公开(公告)号：JPH0747780A

公开(公告)日：1995-02-21

申请号：JP21209893

申请日：1993-08-05

Applicant: TORAY INDUSTRIES

Inventor： SUMIYA TAKASHI ,  HORIUCHI SATORU ,  HIRAOKA TOSHIHIKO

IPC: B32B27/00 ,  B32B27/08 ,  B32B27/36 ,  B32B33/00 ,  B41N1/24

Abstract: PURPOSE:To reduce adhesion to a thermal head, to provide high sensitivity and excellent curl by providing specific values of peak peeling temperature, melting energy and glass transition temperature of characteristics of resins of layers of a two-layer laminated film and providing specific relationship between the peeling temperature and the transition temperature of each layer. CONSTITUTION:A two-layer laminated film comprises a layer A and a layer B, wherein characteristics of resins of the layers are such that the layer A has a peak melting temperature TmA>=150 deg.C, melting energy DELTAHA>=0.1cal/g, and glass transition temperature TgA>=30 deg.C, and the layer B has a peak melting temperature TmB =TmB+5 deg.C, TgA>=TgB+3 deg.C. As a result, a thermal head has low adhesion, high sensitivity, and further the film for a thermal stencil printing base sheet having excellent curl, printing durability can be obtained.

公开(公告)号：JPH073049A

公开(公告)日：1995-01-06

申请号：JP4770794

申请日：1994-02-21

Applicant: TORAY INDUSTRIES

Inventor： SUMIYA TAKASHI ,  FUNAYAMA NOBUTAKA ,  KUROME TAIICHI

IPC: B29C55/02 ,  B29K67/00 ,  B29L7/00 ,  B29L9/00 ,  B32B7/02 ,  B32B27/20 ,  B32B27/36 ,  B41M5/00 ,  B41M5/50 ,  B41M5/52 ,  C08J5/18 ,  C08K3/00 ,  C08L67/00 ,  C08L67/02

Abstract: PURPOSE:To obtain a polyester-based film excellent in printing accuracy and folding property and useful as a base for receiving image by including a thermoplastic polyolefin-based resin, polystyrene-based resin and inorganic particles in specific amounts. CONSTITUTION:The palyester-based film contains (A) 2.5-30wt.% of a thermoplastic polyolefin-based resin and a polystyrene-based resin and (B) two or more kinds of inorganic particles. Furthermore, a laminated polyester-based film obtained by laminating a stretched polyester-based film having >=1mum thickness and containing

公开(公告)号：JPH06293120A

公开(公告)日：1994-10-21

申请号：JP10742893

申请日：1993-04-08

Applicant: TORAY INDUSTRIES

Inventor： HORIUCHI SATORU ,  YAMAMOTO KENJI ,  SUMIYA TAKASHI

IPC: B32B27/36 ,  G09F3/02

Abstract: PURPOSE:To simultaneously embody both of surface ink adhesion and the optimum glossiness in a polyester film for a label. CONSTITUTION:In a polyester film for a label, a B-layer composed of a polyester resin B copolymerlzed with cyclohexanedimethanol is laminated on at least the single surface of an A-layer composed of a polyester resin A and, next, a C-layer composed of a water-soluble or water-dispersible resin is laminated on the B-layer and embossing processing is applied to the surface of the C-layer.

公开(公告)号：JPH06286055A

公开(公告)日：1994-10-11

申请号：JP22647693

申请日：1993-08-18

Applicant: TORAY INDUSTRIES

Inventor： SUMIYA TAKASHI ,  TANAKA IWAO ,  KUROME TAIICHI ,  SHIBATSUJI KUNIO

IPC: B29C55/12 ,  B29K67/00 ,  B29L7/00 ,  B32B15/08 ,  B32B15/09

Abstract: PURPOSE:To obtain a laminate of metal and film which has excellent molding processability and impact resistance and sufficient practical use by thermally a polyester biaxially oriented film in which orientation degrees in all directions are specified on a base material of a metal plate. CONSTITUTION:A laminate comprises a polyester biaxially oriented film thermally adhered to a metal plate base material, wherein formulae are satisfied, where lateral orientation degrees of the film perpendicular to a film flowing direction at a thermal adherence side are AMD, ATD, lateral orientation degrees of the film to the film flowing direction at a center in a film thickness direction are CMD, CTD and lateral orientation degrees of the film in the film flowing direction at a non-thermal adherence side are BMD, BTD, and a difference of orientation degrees between lateral directions to the film flowing direction at all positions of the film is 0.5 or less.

