公开(公告)号：AT157643T

公开(公告)日：1997-09-15

申请号：AT96101038

申请日：1991-12-10

Applicant: BASF AG

Inventor： WINGERT HORST DR ,  WOLF BERND DR ,  BENOIT REMY DR ,  SAUTER HUBERT DR ,  HEPP MICHAEL DR ,  GRAMMENOS WASSILIOS DR ,  KUEKENHOEHNER THOMAS DR

IPC: C07C69/736 ,  C07C20060101 ,  C07C51/09 ,  C07C51/367 ,  C07C59/68 ,  C07C65/21 ,  C07C65/24 ,  C07C67/22 ,  C07C69/738 ,  C07C69/76 ,  C07C235/34 ,  C07C235/78 ,  C07C249/08 ,  C07C251/48 ,  C07C253/14 ,  C07C255/17 ,  C07C255/40 ,  C07C317/24

Abstract: Prepn. of 2-phenoxymethyl benzoic acid derivs. of formula (I) comprises (a) converting a phenol of formula (II) to the phenolate in the presence of a basic diluent; (b) mixing the mixt. with a lactone of formula (III); (c) distilling off the diluent; (d) reacting the mixt. at 50-250 degrees C in the melt; and (e) dissolving the liq. melt with water and acidifying. X, Y = halogen, 1-4C alkyl, 1-4C alkoxy or CF3; m = 0-4; n = 0-3.

公开(公告)号：AT157079T

公开(公告)日：1997-09-15

申请号：AT96101025

申请日：1991-12-10

Applicant: BASF AG

Inventor： WINGERT HORST DR ,  WOLF BERND DR ,  BENOIT REMY DR ,  SAUTER HUBERT DR ,  HEPP MICHAEL DR ,  GRAMMENOS WASSILIOS DR ,  KUEKENHOEHNER THOMAS DR

IPC: C07C69/736 ,  C07C20060101 ,  C07C51/09 ,  C07C51/367 ,  C07C59/68 ,  C07C65/21 ,  C07C65/24 ,  C07C67/22 ,  C07C69/738 ,  C07C69/76 ,  C07C235/34 ,  C07C235/78 ,  C07C249/08 ,  C07C251/48 ,  C07C253/14 ,  C07C255/17 ,  C07C255/40 ,  C07C317/24

Abstract: Prepn. of 2-phenoxymethyl benzoic acid derivs. of formula (I) comprises (a) converting a phenol of formula (II) to the phenolate in the presence of a basic diluent; (b) mixing the mixt. with a lactone of formula (III); (c) distilling off the diluent; (d) reacting the mixt. at 50-250 degrees C in the melt; and (e) dissolving the liq. melt with water and acidifying. X, Y = halogen, 1-4C alkyl, 1-4C alkoxy or CF3; m = 0-4; n = 0-3.

公开(公告)号：AT155775T

公开(公告)日：1997-08-15

申请号：AT95112355

申请日：1992-01-24

Applicant: BASF AG

Inventor： GRAMMENOS WASSILIOS DR ,  HARREUS ALBRECHT DR ,  SAUTER HUBERT DR ,  HELLENDAHL BEATE DR ,  DOETZER REINHARD DR ,  AMMERMANN EBERHARD DR ,  LORENZ GISELA DR

IPC: A01N37/50 ,  A01N43/54 ,  A01N43/58 ,  A01N43/76 ,  A01N43/836 ,  C07C69/65 ,  C07C69/653 ,  C07C69/734 ,  C07C69/738 ,  C07C251/48 ,  C07C251/50 ,  C07C251/52 ,  C07C251/54 ,  C07C251/56 ,  C07C251/58 ,  C07C251/60 ,  C07C251/86 ,  C07C255/15 ,  C07C255/57 ,  C07C255/58 ,  C07C255/62 ,  C07D213/77 ,  C07D239/42 ,  C07D241/20 ,  C07D263/32 ,  C07D333/28

Abstract: Iminoalkyl-phenylacrylic acid derivs. (I) ar new: R = H or 1-6C alkyl; R = H; 1-4C alkyl opt. substd. by halo; or opt. substd. aryl; Z ,Z = H; halo; CN; NO2;etc.;Y = O; NH; or NR ; and R = H; 1-4C alkoxycarbonyl-1-4C alkyl; or opt. substd. alkyl, cycloalkyl, etc.; or Y+R form a ring which is opt. substd. when Y = NH or NR ; R = 1-6C alkyl; X = CH-1-4C alkoxy or CH-1-4C alkylthio (also 1-4C alkylidene and 1-4C alkoxyimino in the description).

