Fuel composition
    73.
    发明授权
    Fuel composition 有权
    燃油组成

    公开(公告)号:US08852299B2

    公开(公告)日:2014-10-07

    申请号:US11427843

    申请日:2006-06-30

    Applicant: Allen A. Aradi

    Inventor: Allen A. Aradi

    CPC classification number: C10L1/305 C10L1/00 C10L1/1241 C10L10/10 C10L2300/20

    Abstract: There is disclosed a method for combusting a secondary organometallic compound in an engine including (a) combining a secondary organometallic compound and methylcyclopentadienyl manganese tricarbonyl, (b) introducing the combination from (a) into a fuel, and (c) causing the fuel from (b) to be combusted in the engine.

    Abstract translation: 公开了一种在发动机中燃烧次级有机金属化合物的方法,其包括(a)将次级有机金属化合物和甲基环戊二烯基三羰基锰组合,(b)将来自(a)的组合引入燃料中,和(c) (b)在发动机中燃烧。

    Low-emissions diesel fuel blend
    74.
    发明授权
    Low-emissions diesel fuel blend 有权
    低排放柴油混合物

    公开(公告)号:US07285140B2

    公开(公告)日:2007-10-23

    申请号:US10357027

    申请日:2003-02-03

    Abstract: A low-emissions diesel fuel comprises a catalyzed blend of fatty acid esters, preferably derived from soybean oil and/or tallow and aviation kerosene. The catalyzed blend is effective in lowering regulated emission pollutants, among which are NOx, particulates, hydrocarbons and carbon monoxide. The catalyst will comprise fuel-soluble platinum and/or cerium or iron. The cerium or iron are typically employed at concentrations of from 2 to 25 ppm and the platinum from 0.05 to 2 ppm, with preferred levels of cerium or iron being from 5 to 10 ppm, e.g., 7.5 ppm, and the platinum being employed at a level of from 0.1 to 0.5 ppm, e.g., 0.15 ppm. A preferred ratio of cerium and/or iron to platinum is from 75:1 to 10:1. The jet fuel component will typically be employed at a volume ratio to the fatty acid esters of from about 2:1 to about 5:1, e.g., about 4:1. The full range of blends extends from 50:1 to 1:50 with some benefit. The jet fuel component of the blend preferably contains grade 55, 50-300 ppm detergent, 25 to about 500 ppm lubricity additive and 0.1-1 ppm platinum COD and 5-20 ppm cerium oleate or octoate. In addition to the fuel blend, a method is provided for reducing the emissions of pollutants from a diesel engine, comprising running the engine on a fuel as defined.

    Abstract translation: 低排放柴油包括脂肪酸酯的催化混合物,优选衍生自大豆油和/或牛脂和航空煤油。 催化的共混物有效地降低了调节的排放污染物,其中包括无机颗粒,碳氢化合物和一氧化碳。 催化剂将包括燃料可溶的铂和/或铈或铁。 通常使用铈或铁的浓度为2至25ppm,铂为0.05至2ppm,优选的铈或铁的含量为5至10ppm,例如7.5ppm,铂用于 水平为0.1至0.5ppm,例如0.15ppm。 铈和/或铁与铂的优选比例为75:1至10:1。 通常,喷气燃料组分的使用量与脂肪酸酯的体积比为约2:1至约5:1,例如约4:1。 混合物的范围从50:1增加到1:50,具有一定的优势。 共混物的喷气燃料组分优选含有55级,50-300ppm洗涤剂,25-约500ppm润滑性添加剂和0.1-1ppm铂COD和5-20ppm油酸铈或辛酸铈。 除了燃料混合物之外,还提供了一种用于减少来自柴油发动机的污染物排放的方法,包括以定义的燃料运行发动机。

    LOW-EMISSIONS DIESEL FUEL BLEND
    75.
    发明申请
    LOW-EMISSIONS DIESEL FUEL BLEND 有权
    低排放柴油燃料混合

    公开(公告)号:US20070209272A1

    公开(公告)日:2007-09-13

    申请号:US10357027

    申请日:2003-02-03

    Inventor: James Valentine

    Abstract: A low-emissions diesel fuel comprises a catalyzed blend of fatty acid esters, preferably derived from soybean oil and/or tallow and aviation kerosene. The catalyzed blend is effective in lowering regulated emission pollutants, among which are NOx, particulates, hydrocarbons and carbon monoxide. The catalyst will comprise fuel-soluble platinum and/or cerium or iron. The cerium or iron are typically employed at concentrations of from 2 to 25 ppm and the platinum from 0.05 to 2 ppm, with preferred levels of cerium or iron being from 5 to 10 ppm, e.g., 7.5 ppm, and the platinum being employed at a level of from 0.1 to 0.5 ppm, e.g., 0.15 ppm. A preferred ratio of cerium and/or iron to platinum is from 75:1 to 10:1. The jet fuel component will typically be employed at a volume ratio to the fatty acid esters of from about 2:1 to about 5:1, e.g., about 4:1. The full range of blends extends from 50:1 to 1:50 with some benefit. The jet fuel component of the blend preferably contains grade 55, 50-300 ppm detergent, 25 to about 500 ppm lubricity additive and 0.1-1 ppm platinum COD and 5-20 ppm cerium oleate or octoate. In addition to the fuel blend, a method is provided for reducing the emissions of pollutants from a diesel engine, comprising running the engine on a fuel as defined.

