公开(公告)号：US20180237654A1

公开(公告)日：2018-08-23

申请号：US15953120

申请日：2018-04-13

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Naiyong Jing ,  Kai H. Lochhaas ,  Kevin M. Hamer ,  Thomas J. Blong ,  Timothy D. Fletcher ,  Zhigang Yu ,  Michael Juergens

IPC: C09D127/22 ,  C08K3/22 ,  C08K3/34 ,  C08K5/3412 ,  C09D7/61 ,  H01L31/049 ,  C08K3/36 ,  C09D127/18 ,  C08K5/544

CPC classification number: C09D127/22 ,  C08K3/22 ,  C08K3/346 ,  C08K3/36 ,  C08K5/3412 ,  C08K2003/2241 ,  C09D7/61 ,  H01L31/049 ,  C09D127/18 ,  C08K5/5442

Abstract: A fluoropolymer coating composition is described comprising an aqueous liquid medium, fluoropolymer particles dispersed in the aqueous liquid medium, and at least one aziridine compound. The aziridine compound comprises at least two aziridine groups (i.e. polyaziridine) or at least one aziridine group and at least one alkoxy silane group.In another embodiment, an article is described comprising a substrate wherein a surface of the substrate comprises a coating comprising fluoropolymer particles; and a reaction product of at least one aziridine compound comprising at least two aziridine groups or at least one aziridine group and at least one alkoxy silane group. The coating can be utilized as a primer for bonding a non-fluorinated substrate to a fluoropolymer film and/or the coating can be used as an (e.g. outer exposed) surface layer. In some embodiments, the article may be the (e.g. backside) film of a photovoltaic module.

公开(公告)号：US10048408B2

公开(公告)日：2018-08-14

申请号：US14361076

申请日：2012-11-01

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Yongshang Lu ,  Naiyong Jing ,  Dang Xie ,  Zhigang Yu ,  Caroline M. Ylitalo ,  Mahfuza B. Ali ,  Alexander J. Kugel ,  Steven P. Swanson

IPC: C09K3/18 ,  C09D133/00 ,  C09D175/04 ,  C08K5/06 ,  G02B1/18 ,  C09D5/02 ,  C09D5/16 ,  C08K5/00 ,  G02B27/00 ,  C03C17/00 ,  C03C17/32

Abstract: Coating compositions are described comprising an aqueous polymeric dispersion; a crosslinker; and an acid or salt of a polyalkylene oxide. Also described are articles comprising the dried and cured coating composition disposed on a substrate as well as a method a providing an anti-fog coating on a substrate.

公开(公告)号：US10040953B2

公开(公告)日：2018-08-07

申请号：US14893232

申请日：2014-04-25

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Justin A. Riddle ,  Paul B. Armstrong ,  Karan Jindal ,  Samuel J. Carpenter ,  Garry W. Lachmansingh ,  William R. Dudley ,  Jason T. Petrin ,  Naiyong Jing

IPC: C09D5/16 ,  B05D7/00 ,  B05D5/00 ,  C09D129/04 ,  C09D5/00 ,  C08J7/04 ,  C03C17/00 ,  C03C17/42

Abstract: Articles having poly(vinyl alcohol) (PVA) and silica nanoparticle multilayer coatings are provided. More specifically, the articles include a substrate and a multilayer coating attached to the substrate. The multilayer coating includes a silica layer that is the outermost layer, the silica layer containing acid-sintered interconnected silica nanoparticles arranged to form a continuous three-dimensional porous network. The multilayer coating also includes a PVA layer disposed between a surface of the substrate and the outermost silica layer. The PVA and silica nanoparticle coatings can be used on a large variety of substrates and tend to be resistant to impacts, scratches, wet abrasions, soil and fog.

公开(公告)号：US20180126426A1

公开(公告)日：2018-05-10

申请号：US15862706

申请日：2018-01-05

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Justin A. Riddle ,  Terry R. Hobbs ,  David D. Lu ,  Andrew S. D'Souza ,  Naiyong Jing ,  James P. Gardner, JR. ,  Yifan Zang ,  Zachary J. Malmberg ,  Milind B Sabade

IPC: B08B3/10 ,  C11D11/00 ,  C11D3/12 ,  C11D3/16 ,  C11D3/08

CPC classification number: B08B3/10 ,  C11D3/08 ,  C11D3/1246 ,  C11D3/162 ,  C11D11/0035

Abstract: A method of removing an unwanted constituent from a siliceous surface in which the method includes contacting the siliceous surface and the unwanted constituent with a multi-functional composition that includes water, a hydrophilic silane, and a surfactant, and drying the surface.