公开(公告)号：JPH06271686A

公开(公告)日：1994-09-27

申请号：JP8692393

申请日：1993-03-23

Applicant: TORAY INDUSTRIES

Inventor： SUMIYA TAKASHI ,  TANAKA IWAO ,  KUROME TAIICHI ,  SHIBATSUJI KUNIO

IPC: B32B15/08 ,  B32B27/36 ,  C08J3/22 ,  C08J5/18 ,  C08K3/16 ,  C08K3/20 ,  C08K3/22 ,  C08L67/02 ,  C08L101/00

Abstract: PURPOSE:To obtain a white film having excellent formability and impact resistance and useful for the metal lamination use, etc., by diluting a resin loaded with a large amount of inorganic particles with a specific resin and forming the blended resin. CONSTITUTION:The objective white film is produced by diluting (A) a resin (e.g. polyester resin) filled with a large amount of inorganic particles such as rutile titanium oxide having an average particle diameter of 0.1-0.5mum with (B) other resin preferably containing >=10wt.% of a resin B' having an intrinsic viscosity higher than that of the resin A by 0.03 and forming the blended resin composition in the form of a film.

公开(公告)号：JPH05246169A

公开(公告)日：1993-09-24

申请号：JP8294492

申请日：1992-03-06

Applicant: TORAY INDUSTRIES

Inventor： SUMIYA TAKASHI ,  HORIUCHI SATORU ,  YANAGA SUSUMU

IPC: B41N1/24

Abstract: PURPOSE:To make the title stencil paper excellent in all of characteristics of curling resistance, printing sharpness, omission resistance, sensitivity, durability and head abrasion resistance by adding a specific amount of spherical particles having a specific particle size to a thermal film layer composed of a specific polyester resin. CONSTITUTION:A thermal stencil paper is characterized by that the melt energy of a polyester resin constituting the thermal film laminated to a porous support is 12.5cal/g or less and 0.01-6wt.% of spherical particles whose particle size is 0.2-4.0 times the thickness of the film are added to the film.

公开(公告)号：JPH04316829A

公开(公告)日：1992-11-09

申请号：JP8404191

申请日：1991-04-16

Applicant: TORAY INDUSTRIES

Inventor： SUMIYA TAKASHI ,  FUNAYAMA NOBUTAKA ,  YAMAGISHI HIDEKI

IPC: B29C55/12 ,  B29K67/00 ,  B29K105/16 ,  B29L7/00 ,  B32B27/36 ,  C08J5/18 ,  C08L67/00

Abstract: PURPOSE:To provide the title film excellent in transparency and processability, stabilized in thermal behavior after processing and suppressed in the lowering of the flatness of the film due to heat shrinkage such as unevenness or a curl. CONSTITUTION:A polyester biaxially stretched film is characterized by that at least two heat absorption peaks observed other than a melting peak is observed at the time of thermal analysis and the difference between the heat absorption peak of the highest temp. and that of the lowest temp. excepting the melting peak is within the range of 20-130 deg.C and heat shrinkage factors in longitudinal and lateral directions at 150 deg.C is 0.8 to -0.5% and the presence probability (Ps) of inorg. particles in the surface layer of at least a single surface and the presence probability (Pc) of inorg. particles in the center part of the film become Ps>2Pc.

