公开(公告)号：GB1174741A

公开(公告)日：1969-12-17

申请号：GB2728568

申请日：1968-06-07

Applicant: OREAL

Inventor： ZVIAK CHARLES ,  GHILARDI GIULIANA

IPC: D06P3/14

Abstract: 1,174,741. Hair dye compositions. L'OREAL. 7 June, 1968 [9 June, 1967], No. 27285/ 68. Heading D1B. A composition suitable for dying animal fibres e.g. dead or live hair at below 50‹C comprises a solution of one or more direct dyes (as defined) dissolved in an homogenous mixture of water and a diol of formula I in which R is a straight or branched chain alkyl radical of 3-8 carbon atoms, a phenyl, benzyl or cyclohexyl radical and n is an integer from 1-4 preferably 1-15% by weight of diol is present and diols specified are 3- amyloxy-1, 2-propanediol, 3-benzyloxy-1, 2- propanediol, and 3-phenoxy-1. 2-propanediol, other organic solvents may also be present. Direct dyes are defined as any colouring substance which is capable of being directly fixed in the fibre in its final shade without the necessity of effecting any chemical transformation, thus nitro, disperse, basic acid dyes and pigments containing solvents are included.

公开(公告)号：DE1492080A1

公开(公告)日：1969-08-07

申请号：DE1492080

申请日：1965-12-23

Applicant: OREAL

Inventor： ZVIAK CHARLES ,  GHILARDI GUILIANA

IPC: C09B51/00

公开(公告)号：GB1158615A

公开(公告)日：1969-07-16

申请号：GB1379167

申请日：1967-03-23

Applicant: OREAL

Inventor： ZVIAK CHARLES ,  BEAULIEU HENRI DE

IPC: A61K8/46 ,  A61Q5/04 ,  C14C9/00 ,  D06M13/252

Abstract: 1,158,615. Aerosol compositions. L'OREAL. 23 March, 1967 [23 March, 1966], No. 13791/67. Heading C4X. [Also in Divisions C6 and D1] An aerosol composition used in the treatment of keratinic fibres comprises a composition having a #H greater than 7 and containing at least one thiol and at least one disulphide of a thiol, the molar ratio of the disulphide to the thiol being at least 1:1. The thiol may be thioglycerol, thioglycollic acid, glycol thioglycollate, glycerol thioglycollate, glycol thiolactate, thiolactic acid, #-mercapto-ethanol or N - carboxymethyl - mercaptoacetamide, and the disulphide may be a disulphide of these thiols. The composition may contain 0À5-10% by weight of the thiol and 3-25% by weight of the disulphide, and may be adjusted to the desired pH by the addition of ammonia or monoethanolamine. Propellants mentioned include butane and " Freon 12 " (Trade Mark).