公开(公告)号：US09926458B2

公开(公告)日：2018-03-27

申请号：US14893262

申请日：2014-04-25

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Karan Jindal ,  Justin A. Riddle ,  Paul B. Armstrong ,  Samuel J. Carpenter ,  William R. Dudley ,  Garry W. Lachmansingh ,  Jason T. Petrin ,  Naiyong Jing

IPC: C09D129/04 ,  B05D3/02 ,  B05D7/00 ,  C08J7/04 ,  C09D5/16 ,  C03C17/34 ,  C09D5/00 ,  C09D7/12

CPC classification number: C09D129/04 ,  B05D3/0272 ,  B05D7/542 ,  B05D7/582 ,  B05D7/5823 ,  C03C17/34 ,  C03C2217/425 ,  C03C2217/734 ,  C08J7/045 ,  C09D5/00 ,  C09D5/1618 ,  C09D5/1693 ,  C09D7/40 ,  C08K5/5415 ,  C08K3/36

Abstract: Articles having poly(vinyl alcohol)-containing (PVA-containing) and silica nanoparticle multilayer coatings are provided. More specifically, articles include a substrate and a multilayer coating attached to the substrate. The multilayer coating includes a first silica layer and a first PVA-containing layer. The first silica layer is a primer layer of the multilayer coating, and the silica layer comprises a plurality of acid-sintered interconnected silica nanoparticles arranged to form a continuous three-dimensional porous network. The PVA-containing and silica nanoparticle multilayer coatings can be used on a large variety of substrates and tend to be resistant to wet and dry abrasions, scratches, and impacts.

公开(公告)号：US20170252761A1

公开(公告)日：2017-09-07

申请号：US15306224

申请日：2015-10-28

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Adam J. Meuler ,  Nicholas L. Untiedt ,  Stephen C.P. Joseph ,  Thomas P. Klun ,  Naiyong Jing ,  Paul B. Armstrong ,  David A. Gzik ,  Cheryl L.S. Elsbernd

IPC: B05B7/24 ,  C09D127/18 ,  C09D7/12 ,  C09D5/00

CPC classification number: B05B7/2478 ,  B05B7/2481 ,  C08K3/36 ,  C08K5/435 ,  C08K5/5419 ,  C08K9/02 ,  C09D5/00 ,  C09D7/61 ,  C09D7/62 ,  C09D7/63 ,  C09D127/18

Abstract: Presently described are components of a spray application system. At least one component comprises a liquid repellent surface layer. The liquid repellent surface (e.g. layer) may comprise a porous layer and a lubricant impregnated into pores of the porous layer; a fluoropolymer; a fluorochemical material and an organic polymeric binder; or a fluorochemical material melt additive and a thermoplastic polymeric material component. The component is typically a liquid reservoir, a liquid reservoir liner, a lid for a liquid reservoir or liner, or a combination thereof. In some embodiments, the component comprises a thermoplastic polymeric material. In some favored embodiments, the component is a removable liquid reservoir or liner. In some favored embodiments, the component is a collapsible liquid reservoir or liner. The spray application system typically further comprises a gravity-fed spray gun. Also described are spray application systems, methods of using a spray application system, as well as methods of making a component of a spray application system wherein the component has a liquid repellent surface.

公开(公告)号：US09650661B2

公开(公告)日：2017-05-16

申请号：US14891760

申请日：2014-05-13

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Kelvin J. Witcher ,  William E. Foltz ,  Naiyong Jing

IPC: C12N11/06 ,  C12Q1/22

CPC classification number: C12Q1/22 ,  C12N11/06

Abstract: Spore carriers suitable for use in biological indicators are described. The spore carriers include a substrate such as polymeric film or non-woven web with a hydrophilic nanostructured layer bonded to it. Spores are bonded to the nanostructured layer. Nanostructured layers including nanoparticles, such as acid-sintered silica nanoparticles are described. Biological indicators including such spore carriers are also described.

公开(公告)号：US20160289454A1

公开(公告)日：2016-10-06

申请号：US15026850

申请日：2013-10-04

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Naiyong Jing ,  Xuan Jiang ,  Justin A. Riddle ,  Fuxia Sun ,  Daniel J. Schmidt

IPC: C09D1/00 ,  C03C17/23 ,  C08J7/06 ,  C09D7/12

CPC classification number: C09D1/00 ,  C03C17/23 ,  C03C2218/11 ,  C08J7/06 ,  C08J2367/03 ,  C08K3/36 ,  C09D7/61

Abstract: A method of making a coatable composition includes: providing a first composition comprising silica nanoparticles dispersed in an aqueous liquid vehicle, wherein the first composition has a pH greater than 6; acidifying the first composition to a pH of less than or equal to 4 using inorganic acid to provide a second composition; and dissolving at least one metal compound in the second composition to form the coatable composition. The silica nanoparticles have a polymodal particle size distribution, wherein the polymodal particle size distribution comprises a first mode having a first particle size in the range of from 8 to 35 nanometers, wherein the polymodal particle size distribution comprises a second mode having a second particle size in the range of from 2 to 20 nanometers, wherein the first particle size is greater than the second particle size. Coatable compositions, antistatic compositions, preparable by the method are also disclosed. Soil-resistant articles including the antistatic compositions are also disclosed.