公开(公告)号：JPH03292140A

公开(公告)日：1991-12-24

申请号：JP9612790

申请日：1990-04-10

Applicant: TORAY INDUSTRIES

Inventor： SUMIYA TAKASHI ,  YAMAGISHI HIDEKI ,  FUNAYAMA NOBUTAKA

IPC: B32B27/36

Abstract: PURPOSE:To obtain good transparency and easy slip properties and to prevent the generation of rupture at the time of film formation by providing a base material layer composed of a polyester resin having intrinsic viscosity A and the film layer having thickness Tmum and composed of a polyester resin film having intrinsic viscosity B containing inorg. particles having an average particle size (d)mum and setting A, B, T, (d) so as to satisfy specific conditions. CONSTITUTION:A base material layer composed of a polyester resin having intrinsic viscosity A and the film layer having thickness Tmum and composed of a polyester resin having intrinsic viscosity B containing inorg. particles having an average particle size (d)mum are provided and B, A, T, (d) satisfy conditions of 0.5>=B-A>=0.02 and 25>=T/d>=1.5. The average particle size (d) of the inorg. particles is set to 0.2 - 1.0mum and the addition amount of the inorg. particles to the polyester resin having intrinsic viscosity B is set to 1wt.% or less. When the polyester resin having intrinsic viscosity higher than that of the base material layer is used on the side of the film layer, the rupture at the time of film formation can be reduced. Further, since the height of the projections formed on the side of the film layer by org. particles can be increased at the stretching time of a film, good easy slip properties can be imparted.

公开(公告)号：JPH02158915A

公开(公告)日：1990-06-19

申请号：JP31442488

申请日：1988-12-12

Applicant: TORAY INDUSTRIES

Inventor： SUMIYA TAKASHI ,  YAMAGISHI HIDEKI ,  KUBOYAMA HIROSHI

IPC: G11B5/80 ,  C09D127/06 ,  C09D133/06 ,  C09D167/02 ,  C09D175/04 ,  G11B5/73 ,  G11B5/733 ,  G11B5/738

Abstract: PURPOSE:To improve the moisture resistant adhesiveness of a resin layer and base material film and to eliminate the defect by the cleavage of the resin layer by providing a magnetic recording layer on a polyester film which has the resin layer having a prescribed degree of orientation and thickness and consisting of a water soluble or water dispersible resin on one surface and which has the optical density of a prescribed value or above. CONSTITUTION:The magnetic recording layer is formed on the polyester film which has the resin layer having 0.03 to 0.6 degree of orientation and 0.001 to 3.0mum thickness and consisting of the water soluble or water dispersible resin on one surface and has >=0.5 optical density and >=80% whiteness and the magnetic recording card is constituted of the polyester film formed with such magnetic recording layer. The water soluble or water dispersible resin of this magnetic card is an acrylic resin, polyester resin, urethane resin or vinyl resin or the mixture composed thereof. The moisture resistant adhesiveness of the resin layer and the base material film is thus improved and the adhesion defect by the cleavage of the resin layer is prevented.

公开(公告)号：JPH0224193A

公开(公告)日：1990-01-26

申请号：JP17422988

申请日：1988-07-12

Applicant: TORAY INDUSTRIES

Inventor： SUMIYA TAKASHI ,  YAMAGISHI HIDEKI ,  MIMURA TAKASHI

IPC: B41M5/382 ,  B41M5/26 ,  B41M5/50 ,  B41M5/52

Abstract: PURPOSE:To prevent decrease of sensitivity, and density decrease and fading of a recorded image from occurring by adding a polymer having a specific repetitive unit as a main component within a specific range rate in a sublimate dye accepting layer. CONSTITUTION:A sublimate dye accepting layer contains 5wt.% or over up to and including 95wt.% of a polymer A having a repetitive unit as given in the formula I as a main component in a sublimate transfer recording image receiving having the sublimate dye accepting layer at least on its side surface. In the formula I, R indicates hydrogen, or methyl radical, M indicating hydrogen, alkali metal, alkali earth group or ammonium, and R1, R2, R3 and R4 indicate respectively hydrogen, halogen, alkyl radical or alkoxy radical. As a representative example of a polymer having such a structure, a copolymer with acrylic acid, acrylic ester, methacrylic acid, methacrylic ester or styrene in a form of the formula II, and otherwise a polymer composed of only the formula III can be exemplified. Sensitivity is increased thereby, and density decrease and fading of an image when recording speed is increased are prevented.