公开(公告)号：DE19548370A1

公开(公告)日：1997-07-03

申请号：DE19548370

申请日：1995-12-27

Applicant: BASF AG

Inventor： GROTE THOMAS DR ,  SAUTER HUBERT DR ,  KIRSTGEN REINHARD DR ,  BAYER HERBERT DR ,  MUELLER RUTH DR ,  MUELLER BERND DR ,  OBERDORF KLAUS DR ,  GRAMMENOS WASSILIOS DR ,  GOETZ NORBERT DR ,  RACK MICHAEL DR ,  HARREUS ALBRECHT DR ,  ROEHL FRANZ DR ,  AMMERMANN EBERHARD DR ,  HARRIES VOLKER DR ,  LORENZ GISELA DR ,  STRATHMANN SIEGFRIED DR

IPC: A01N37/38 ,  A01N37/50 ,  C07C251/60 ,  C07C251/56 ,  A01N35/10 ,  A01N37/10 ,  A01N37/34 ,  A01N41/04 ,  A01N43/78 ,  C07C249/12 ,  C07C249/14 ,  C07C251/58 ,  C07C255/61 ,  C07C257/06

Abstract: 2-(2-(Iminooxy)-phenyl)-2-(methoxyimino, methoxymethylene or ethylidene)-acetic acid amide or methyl ester derivatives of formula (I) and their salts are new. R = (a) -C(=NOMe)-COOMe, (b) -C(=NOMe)-CONHMe, (c) -C(=NOMe)-CONH2, (d) -C(=CHOMe)-COOMe or (e) -C(=CHMe)-COOMe; R = CN, NO2, CF3, halogen, 1-4C alkyl or 1-4C alkoxy; m = 0-2; R = H, OH, cyclopropyl, halogen, 1-4C alkyl, CN, 1-4C alkoxy or 1-4C alkylthio; R = 1-8C alkyl, 2-8C alkenyl, 2-8C alkynyl, 3-8C cycloalkyl, aryl or heteroaryl (all optionally partially or completely halogenated or substituted by 1-3 of CN, NO2, OH, SH, NH2, COOH, CONH2, CSNH2, halogen, alkyl, haloalkyl, alkylsulphonyl, alkylsulphoxyl, 3-6C cycloalkyl, alkoxy, haloalkoxy, alkoxycarbonyl, alkylthio, mono- or dialkylamino, mono- or dialkylaminocarbonyl, mono- or dialkylaminothiocarbonyl, alkenyl, alkenyloxy, benzyl, benzyloxy, aryl, aryloxy, heteroaryl and heteroaryloxy); or R -Y-N=C(R )-; R = (i) H; (ii) 1-10C alkyl, 3-6C cycloalkyl, 2-10C alkenyl, 3-10C alkynyl, (1-10C) alkylcarbonyl, (2-10C) alkenylcarbonyl, (3-10C) alkynylcarbonyl or (1-10C) alkylsulphonyl (all optionally partially or completely halogenated or substituted by 1-3 of CN, NO2, OH, SH, NH2, COOH, CONH2, CSNH2, halogen, alkyl, haloalkyl, alkylsulphonyl, alkylsulphoxyl, 3-6C cycloalkyl, alkoxy, haloalkoxy, alkoxycarbonyl, alkylthio, mono- or dialkylamino, mono- or dialkylaminocarbonyl, mono- or dialkylaminothiocarbonyl, alkenyl, alkenyloxy, benzyl, benzyloxy, aryl, aryloxy, arylthio, heteroaryl, heteroaryloxy and heteroarylthio (where aromatic or heteroaromatic moieties are themselves optionally partially or completely halogenated or substituted by 1-3 of CN, NO2, OH, SH, NH2, COOH, CONH2, CSNH2, halogen, alkyl, haloalkyl, alkylsulphonyl, alkylsulphoxyl, 3-6C cycloalkyl, alkoxy, haloalkoxy, alkoxycarbonyl, alkylthio, mono- or dialkylamino, mono- or dialkylaminocarbonyl, mono- or dialkylaminothiocarbonyl, alkenyl, alkenyloxy, benzyl, benzyloxy, aryl, aryloxy, arylthio, heteroaryl, heteroaryloxy, heteroarylthio and -C(=NOR )-An-R )); or (iii) aryl, heteroaryl, arylcarbonyl, heteroarylcarbonyl, arylsulphonyl or heteroarylsulphonyl (all optionally partially or completely halogenated or substituted by 1-3 of CN, NO2, OH, SH, NH2, COOH, CONH2, CSNH2, halogen, alkyl, haloalkyl, alkylcarbonyl, alkylsulphonyl, alkylsulphoxyl, 3-6C cycloalkyl, alkoxy, haloalkoxy, alkoxycarbonyl, alkylthio, mono- or dialkylamino, mono- or dialkylaminocarbonyl, mono- or dialkylaminothiocarbonyl, alkenyl, alkenyloxy, benzyl, benzyloxy, aryl, aryloxy, heteroaryl, heteroaryloxy and -C(=NOR )-An-R ); A = O, S, NH or N(alkyl); n = 0 or 1; R ,R = H or alkyl; R = H, OH, halogen or as R ; Y = O or NR ; R = H or alkyl; unless specified otherwise alkyl moieties have 1-6C and alkenyl moieties 2-6C. Intermediates of formulae (IV) and (IIA) are also new. R = 1-8C alkyl; X = F or other nucleofugeous leaving group.