    Abstract translation: 低排放柴油包括脂肪酸酯的催化混合物,优选衍生自大豆油和/或牛脂和航空煤油。 催化的共混物有效地降低了调节的排放污染物,其中包括无机颗粒,碳氢化合物和一氧化碳。 催化剂将包括燃料可溶的铂和/或铈或铁。 通常使用铈或铁的浓度为2至25ppm,铂为0.05至2ppm,优选的铈或铁的含量为5至10ppm,例如7.5ppm,铂用于 水平为0.1至0.5ppm,例如0.15ppm。 铈和/或铁与铂的优选比率为75:1至10:1。 通常,喷气燃料组分的使用量与脂肪酸酯的体积比为约2:1至约5:1,例如约4:1。 混合物的范围从50:1增加到1:50,具有一定的优势。 共混物的喷气燃料组分优选含有55级,50-300ppm洗涤剂,25-约500ppm润滑性添加剂和0.1-1ppm铂COD和5-20ppm油酸铈或辛酸铈。 除了燃料混合物之外,还提供了一种用于减少来自柴油发动机的污染物排放的方法,包括以定义的燃料运行发动机。

    Fuel compositions exhibiting improved fuel stability
    78.
    发明申请
    Fuel compositions exhibiting improved fuel stability 失效
    显示燃料稳定性提高的燃料组合物

    公开(公告)号:US20040237384A1

    公开(公告)日:2004-12-02

    申请号:US10722063

    申请日:2003-11-24

    Inventor: William C. Orr

    Abstract: A fuel composition of the present invention exhibits minimized hydrolysis and increased fuel stability, even after extended storage at 65null F. for 6-9 months. The composition, which is preferably not strongly alkaline (3.0 to 10.5), is more preferably weakly alkaline to mildly acidic (4.5 to 8.5) and most preferably slightly acidic (6.3 to 6.8), includes a lower dialkyl carbonate, a combustion improving amount of at least one high heating combustible compound containing at least one element selected from the group consisting of aluminum, boron, bromine, bismuth, beryllium, calcium, cesium, chromium, cobalt, copper, francium, gallium, germanium, iodine, iron, indium, lithium, magnesium, manganese, molybdenum, nickel, niobium, nitrogen, phosphorus, potassium, palladium, rubidium, sodium, tin, zinc, praseodymium, rhenium, silicon, vanadium, or mixture, and a hydrocarbon base fuel.

    Abstract translation: 本发明的燃料组合物即使在65°F下延长储存6-9个月之后,表现出最小化的水解和增加的燃料稳定性。 优选不强碱性(3.0〜10.5)的组合物更优选弱碱性至弱酸性(4.5〜8.5),最优选微酸性(6.3〜6.8),包括低级碳酸二烷基酯,燃烧改善量 含有选自铝,硼,溴,铋,铍,钙,铯,铬,钴,铜,ium,镓,锗,碘,铁,铟的至少一种元素的至少一种高加热可燃化合物, 锂,镁,锰,钼,镍,铌,氮,磷,钾,钯,铷,钠,锡,锌,镨,铼,硅,钒或混合物,以及烃类燃料。

    Process for the selective noncatalytic reduction of the emission of
pollutants from oil-fired boiler plants
    79.
    发明授权
    Process for the selective noncatalytic reduction of the emission of pollutants from oil-fired boiler plants 失效
    从燃油锅炉厂排放污染物的选择性非生物降解方法

    公开(公告)号:US5118282A

    公开(公告)日:1992-06-02

    申请号:US583100

    申请日:1990-09-17

    Abstract: In this process for the selective noncatalytic reduction of the emission of pollutants from oil-fired boiler plants, chemical compounds which affect the combustion process are admixed, in solutions miscible with the liquid fuel, in metered amounts to the liquid fuel or to the combustion air, among these compounds being salts of organic acids, such as naphthenates, octoates, tallates, salts of sulfonic acids, saturated or unsaturated fatty acids, such as oleic acid, and tall oil, with metals from the group of K, Ba, Mg, Ca, Ce, Mn, Fe; rare earth metals; organometallic compounds, such as carbonyl compounds, mixed cyclopentadienylcarbonyl compounds, or aromatic complexes of the transition metals Fe or Mn. For the purpose of minimizing the NO.sub.x values in the waste gas and the dust load with economical consumption of chemicals, a reducing agent is introduced in metered quantities into the firebox (burner chamber) via a boiler metering system with the use of the liquid or also gaseous carrier stream as an aqueous solution of urea or also urea precursors, such as ammonia or ammonium carbonate, which can also contain further ingredients, such as alkanols, alkanecarboxylic acids, alkanals, or alkanones.

    Abstract translation: 在这种选择性非催化还原燃油锅炉设备污染物排放的过程中,影响燃烧过程的化合物与液体燃料混溶,溶液量与液体燃料或燃烧空气混合 在这些化合物中,作为有机酸的盐,例如环烷酸盐,辛酸盐,妥尔酸盐,磺酸盐,饱和或不饱和脂肪酸如油酸和妥尔油,与K,Ba,Mg, Ca,Ce,Mn,Fe; 稀土金属; 有机金属化合物,如羰基化合物,混合环戊二烯基羰基化合物,或过渡金属Fe或Mn的芳族络合物。 为了最大限度地减少废气中的NOx值和粉尘负荷,经济地消耗化学品,将还原剂通过使用液体的锅炉计量系统引入火炉(燃烧室) 作为尿素水溶液的气态载体物流或者还可以含有其它成分如链烷醇,链烷羧酸,链烷烃或链烷烃的尿素前体,如氨或碳酸铵。

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