结构（1） ，（2）：-O-CH2-CH = CH-CH2-和（3）：-O-CH2-CH2-CH2-CH2-，（ii）m + n + p的总值为5至70 ; （iii）n /（m + n + p）的值在0.2至0.4的范围内，即，残基（2）构成残基（1），（2）的总摩尔数的20至40摩尔％ 和（3）; 和（iv）至少98％的端基具有结构（4）或（5）：HO-CH 2 -CH = CH-CH 2 - 。

公开(公告)号：WO1996011963A2

公开(公告)日：1996-04-25

申请号：PCT/US1995013499

申请日：1995-10-10

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： EASTMAN CHEMICAL COMPANY ,  SEEGER, Horst, Kurt ,  HOLLIDAY, Robert, Emmett

IPC: C08F110/14

CPC classification number: C08F6/02 ,  C08F110/14 ,  C08L23/00 ,  C08F2/06 ,  C08F2/14 ,  C08F2500/17

Abstract: A process for the production of amorphous polyolefins is disclosed. The process entails contacting the olefin monomer, in an unreactive hydrocarbon solvent, with a catalyst in a recirculated, stirred reactor thereby producing amorphous polyolefin. The reactor is capable of recirculating contents that are very viscous.

Abstract translation: 公开了一种生产无定形聚烯烃的方法。 该方法需要使烯烃单体在非反应性烃溶剂中与催化剂在再循环的搅拌反应器中接触，由此生产无定形聚烯烃。 反应器能够使非常粘稠的内容物再循环。

公开(公告)号：WO1996010620A1

公开(公告)日：1996-04-11

申请号：PCT/US1995012191

申请日：1995-09-25

Applicant: EASTMAN CHEMICAL COMPANY

Inventor： EASTMAN CHEMICAL COMPANY ,  KRUTAK, James, John, Sr. ,  CUSHMAN, Michael, Roy ,  WEAVER, Max, Allen

IPC: C10L01/00

CPC classification number: C10L1/003 ,  C10L1/232 ,  C10L1/233 ,  C10L1/24 ,  C10L1/2406 ,  C10L1/2412 ,  C10L1/2418 ,  C10L1/2431 ,  C10L1/2437 ,  C10L1/245 ,  C10L1/2456 ,  C10L1/28 ,  C10L1/30 ,  C10L1/301 ,  C10L1/305 ,  C10L1/308 ,  C10M171/007 ,  G01N33/2882 ,  Y10T436/13

Abstract: This invention provides a method for imparting invisible markings for identification purposes to petroleum hydrocarbons by incorporating one or more infrared fluorescing compounds therein. Certain infrared fluorophores from the classes of squaraines (derived from squaric acid), phthalocyanines and naphthalocyanines are useful in providing invisibly marked petroleum hydrocarbons such as crude oil, lubricating oils, waxes, gas oil (furnace oil), diesel oil, kerosene and in particular gasoline. The near infrared fluorophores are added to the hydrocarbons at extremely low levels and are detected by exposing the marked hydrocarbon compositions to near infrared radiation having a wavelength in the 670-850 nm range and then detecting the emitted fluorescent light via near infrared light detection means.

Abstract translation: 本发明提供了一种通过在其中掺入一种或多种红外荧光化合物来赋予石油烃识别目的的不可见标记的方法。 来自方酸类（衍生自方酸），酞菁和萘酞菁的某些红外荧光团可用于提供不可见的石油烃，例如原油，润滑油，蜡，瓦斯油（炉油），柴油，煤油 汽油。 将近红外荧光团以非常低的水平添加到烃中，并通过将标记的烃组合物暴露于具有在670-850nm范围内的波长的近红外辐射，然后通过近红外光检测装置检测发射的荧光来检测。