ELASTOMEROS DE POLIURETANO MICROCELULARES QUE CONTIENEN GRUPOS UREA.

    公开(公告)号:MX9805047A

    公开(公告)日:1998-10-31

    申请号:MX9805047

    申请日:1998-06-22

    Applicant: BASF AG

    Abstract: La invencion se refiere a un elastomero PU microcelular con mejores características mecánicas-dinámicas, a base de un componente que contiene esencialmente 4,4'-mdi y otros componentes estándar. El elastomero en cuestion tiene una estructura fisicoquímica caracterizada pro una señal de uno o dos picos proxima a la señal principal molecular baja para una masa molar (aparente) mayor de 25,000 q/mol medida por cromatografía de permeacion en gel a partir de una solucion del elastomero PO microcelular producido a 90 degree C en N,N-dimetilformamida con 1% de di-n-butilamina, contra metacrilato de polimetilo (PMMA) como el estándar, siendo la señal reducida o eliminada después de la adicion de cloruro de litio a esta solucion. El elastomero tiene un contenido de urea de 14-10% en peso. También se describe un proceso para producir este elastomero PU microcelular con mejores características mecánicas-dinámicas y el uso de este elastomero para producir elementos amortiguadores.

    83.
    发明专利
    未知

    公开(公告)号:TR199800670T1

    公开(公告)日:1998-06-22

    申请号:TR9800670

    申请日:1996-09-30

    Applicant: BASF AG

    Abstract: Compact and preferably cellular polyurethane elastomers based on polyisocyanate mixtures containing 3,3'-dimethylbiphenyl 4,4'-diisocyanate are produced by reactinga) relatively high molecular weight polyhydroxyl compounds and, if desired,b) low molecular weight hydroxyl-containing chain extenders and/or crosslinkers withc) 3,3'-dimethylbiphenyl 4,4'-diisocyanate and at least one additional aromatic diisocyanate selected from the group consisting of tolylene diisocyanate, diphenylmethane diisocyanate, 1,2-diphenylethane diisocyanate and phenylene diisocyanate, and/or at least one aliphatic diisocyanate having from 4 to 12 carbon atoms and/or at least one cycloaliphatic diisocyanate having from 6 to 18 carbon atoms, where the formative components (a), (c) and, if used, (b) are advantageously reacted by the prepolymer method,in the presence or absence ofd) catalysts,e) blowing agents andf) additives.Isocyanate prepolymers suitable for this purpose are preferably ones based on diphenylmethane 4,4'-diisocyanate and 3,3'-dimethylbiphenyl 4,4'-diisocyanate.

    84.
    发明专利
    未知

    公开(公告)号:TR199800465T1

    公开(公告)日:1998-05-21

    申请号:TR9800465

    申请日:1996-09-09

    Applicant: BASF AG

    Abstract: Compact and preferably cellular polyurethane elastomers are produced by reactinga) polyhydroxyl compounds having molecular weights of from 800 to 6000 and, if desired,b) chain extenders and/or crosslinkers having molecular weights of up to 800 [lacuna]c) naphthylene 1,5-diisocyanate and at least one additional aromatic diisocyanate selected from the group consisting of tolylene diisocyanate, diphenylmethane diisocyanate, 3,3'-dimethylbiphenyl diisocyanate, 1,2-diphenylethane diisocyanate and phenylene diisocyanate, and/or aliphatic diisocyanate having from 4 to 12 carbon atoms and/or cycloaliphatic diisocyanate having from 6 to 18 carbon atoms, where the formative components (a), (c) and, if used, (b) are preferably reacted by the prepolymer method,in the presence or absence ofd) catalysts,e) blowing agents andf) additives. Isocyanate prepolymers suitable for this purpose are also described.

    Microcellular polyurethane elastomer containing urea groups

    公开(公告)号:AU1372697A

    公开(公告)日:1997-07-17

    申请号:AU1372697

    申请日:1996-12-16

    Applicant: BASF AG

    Abstract: PCT No. PCT/EP96/05640 Sec. 371 Date Oct. 7, 1998 Sec. 102(e) Date Oct. 7, 1998 PCT Filed Dec. 16, 1996 PCT Pub. No. WO97/23535 PCT Pub. Date Jul. 3, 1997A microcellular PU elastomer having improved dynamic mechanical properties and based on an isocyanate component consisting essentially of 4,4'-MDI and further customary constituents has a physicochemical structure which, in the gel permeation chromatograph (GPC) of a solution of the microcellular polyurethane elastomer prepared at 90 DEG C. in N,N-dimethylformamide containing 1 percent of di-n-butylamine measured against polymethyl methacrylate (PMMA) as standard, displays a signal occurring in addition to low molecular weight main signal and comprising one or more peaks at an (apparent) molar mass of greater than 250,000 g/mol which becomes smaller or disappears on addition of lithium chloride to this solution, and a urea content of from 14 to 18% by weight. A process is also provided for preparing such a microcellular PU elastomer having improved dynamic mechanical properties. The microcellular PU elastomers can be used for producing damping elements.

    88.
    发明专利
    未知

    公开(公告)号:BR9504534A

    公开(公告)日:1997-05-27

    申请号:BR9504534

    申请日:1995-10-24

    Applicant: BASF AG

    Abstract: In an apparatus for producing foamed plastics parts, a closed mold (1) is filled with polymer molding compound and, after the elapse of a reaction time, the finished part is removed. A plurality of identical molds (1) run on mold carriers (5) through a production installation. For the purpose of reducing the production outlay, a demolding device (11) shared by all the molds (1) is brought into operative connection successively with the molds (1) and in each case one mold (1) is opened. The movements required in this operation are executed by the demolding device (11). An unlocking unit (19) and a swiveling unit (20) of the demolding device (11) are brought into engagement with the mold (1) by a positioning unit (21), after which the mold (1) is unlocked and one mold half (1a) of the mold (1) is swung open. For unlocking the mold (1), the latter is raised against spring force and a positive locking is brought out of engagement.

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