公开(公告)号：GB1101628A

公开(公告)日：1968-01-31

申请号：GB773266

申请日：1966-02-22

Applicant: OREAL

Inventor： ZVIAK CHARLES ,  VIOUT ANDRE

IPC: A61K8/81 ,  A61Q5/04 ,  A61Q5/06 ,  C08F8/00 ,  C08F8/34 ,  D06M15/273 ,  D06M15/285 ,  D06P1/52

Abstract: A composition suitable for treating keratinous fibre fabrics comprises a solution of a polysulph-hydryl polymer which is a polymer in which the backbone consists of saturated carbon atoms or saturated carbon atoms and oxygen, nitrogen or sulphur atoms which contains one or, at more or less regular intervals, more -SH radicals either joined directly to the polymer chain or via intermediate groupings, e.g. amide and ester groupings. The solution may contain 1-20% by weight of the polysulph-hydryl polymer and may be adjusted to a pH of 3.5-10 by, for example, the addition of ammonia or monoethanolamine. Specified polymers are those obtained by the reaction of b -mercapto ethylamine with a styrene/maleic anhydride copolymer or maleic anhydride/ethylene copolymer, by the reaction of N-(b -aminoethyl)thioglycolamide with an ethylene/maleic anhydride copolymer, by the reaction of b -mercaptoethylamine and N,N-diethylpropylene diamine with an ethylene/maleic anhydride copolymer, by the reaction of b -mercaptoethylamine and n-butylamine with a vinyl acetate/maleic anhydride copolymer, by the reaction of b -mercaptoethylamine or N(b -aminoethyl)-thioglycolamide with a vinyl acetate/maleic anhydride copolymer or by the reaction of b -mercaptoethylamine alone or in admixture with butylamine with poly-(maleic anhydride). The composition may be in the form of an aerosol composition the propellant being dichlorodifluoromethane, trichloromonofluoromethane or butane, and optionally containing an anti-foam silicone, a fatty alcohol polyethyoxyether or alkyl phenol polyethoxyether, or may be applied by means of a rotating ball liquid dispenser bottle.ALSO:An aerosol composition suitable for treating keratinous fibre fabrics comprises a solution of a polysulph-hydryl polymer which is a polymer in which the backbone consists of saturated carbon atoms or saturated carbon atoms and oxygen, nitrogen or sulphur atoms which contains one or, at more or less regular intervals, more -SH radicals either joined directly to the polymer chain or via intermediate groupings, e.g. amide and ester groupings. The solution may contain 1-20% by weight of the polysulph-hydryl polymer and may be adjusted to a pH of 3.5-10 by, for example, the addition of ammonia or monoethanolamine. The propellent may be dichlorodifluoromethane, trichloromonofluoro-methane or butane and the composition may optionally contain an anti-foam silicone, a fatty alcohol polyethoxyether or alkyl phenolpolyethoxyether, specified polymers are those obtained by the reaction of b -mercapto ethylamine with a styrene/maleic anhydride copolymer or maleic anhydride/ethylene copolymer, by the reaction of N-(b -aminoethyl) thioglycolamide with an ethylene/maleic anhydride copolymer, by the reaction of b -mercaptoethylamine and N,N-diethylpropylene diamine with an ethylene/maleic anhydride copolymer, by the reaction of b -mercaptoethylamine and n-butylamine with a vinyl acetate/maleic anhydride copolymer, by the reaction of b -mercaptoethylamine or N-(b -aminoethyl)-thioglycolamide with a vinyl acetate/maleic anhydride copolymer or by the reaction of b -mercaptoethylamine alone or in admixture with butylamine with poly (maleic anhydride).ALSO:Durable creases are imparted to fabrics comprising keratinic fibres, e.g. wool, alpaca, camel hair or mohair, by treating them with a solution of a polysulph-hydryl polymer at the location where it is desired to form the crease and forming the crease by applying heat and pressure, e.g. by means of a hot iron or clothes press, to the impregnated fabric while it is arranged in the form of a crease. The polysulph-hydryl polymer is a polymer in which the backbone consists of saturated carbon atoms or saturated carbon atoms and oxygen, nitrogen or sulphur atoms which contains one or, at more or less regular intervals, more -SH radicals either joined directly to the polymer chain or via intermediate groupings, e.g. amide and ester groupings. An aqueous solution containing 1-20% by weight of the polysulph - hydryl polymer and having a pH of 3.5-10 adjusted by, for example, the addition of ammonia or monoethanol amine may be used. Polysulph-hydryl polymers obtained by the reaction of b -mercapto ethylamine with a styrene/maleic anhydride copolymer or maleic anhydride/ethylene copolymer, by the reaction of N-(b -aminoethyl) thioglycolamide with an ethylene/maleic anyhydride copolymer by the reaction of b -mercapto ethylamine and N,N-diethylpropylene diamine with an ethylene/maleic anhydride copolymer, by the reaction of b -mercapto ethylamine and n-butylamine with a vinyl acetate/maleic anhydride copolymer by the reaction of b -mercaptoethylamine or N-(b -aminoethyl)-thioglycolamide with a vinyl acetate/maleic anhydride copolymer or by the reaction of b -mercaptoethylamine alone or in admixture with butylamine with poly(maleic anhydride) are examples of numerous suitable polymers indicated. The treating composition may be used in the form of an aerosol composition, the propellent being dichlorodifluoromethane, trichloromonofluoromethane or butane, and optionally containing an anti-foam silicone, a fatty alcohol polyethoxyether or alkylphenol polyethoxyether, or may be applied by means of a rotating ball liquid dispenser bottle. The fabric may be a woven or knitted fabric, lace or felt.