公开(公告)号：DE19545094A1

公开(公告)日：1997-06-05

申请号：DE19545094

申请日：1995-12-04

Applicant: BASF AG

Inventor： MUELLER RUTH DR ,  BAYER HERBERT DR ,  KIRSTGEN REINHARD DR ,  SAUTER HUBERT DR ,  RACK MICHAEL DR ,  HARREUS ALBRECHT DR ,  MUELLER BERND DR ,  GROTE THOMAS DR ,  OBERDORF KLAUS DR ,  GRAMMENOS WASSILIOS DR ,  ROEHL FRANZ DR ,  LORENZ GISELA DR ,  AMMERMANN EBERHARD DR ,  HARRIES VOLKER DR ,  STRATHMANN SIEGFRIED DR

IPC: A01N43/36 ,  A01N43/56 ,  A01N43/76 ,  A01N43/78 ,  C07D207/33 ,  C07D231/12 ,  C07D263/30 ,  C07D277/22 ,  C07D277/28 ,  C07D521/00 ,  A01N37/50 ,  A01N43/00 ,  C07D227/04 ,  C07D247/00 ,  C07D255/02 ,  C07D261/08 ,  C07D263/32 ,  C07D271/02 ,  C07D307/36 ,  C07D333/06

Abstract: The invention relates to phenylacetic acid derivatives of the formula (I), in which the substituents and the index have the following meaning: X is NOCH3, CHOCH3, CHCH3 and CHCH2CH3; Y is NR and O; R , R are hydrogen and alkyl; R is cyano, nitro, halogen, alkyl, alkyl halide and alkoxy; m is 0, 1 or 2; R is hydrogen, hydroxy, amino, cyano, halogen, alkyl, alkyl halide, cycloalkyl, alkoxy, alkylthio, alkylamino and dialkylamino; A is a 5 or 6 membered hetero-aromatic ring; R is a substituted aryl; R is hydrogen, optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkenyl, heterocyclyl, aryl and hetaryl. The invention also relates to the salts of said derivatives, a process and intermediates for the preparation and use thereof.

公开(公告)号：DE19540361A1

公开(公告)日：1997-05-07

申请号：DE19540361

申请日：1995-10-30

Applicant: BASF AG

Inventor： BAYER HERBERT DR ,  SAUTER HUBERT DR ,  OBERDORF KLAUS DR ,  GRAMMENOS WASSILIOS DR ,  GROTE THOMAS DR ,  KIRSTGEN REINHARD DR ,  MUELLER BERND DR ,  MUELLER RUTH DR ,  ROEHL FRANZ DR ,  AMMERMANN EBERHARD DR ,  HARRIES VOLKER DR ,  LORENZ GISELA DR ,  STRATHMANN SIEGFRIED DR ,  GOETZ NORBERT DR ,  HARREUS ALBRECHT DR

