公开(公告)号：JPS62129107A

公开(公告)日：1987-06-11

申请号：JP26995385

申请日：1985-11-29

Applicant: AGENCY IND SCIENCE TECHN

Inventor： HIROTSU TOSHIHIRO ,  ICHIMURA KUNIHIRO ,  MIZOGUCHI KENSAKU ,  NAKAMURA EIICHIRO

IPC: B01D61/36 ,  B01D67/00 ,  B01D69/12 ,  B01D71/38

Abstract: PURPOSE:To prepare a water selective and permeable separating membrane having such practical performances as superb separability, mechanical strength of membrane, etc. by utilizing photo-crosslinked photosensitive polyvinyl alcohol derivative to apply the porous high-molecular membrane. CONSTITUTION:The water solution of water soluble photosensitive resin such as polyvinyl alcohol or partial saponifiable vinyl acetate, etc. shown in the formula is applied on the porous high-molecular membrane such as cellulose acetate porous membrane, exposed to the interior light and the like after air-drying, sensitized and crosslinked with water soluble photosensitive resin to render the said membrane insoluble. By utilizing the composite membrane thus prepared, pervaporation is carried out to separate the water-ethanol mixing solution and the like.

公开(公告)号：JPS6248725A

公开(公告)日：1987-03-03

申请号：JP18708085

申请日：1985-08-26

Applicant: AGENCY IND SCIENCE TECHN

Inventor： ICHIMURA KUNIHIRO ,  HIROTSU TAKAHIRO ,  SAKURAGI MASAKO ,  MORII NAOYUKI ,  SUDA MASAO

IPC: C02F1/42 ,  B01D15/00 ,  B01J20/26 ,  C01G43/00 ,  C08G73/00 ,  C08G73/02 ,  C08G73/04

Abstract: PURPOSE:To obtain the titled resin suitable for the adsorption and recovery of trace metallic ion dissolved in seawater, by reacting a specific polyethylenimine derivative with hydroxylamine. CONSTITUTION:The objective resin having the hydroxamic acid residue of formula on the side chain can be produced by (1) reacting (A) a crosslinked polyethylenimine polymer compound obtained e.g. by the graft-polymerization of polyethylenimine to crosslinked polystyrene, etc., with (B) an acrylic acid ester e.g. in a dispersing medium (e.g. water) to obtain a polyethylenimine derivative having propionic acid ester residue on the side chain, (2) suspending the product in a solvent containing hydroxylamine and (3) reacting at a temperature between room temperature and the boiling point of the solvent for 1-5 days.

公开(公告)号：JPS61259799A

公开(公告)日：1986-11-18

申请号：JP9967685

申请日：1985-05-13

Applicant: AGENCY IND SCIENCE TECHN ,  EBARA RES CO LTD

Inventor： ICHIMURA KUNIHIRO ,  WATANABE AKIRA ,  MISHIMA KOJI ,  ENDO KANEAKI

IPC: C02F3/28 ,  B09B3/00 ,  C02F11/04 ,  C12P5/02

Abstract: PURPOSE:To efficiently obtain methane gas, by using methane producing bacteria included and immobilized by a photosensitive polyvinyl alcohol prepolymer having a stilbazolium group in the side chain thereof. CONSTITUTION:Methane-producing bacteria included and immobilized by a photosensitive polyvinyl alcohol prepolymer having a stilbazolium group in the side chain thereof as a photosensitive group are used in org. waste water or org. waste. The introducing ratio of the stilbazolium group into the photosensitive polyvinyl alcohol prepolymer is pref. 1.0-7.0mol% to the mol number of the vinyl group is the prepolymer. From the aspect of the production of methane, it is effective and preferable that the polymerization degree of the polyvinyl alcohol component of the photosensitive polyvinyl alcohol prepolymer is 300-2,500 and the saponification degree thereof is 65-88%.