公开(公告)号：FR1455788A

公开(公告)日：1966-10-21

申请号：FR983968

申请日：1964-08-03

Applicant: OREAL

Inventor： KALOPISSIS GREGOIRE ,  ROUSSOPOULOS PAUL ,  ZVIAK CHARLES

IPC: A45D7/04 ,  A61K20060101 ,  A61K8/46 ,  A61Q5/04

公开(公告)号：FR87224E

公开(公告)日：1966-07-01

申请号：FR2339

申请日：1965-01-18

Applicant: OREAL

Inventor： KALOPISSIS GREGOIRE ,  ZVIAK CHARLES ,  VIOUT ANDRE

IPC: A61K8/81 ,  A61Q5/06 ,  C08F8/30 ,  C08F8/32 ,  C08F8/34 ,  C08F228/00 ,  C08G59/18

Abstract: A polymer has a recurring structural unit of formula in which R1 and R11 are -H, a C1- 4 alkyl or alkoxy radical or a phenyl radical, R111 is -H, -OCOCH3, -COOCH3 or -CN, Y is Q or Q1, where is where R1 is -H or -CH3, R2 is -H or -COOH, q is 1-5, q1 and p are 0 or 1 and Q1 is where R3 is -H, or a C1- 4 alkyl radical, R4 is R3 or where the r's are a C1- 4 alkyl radical or, together with the N-atom to which they are attached, form a heterocyclic ring, and m is 2-4; the polymer containing both Q and Q1. The polymer may be produced by condensing an amino-thiol and an alkylamine with a copolymer having the repeating unit where the symbols in the formulae are as above. In examples, methyl acrylate, methyl methacrylate, acrylonitrile, vinyl acetate, ethylene or styrene-maleic an hydrid copolymer was condensed with b -mercapto ethylamine, cysteine or N - (b - aminoethyl) thioglycolamide and N,N - diethylpropylene diamine, n-butyl-amine or N-(b -aminoethyl) morpholine. The polymers may be compounded with (A) a vinyl pyrrolidone/vinyl acetate copolymer, water, ethyl alcohol, the tetrasodium salt of ethylene diamine tetracetic acid and 2-amino-2-methyl-1-propanol, triethanolamine or N,N-dimethyl ethanolamine, or (B) a cetyl-stearyl alcohol/ethylene oxide condensate and an aerosol propellant, e.g. a fluorinated hydrocarbon.ALSO:Human hair is set and the receptivity of textile keratinic fibres towards reactive dyes is improved by treatment with a polymer having the repeating unit where R1 and R11 are -H, a C1-4 alkyl or alkoxy radical or a phenyl radical, R111 is -H, -OCOCH3, -COOCH3 or -CN, Y is Q or Q1 where Q is where R1 is -H or -CH3, R2 is -H or -COOH, q is 1-5, q1 and p are 0 or 1 and Q1 is where R3 is -H or a C1-4 alkyl radical, R4 is R3 or where the r's are a C1-4 alkyl radical 2 or 1 together with the N-atom to which they are attached, form a heaterocyclic ring, and m is 2-4; the polymer containing both Q and Q1. In examples the polymer resulting from the condensation of b -mercaptoethylamine or N-(b -aminoethyl)thioglycolamide and N,N-diethylpropylenediamine or butylamine with an ethylene vinyl acetate, methyl methacrylate or acrylonitrile and maleic anhydride copolymer was compounded with water ethanol, the tetrasodium salt of ethylene diamine tetracetic acid and 2-amino-2-methyl-1-propanol, triethanolamine or N,N-dimethyl ethanolamine to form a setting lotion for human hair and with a cetyl-stearyl alcohol/ethylene oxide condensate and a fluorinated hydrocarbon to form an aerosol foam for hair.ALSO:A setting lotion or aerosol foam for human hair contains a polymer having a recurring structural unit of formula (I) in which R1 and R11 are -H, a C1-4 alkyl or alkoxy radical or a phenyl radical R111 is -H, -OCOCH3, -COOCH3 or -CN, Y is Q or Q1 where Q is (II) where R1 is -H or -CH3, R2 is -H or -COOH, q is 1-5, q and p are 0 or 1 and Q1 is (III) where R3 is -H, or a C1-4 alkyl radical, R4 is R3 or where the r's are a C1-4 alkyl radical or, together with the N-atom to which they are attached, form a heterocyclic ring, and m is 2-4; the polymer containing both Q and Q1. In examples the polymer resulting from the condensation of b -mercapto-ethylamine or N-(b -aminoethyl) thioglycolamide and N,N-diethylpropylene-diamine or butylamine with an ethylene, vinyl acetate, methyl methacrylate or acrylonitrile and maleic anhydride copolymer was compounded with a vinyl pyrrolidone vinyl acetate copolymer, water, ethyl alcohol, the tetrasodium salt of ethylene diamine tetracetic acid and 2-amino-2-methyl-1-propanol, triethanolamine or N,N-dimethyl ethanolamine to form a setting lotion and with a cetylstearyl alcohol/ethylene oxide condensate and an aerosol propellant, e.g. a fluorinated hydrocarbon, to form an aerosol foam.