IPC: C07D521/00 ,  A01N35/10 ,  A01N37/36 ,  A01N37/50 ,  A01N43/08 ,  A01N43/10 ,  A01N43/36 ,  A01N43/40 ,  A01N43/50 ,  A01N43/54 ,  A01N43/56 ,  A01N43/58 ,  A01N43/60 ,  A01N43/64 ,  A01N43/76 ,  A01N43/78 ,  A01N43/80 ,  A01N47/20 ,  C07C49/76 ,  C07C251/40 ,  C07C251/48 ,  C07C251/60 ,  C07C255/17 ,  C07C271/28 ,  C07C249/04 ,  C07C49/213 ,  A01N37/10

Abstract: The invention concerns phenylacetic acid derivatives of formula (I), in which the variables have the following meanings: X = NOCH3, CHOCH3 or CHCH3; Y = O or NZ, Z standing for hydrogen or alkyl; R = H or alkyl; R = cyano, nitro, trifluoromethyl, halogen, alkyl or alkoxy; m = 0, 1 or 2, wherein the group R can be different when m = 2; R = H, cyano, alkyl, alkyl halide, alkoxy or cyclopropyl; R = alkylenedioxy, the alkylene groups being partially or completely halogenated, or one of the groups: -(C=O)-R , -C(=NOR )-Ap-R , -NR -(C=O)-Ap-R , -O-(C=O)-NR R or -N(R )-OR , R , R , independently of each other, being H or optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkenyl, heterocyclyl, aryl or heteroaryl; R , R , independently of each other, being H or optionally substituted alkyl, alkenyl, alkinyl, alkylcarbonyl, alkenylcarbonyl, alkinylcarbonyl, alkoxycarbonyl, alkenyloxycarbonyl, alkinyloxycarbonyl, cycloalkyl, cycloalkylcarbonyl, cycloalkyloxycarbonyl, arylcarbonyl or heteroarylcarbonyl; p = 0 or 1; A = O, S or N, the N-atom carrying H or alkyl; n = 1 or 2, wherein the group R can be different when n = 2; and R = H, alkylsulphonyl or optionally substituted alkyl, alkenyl, alkinyl or cycloalkyl. The invention further concerns salts of these substances, a process and intermediate products for their preparation, and their use as fungicides and pesticides.

公开(公告)号：DE19537750A1

公开(公告)日：1997-04-17

申请号：DE19537750

申请日：1995-10-10

Applicant: BASF AG

Inventor： BAYER HERBERT DR ,  SAUTER HUBERT DR ,  OBERDORF KLAUS DR ,  GRAMMENOS WASSILIOS DR ,  GROTE THOMAS DR ,  KIRSTGEN REINHARD DR ,  MUELLER BERND DR ,  MUELLER RUTH DR ,  ROEHL FRANZ DR ,  AMMERMANN EBERHARD DR ,  HARRIES VOLKER DR ,  LORENZ GISELA DR ,  STRATHMANN SIEGFRIED DR ,  GOETZ NORBERT DR

IPC: C07D233/64 ,  A01N37/52 ,  C07C259/12 ,  C07C259/14 ,  C07C327/56 ,  C07D207/335 ,  C07D207/34 ,  C07D213/61 ,  C07D213/64 ,  C07D213/65 ,  C07D213/74 ,  C07D213/84 ,  C07D213/85 ,  C07D231/20 ,  C07D231/38 ,  C07D261/08 ,  C07D263/32 ,  C07D263/34 ,  C07D271/06 ,  C07D271/10 ,  C07D275/02 ,  C07D275/04 ,  C07D277/20 ,  C07D277/28 ,  C07D277/32 ,  C07D277/42 ,  C07D277/82 ,  C07D285/08 ,  C07D285/12 ,  C07D307/52 ,  C07D307/56 ,  C07D307/68 ,  C07D317/54 ,  C07D317/62 ,  C07D317/66 ,  C07D333/20 ,  C07D333/24 ,  C07D333/28 ,  C07D333/58 ,  C07D521/00 ,  C07D227/02 ,  C07C251/60 ,  C07C251/50 ,  C07C255/17 ,  C07C327/38 ,  C07D247/00 ,  C07D315/00 ,  C07D255/00 ,  C07D257/00 ,  C07D269/00 ,  A01N43/00

Abstract: The disclosure concerns oxyamino oxime ethers of formula (I), wherein: X is NOCH3, CHOCH3, CHCH3; Y is O or NZ, Z being H or alkyl; R is H or alkyl; R is cyano, nitro, trifluoromethyl, halogen, alkyl or alkoxy, m = 0, 1 or 2 and the groups R can be different if m = 2; R is H, alkyl, alkyl halide or cycloalkyl; R is H or optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkenyl, heterocyclyl, aryl, heteroaryl; R is H or alkylsulphonyl, or optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl; and their salts. Also disclosed are methods and intermediate products for use in producing them and their use for controlling harmful fungi and insect pests.