公开(公告)号：JPS61230138A

公开(公告)日：1986-10-14

申请号：JP6913985

申请日：1985-04-03

Applicant: AGENCY IND SCIENCE TECHN ,  OJI PAPER CO

Inventor： ICHIMURA KUNIHIRO ,  ITO MASATAKA ,  YAMANA MASAHIRO ,  ITO HIROSHI

IPC: C08F2/48 ,  C08F8/44 ,  G03F7/038 ,  G03F7/12 ,  H01J9/227

Abstract: PURPOSE:To enhance water and solvent resistances, and storage stability and to improve resolution and surface smoothness by using as an essential component a specified photosensitive polyvinyl acetate saponified deriv. as a protective colloid. CONSTITUTION:The emulsion resin compsn. is composed of an aq. emulsion of a film-forming resin and its protective colloid represented by formulae I and IV, consisting of a main chain of a polyvinyl acetate saponified product represented by formula II and V, and photosensitive units each represented by formula I (a part of formula II is said main PVA chain; m is 1-6; n is 0 or 1; Y is formula III; R1 is H, alkyl, or the like; R2 is H or lower alkyl; and X is an anion), and hydrophobic units each represented by formula IV in which R3 is H, 1-18C alkyl, phenyl, or the like. Both units permit the photosensitive resin compsn. to have water developability, the image parts obtained by exposure hardening to be enhanced water and solvent resistances, and said compsn. to be stably stored for a long period by using only a water medium.

公开(公告)号：JP2000284288A

公开(公告)日：2000-10-13

申请号：JP2000047131

申请日：2000-02-24

Applicant: AGENCY IND SCIENCE TECHN

Inventor： TAMAOKI TAKASHI ,  KAWANISHI YUJI ,  AKIYAMA AKIHISA ,  ICHIMURA KUNIHIRO

IPC: G02F1/1337

Abstract: PROBLEM TO BE SOLVED: To provide a liquid crystal cell using a tilt alignment film for a liquid crystal having high productivity in which any tilt angles can be designed, by irradiating a resin film containing a photoisomerization reaction structural unit with non-polarized light in an oblique direction. SOLUTION: A resin film containing a photoisomerization reaction structural unit is irradiated with non-polarized light in an oblique direction to form a tilt alignment film for a liquid crystal. The resin film used contains a photoisomerization reaction structural unit, and the photoisomerization reaction structural unit preferably has at least one double bond selected from N=N and C=C bonds and causes geometrical photoisomerization reaction by irradiation of light. As for the photoisomerization reaction structural unit having N=N bonds, for example, azobenzene and azopyridine can be used. As for the photoisomerization reaction structural unit having Cr=C bonds, for example, stilbene and stilbazole can be used. As for the resin containing the photoisomerization reaction structural unit, any of vinyl polymers, ring-opened polymers or the like can be used.

公开(公告)号：JPH0849188A

公开(公告)日：1996-02-20

申请号：JP9854195

申请日：1995-04-24

Applicant: AGENCY IND SCIENCE TECHN ,  AJINOMOTO KK ,  SONY CORP

Inventor： IGUCHI MASATOSHI ,  MIHASHI SHIGENOBU ,  ICHIMURA KUNIHIRO ,  YAMANAKA SHIGERU ,  WATABE OTOHIKO ,  NISHI MIO ,  URYU MASARU

IPC: C08J5/04 ,  C08L1/00 ,  D01F2/00 ,  D21H11/00 ,  H01B3/48

Abstract: PURPOSE:To obtain the subject sheet containing the bacterial cellulose of ribbon- like fibril form and excellent in dynamic characteristics such as expansion resistance and elasticity. CONSTITUTION:Acetobacter aceti xylinum ATCC 10821 bacteria as a microorganism for producing bacterial cellulose is cultured, and the gel-like film formed in the upper layer of the culture solution and containing a bacterial cellulose polysaccharide is disaggregated and subsequently filtered off to obtain the bacterial cellulose disaggregation product comprising ribbon-like fibrils. A wood pulp slurry is mixed with the produced bacterial cellulose disaggregation product and subsequently processed into a paper sheet. The paper sheet is impregnated with a composition containing a phenolic resin, dried with air, and subsequently heat-pressed to obtain a phenolic resin laminate board.

公开(公告)号：JPH07146549A

公开(公告)日：1995-06-06

申请号：JP28083791

申请日：1991-09-30

Applicant: AGENCY IND SCIENCE TECHN ,  GOO KAGAKU KOGYO KK

Inventor： ICHIMURA KUNIHIRO ,  MORIGAKI TOSHIO ,  NAKANISHI NOBUO

IPC: G03F7/004 ,  G03F7/021 ,  G03F7/027 ,  G03F7/028 ,  G03F7/033 ,  G03F7/038 ,  G03F7/04 ,  G03F7/12

Abstract: PURPOSE:To obtain a screen printing plate having good printability, solvent resistance, water resistance and printing resistance, to obviate the generation of the printing plate by blurring and infiltrating of ink to the rear side at the time of printing, to enable good printing of ultra-fine lines and good printing of a rugged surface and to improve the life of the printing plate. CONSTITUTION:This photosensitive resin compsn. for screen plate making contains at least (A) a fluorine having an ethylenic unsatd. bond or fluorine compd. having the ethylenic unsatd. bond and compd. having another ethylenic unsatd. bond, (B) a photopolymn. initiator and (C) a polyvinyl alcohol and/or water dispersible polymer. The photosensitive film is formed by drying the compsn. on a plastic film and drying the coating and this screen printing plate for plate making is formed by using the film.