公开(公告)号：FR1377301A

公开(公告)日：1964-11-06

申请号：FR936137

申请日：1963-05-27

Applicant: OREAL

Inventor： ZVIAK CHARLES ,  GHILARDI GIULIANA

公开(公告)号：GB974611A

公开(公告)日：1964-11-04

申请号：GB2466963

申请日：1963-06-20

Applicant: OREAL

Inventor： ZVIAK CHARLES ,  ROUET JEAN

IPC: A61K20060101 ,  A61K8/43 ,  A61K8/46 ,  A61K8/49 ,  A61Q9/04 ,  C14C1/06

Abstract: A depilatory composition comprises in admixture one or more thiol acids or alkaline earth metal salts thereof and, as accelerator for the action thereof, melamine or dicyandiamide or both. 0.5 to 2.0 parts of accelerator per part of thiol acid or salt may be used. Preferred thiol acids are thiolactic acid, thioglycolic acid and b -mercapto propionic acid. Preferred salts are the calcium and strontium salts. The pH of the composition is preferably 12. Optional additions, apart from the depilatory base, are urea or thiourea.

公开(公告)号：CA626244A

公开(公告)日：1961-08-22

申请号：CA626244D

Applicant: OREAL

Inventor： ZVIAK CHARLES

公开(公告)号：FR1200498A

公开(公告)日：1959-12-22

申请号：FR1200498D

申请日：1958-06-26

Applicant: OREAL

Inventor： ZVIAK CHARLES

IPC: A61K8/46 ,  A61K8/67 ,  A61K31/045 ,  A61Q5/02 ,  C11D1/00

Abstract: A hair shampoo comprises an aqueous or alcoholic solution of a detergent and 0,2 to 10% of a compound of the formula:- where X denotes OH, NH2OR or -NH(C2H4OH)3 and where R is an alkyl or hydroxyalkyl group containing not more than 3 carbon atoms together with one or more adjuvants. Specified detergents are trimethylcetyl-ammonium chloride, triethanolamine lauryl sulphate and sodium lauroylsarcosinate. When the detergent is of the cationic type and the composition has an acid p.H., the thiodiglycollic acid is present in the form of its amide or the acid per se. Other additives include essential oils, e.g. cedar, cade or lavender oil; perfume; amino compounds e.g. glutamic acid or cystine; vitamin products e.g. calcium partothenate, ethyl nicotinate and pantothenic alcohol; superfatting products, e.g. glycol oleate or glycerol stearate; magnesium stearate, alcohol-soluble ethoxylated lanolin alcohols, methyl methacrylate and salicylic acid.ALSO:A hair-tonic composition comprises an aqueous or ethyl alcoholic solution containing from 0.2 to 10% of a compound of general formula where X denotes Oh, NH2, OR or -ONH (C2H4OH)3 and where R represents an alkyl or hydroxy alkyl group containing not more than 3 carbon atoms together with one or more adjuvants. Specified active ingredients are the ethyl and diglycollic ester, the diamide, the triethanolamine salt of thiodiglycollic acid and the acid per se. The composition may be in the form of (a) a lotion having as adjuvant an essential oil e.g. cedar, cade or lavender oil or a perfume; or (b) a shampoo containing a detergent material e.g. trimethyl cetyl ammonium chloride, triethanolamine lauryl sulphate or sodium lauroyl sarcosinate. When the detergent is cationic in nature thiodiglycollic acid or its amide are used. Other additives are amino compounds e.g. glutamic acid or cystine; vitamin products e.g. calcium pantothenate, ethyl nicotinate and pantothenic alcohol; superfatting products e.g. glycol oleate or glycerol stearate; magnesium stearate, alcohol-soluble ethoxylated lanolin alcohols, methyl methacrylate and salicylic acid.