公开(公告)号：CZ231796A3

公开(公告)日：1997-02-12

申请号：CZ231796

申请日：1995-01-03

Applicant: BASF AG

Inventor： BAYER HERBERT DR ,  SAUTER HUBERT DR ,  MULLER RUTH DR ,  GRAMMENOS WASSILIOS DR ,  HARREUS ALBRECHT DR ,  KIRSTGEN REINHARD DR ,  ROHL FRANZ DR ,  AMMERMANN EBERHARD DR ,  LORENZ GISELA DR

IPC: C07C327/04 ,  A01N37/50 ,  A01N41/10 ,  A01N43/08 ,  A01N43/10 ,  A01N43/36 ,  A01N43/40 ,  A01N43/50 ,  A01N43/54 ,  A01N43/58 ,  A01N43/60 ,  A01N43/68 ,  A01N43/707 ,  A01N43/76 ,  A01N43/78 ,  A01N43/80 ,  A01N43/88 ,  A01N47/02 ,  C07C327/22 ,  A01N37/00

公开(公告)号：ES2093327T3

公开(公告)日：1996-12-16

申请号：ES93110979

申请日：1993-07-09

Applicant: BASF AG

Inventor： OBERDORF KLAUS DR ,  SAUTER HUBERT DR ,  GRAMMENOS WASSILIOS DR ,  KIRSTGEN REINHARD DR ,  HARRIES VOLKER DR ,  LORENZ GISELA DR

IPC: A01N37/18 ,  A01N37/34 ,  A01N37/36 ,  A01N37/38 ,  A01N37/50 ,  C07C251/40 ,  C07C251/48 ,  C07C251/50 ,  C07C251/52 ,  C07C251/54 ,  C07C251/58 ,  C07C251/60 ,  C07C255/32 ,  C07C255/62 ,  C07D213/63 ,  C07D333/32 ,  C07D521/00

Abstract: Substituted oxime ethers of the general formula I in which R denotes alkyl, alkenyl, alkynyl, haloalkyl, haloalkenyl, alkoxyalkyl, cycloalkyl, cycloalkylalkyl, cyanoalkyl, alkoxycarbonylalkyl, arylalkyl, heteroarylalkyl, arylalkenyl or aryloxyalkyl, the aromatic or heteroaromatic ring optionally being substituted, R and R denote hydrogen, alkyl, haloalkyl, alkoxy, haloalkoxy, halogen, cyano or nitro, R denotes hydrogen, alkyl, cycloalkyl, haloalkyl or aryl, the aromatic ring optionally being substituted and R and R are identical or different and denote hydrogen or alkyl, and X denotes CH or N, and fungicides and pesticides containing these compounds.

公开(公告)号：AT143356T

公开(公告)日：1996-10-15

申请号：AT91121148

申请日：1991-12-10

Applicant: BASF AG

Inventor： WINGERT HORST DR ,  WOLF BERND DR ,  BENOIT REMY DR ,  SAUTER HUBERT DR ,  HEPP MICHAEL DR ,  GRAMMENOS WASSILIOS DR ,  KUEKENHOEHNER THOMAS DR

IPC: C07C69/736 ,  C07C20060101 ,  C07C51/09 ,  C07C51/367 ,  C07C59/68 ,  C07C65/21 ,  C07C65/24 ,  C07C67/22 ,  C07C69/738 ,  C07C69/76 ,  C07C235/34 ,  C07C235/78 ,  C07C249/08 ,  C07C251/48 ,  C07C253/14 ,  C07C255/17 ,  C07C255/40 ,  C07C317/24

Abstract: Prepn. of 2-phenoxymethyl benzoic acid derivs. of formula (I) comprises (a) converting a phenol of formula (II) to the phenolate in the presence of a basic diluent; (b) mixing the mixt. with a lactone of formula (III); (c) distilling off the diluent; (d) reacting the mixt. at 50-250 degrees C in the melt; and (e) dissolving the liq. melt with water and acidifying. X, Y = halogen, 1-4C alkyl, 1-4C alkoxy or CF3; m = 0-4; n = 0-3.