公开(公告)号：JPH0651522A

公开(公告)日：1994-02-25

申请号：JP4089691

申请日：1991-02-12

Applicant: AGENCY IND SCIENCE TECHN ,  INK TEC KK ,  DAINIPPON PRINTING CO LTD

Inventor： ICHIMURA KUNIHIRO ,  KOBAYASHI SHUSABURO ,  KOMATSU TOSHIO ,  OKAZAKI AKIRA

IPC: G02B5/20 ,  G03C1/00 ,  G03F7/00 ,  G03F7/004 ,  G03F7/105

Abstract: PURPOSE:To obtain a transparent colored image having excellent spectral characteristic transmitting light of a specific visible ray region at high transmissivity, excellent in durability and simplified in production process. CONSTITUTION:A coating film is formed in pattern state by irradiating a photosensitive resin, having the spectral characteristic transmitting light of the specific visible ray region and in which a pigment having particle diameter distribution so that particle having >=1mum particle diameter is =30wt.% to total particle is dispersed, with light and developing. The light transmissivity of light absorbing region in the spectral characteristic curve of visible ray region of the photosensitive resin after forming the coating film is =50%.

公开(公告)号：JPH0592955A

公开(公告)日：1993-04-16

申请号：JP28083991

申请日：1991-09-30

Applicant: AGENCY IND SCIENCE TECHN ,  GOO KAGAKU KOGYO KK

Inventor： ICHIMURA KUNIHIRO ,  NISHIMURA TOSHIAKI ,  HASHIMOTO SOICHI

IPC: C07D213/46 ,  C08F20/52 ,  C08F20/60 ,  G03F7/027

Abstract: PURPOSE:To obtain a new photo-crosslinkable styrylpyridinium derivative producible readily and in high yield, capable of being subjected to addition polymerization with various unsaturated monomers and easily controlling physical properties of obtained photosensitive polymer. CONSTITUTION:A compound of formula I (R1 is H or methyl; R2 is alkyl or aralkyl which may contain hydroxyl, carbamoyl, ether bond or unsaturated bond; B is anion) or a compound of formula II (R3 is alkylene; X is SO 3 or CO 2). The compound is obtained by reacting diacetone (meth)acrylamide with a compound of formula III or formula IV in water or a polar solvent (e.g. methanol, ethanol, DMF, DMSO or cellosolve-based solvent) in the presence of a catalyst at

公开(公告)号：JPH0486667A

公开(公告)日：1992-03-19

申请号：JP20096390

申请日：1990-07-27

Applicant: TOPPAN PRINTING CO LTD ,  AGENCY IND SCIENCE TECHN

Inventor： OE YASUSHI ,  ICHIMURA KUNIHIRO

IPC: G03F7/004 ,  G03F7/029 ,  G03F7/038 ,  G03F7/039 ,  G03H1/02 ,  H01L21/027

Abstract: PURPOSE:To improveme the sensitivity and heat resistance by forming this material with a specified high polymer compound, a diaryl iodonium salt and a specified p-aminobenzylidene derivative. CONSTITUTION:The material is consisting of one part of the high polymer compound composed of 30-100 mol% a structural unit expressed with formula I, 0-70 mol% a structural unit expressed with formula PI,and 0.02-0.2 parts a diaryl iodonium salt and 0.03-0.2 parts p-aminobenzylidene derivative expressed with formula III. In formula I,R1 denotes tert.-butoxycarbonyl group and tetorahydropyranyl group, and in formula PI,R2 is H,or methyl group,and R3 is 1-4C of a lower alkoxycarbonyl group, aryloxycarbonyl group,etc. In formula III,R1 and R2 is lower alkyl groups and X is H atom and phenyl group, etc., and Y is a residual group selected from acyl group,cyano group, etc., and (n) is 0 or 1. Thus the sensitivity and heat resistance are improved.