Abstract translation: 制备可涂覆组合物的方法包括：提供包含分散在水性液体载体中的二氧化硅纳米颗粒的第一组合物，其中所述第一组合物具有大于6的pH; 使用无机酸将第一组合物酸化至pH小于或等于4，以提供第二组合物; 并将至少一种金属化合物溶解在第二组合物中以形成可涂覆组合物。 所述二氧化硅纳米颗粒具有多晶型粒度分布，其中所述多晶型粒度分布包括具有在8至35纳米范围内的第一粒度的第一模式，其中所述多模式粒度分布包括具有第二粒径的第二模式 在2至20纳米的范围内，其中第一粒度大于第二粒径。 还公开了可通过该方法制备的可涂敷组合物，抗静电组合物。 还公开了包括抗静电组合物的防锈制品。

公开(公告)号：US20160230036A1

公开(公告)日：2016-08-11

申请号：US15133262

申请日：2016-04-20

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Naiyong Jing ,  Xue-hua Chen ,  Ruo-Ni Sun ,  Zhigang Yu ,  Xiaoling Xie ,  Jinyu Chen

IPC: C09D163/00 ,  C03C17/32

CPC classification number: C09D163/00 ,  B82Y30/00 ,  C01P2004/64 ,  C03C17/32 ,  C09C1/00 ,  C09C1/3081 ,  C09C1/407 ,  C09C3/12 ,  C09D1/00 ,  C09D5/008 ,  Y10T428/259

Abstract: A coating composition which imparts antifog properties to substrates coated therewith. The coating compositions are removable and utilize nanoparticles functionalized with epoxy groups. The removable coating compositions are particularly useful on personal protection equipment such as face masks, shields, and protective glasses.

Abstract translation: 一种涂料组合物，其赋予其涂布的基材上的防雾性能。 涂料组合物是可去除的并且利用用环氧基团官能化的纳米颗粒。 可去除的涂料组合物特别适用于个人防护设备，如面罩，护罩和防护眼镜。

公开(公告)号：US09206335B2

公开(公告)日：2015-12-08

申请号：US13678666

申请日：2012-11-16

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Patrick J. Hager ,  Jay S. Schlechte ,  Elaine M. Yorkgitis ,  Naiyong Jing

IPC: C08G77/04 ,  C09D183/06 ,  B82Y30/00 ,  C09D7/12 ,  C09C1/00 ,  C09C1/30 ,  C09D183/02 ,  C09D183/04 ,  C08K3/36 ,  C08G77/02 ,  C08K5/00 ,  C08K5/5419 ,  C08K5/5425 ,  C08K5/5435 ,  C08K5/548 ,  C08K9/06 ,  C08G77/18 ,  C08G77/20

CPC classification number: C09D183/06 ,  B82Y30/00 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/22 ,  C08G77/02 ,  C08G77/045 ,  C08G77/18 ,  C08G77/20 ,  C08K3/36 ,  C08K5/0091 ,  C08K5/5419 ,  C08K5/5425 ,  C08K5/5435 ,  C08K5/548 ,  C08K9/06 ,  C09C1/0009 ,  C09C1/3081 ,  C09C1/309 ,  C09D7/62 ,  C09D7/67 ,  C09D183/02 ,  C09D183/04 ,  Y10T428/259

Abstract: A coating composition is provided comprising a) an aqueous dispersion, having a pH of less than 7.5, of silica nanoparticles having average particle diameters of 40 nanometers or less, b) an alkoxysilane oligomer; c) a silane coupling agent, and d) optionally a metal β-diketone complexing agent. The compositions may be used to prepare coated articles wherein the coating is substantially uniform in thickness, durably adheres to the substrate, and provides hydrophilic and/or antireflection surface properties to the substrate.

Abstract translation: 提供一种涂料组合物，其包含：a）具有平均粒径为40纳米或更小的二氧化硅纳米颗粒的pH小于7.5的水分散体，b）烷氧基硅烷低聚物; c）硅烷偶联剂，和d）任选的金属与二酮络合剂。 组合物可用于制备涂层制品，其中涂层的厚度基本上均匀，持久地粘附到基底上，并为基底提供亲水和/或抗反射表面性质。