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    85.
    发明专利
    未知

    公开(公告)号：DE59502205D1

    公开(公告)日：1998-06-25

    申请号：DE59502205

    申请日：1995-03-17

    Applicant: BASF AG

    Inventor： KIRSTGEN REINHARD DR ,  OBERDORF KLAUS DR ,  SAUTER HUBERT DR ,  BAYER HERBERT DR ,  GRAMMENOS WASSILIOS DR ,  RANG HARALD DR ,  HARRIES VOLKER DR ,  LORENZ GISELA DR ,  AMMERMANN EBERHARD DR

    IPC: A01N37/38 ,  A01N37/50 ,  A01N37/52 ,  C07C251/48 ,  C07C251/50 ,  C07C255/62 ,  C07C255/64 ,  C07C259/02 ,  C07C259/10 ,  C07C259/18 ,  C07C323/47 ,  C07C327/58 ,  C07D317/18 ,  C07D333/28 ,  C07D521/00

    Abstract: Oximino-substd benzyloxybenzene derivs of formula (I) are new. Ra = a gp. of formula (i); X = CHOMe, CH-Me or N-OMe; R1 = 1-6C alkyl (opt substd by halo, 1-4C alkoxy, CN, 1-6C alkoxycarbonyl, aryl, aryloxy or heteroaryl); 2-6C alkenyl; 3-6C alkynyl or haloalkenyl; 3-6C cycloalkyl; 3-6C cycloalkyl(1-4C)alkyl; aryl(3-6C)alkenyl; satd or unsatd 4-6 membered heterocyclyl or heterocyclyl(1-4C)alkyl where the heterocyclic rings includes 1 or 2 ring members selected from one O or S and one or two N and one or two NMe gps.; and carbocyclic or heterocyclic rings are opt substd by 1 or more halo, 1-4C alkyl or alkoxy, 1-2C haloalkyl or haloalkoxy, 3-6C cycloalkyl, aryl or aryloxy; R2 and R3 = H, halo, CN, NO2, 1-4C alkyl or alkoxy, 1-2C haloalkyl or haloalkoxy, or if on adjacent C atoms are together oxy(m)ethylideneoxy (opt substd on each C by 1 or 2 halo and/or Me); R4 = CN, Cl, Br, 1-6C alkoxy or alkylthio, 1-4C haloalkoxy, 1-4C alkoxy(1-4C)alkoxy, 3-6C cycloalkyl(1-2C)alkoxy, mon o or di(1-6C)alkylamino, 3-6C alkenyloxy or alkynyloxy, aryloxy or arylthio (aromatic rings opt substd by 1-3 of 1-4C(halo)alkyl, (halo)alkoxy or alkylthio, and additionally by halo atoms to a total no of 4 or 5 substits); R5 = NO2, CN, halo, 1-4C(halo)alkyl, (halo)alkoxy or alkylthio, phenyl or phenoxy (opt substd as aromatic rings in R4); or 2 R5 on adjacent C form a 1,3-butadiene-1,4-diyl gp. (i.e. a fused benzene ring), opt. substd by 1 or 2 halo, and opt. also by 1 or 2 of NO2, CN, halo, 1-4C haloalkyl, (halo)alkoxy or alkylthio; n = 0-4 (R5 same or different if n = 2 or more); Y = O, NH or NMe; R6 = H or 1-4C alkyl. Also new are intermediates of formulae (XI') and (IVb'). Y' = NH or NMe; R2 and R3 are above except that in (X1') they do not represent alkylenedioxy; in (IVb') Y is limited to Y'.

    86.
    发明专利
    未知

    公开(公告)号：AT166341T

    公开(公告)日：1998-06-15

    申请号：AT95103942

    申请日：1995-03-17

    Applicant: BASF AG

    Inventor： KIRSTGEN REINHARD DR ,  OBERDORF KLAUS DR ,  SAUTER HUBERT DR ,  BAYER HERBERT DR ,  GRAMMENOS WASSILIOS DR ,  RANG HARALD DR ,  HARRIES VOLKER DR ,  LORENZ GISELA DR ,  AMMERMANN EBERHARD DR

    IPC: A01N37/38 ,  A01N37/50 ,  A01N37/52 ,  C07C251/48 ,  C07C251/50 ,  C07C255/62 ,  C07C255/64 ,  C07C259/02 ,  C07C259/10 ,  C07C259/18 ,  C07C323/47 ,  C07C327/58 ,  C07D317/18 ,  C07D333/28 ,  C07D521/00

    Abstract: Oximino-substd benzyloxybenzene derivs of formula (I) are new. Ra = a gp. of formula (i); X = CHOMe, CH-Me or N-OMe; R1 = 1-6C alkyl (opt substd by halo, 1-4C alkoxy, CN, 1-6C alkoxycarbonyl, aryl, aryloxy or heteroaryl); 2-6C alkenyl; 3-6C alkynyl or haloalkenyl; 3-6C cycloalkyl; 3-6C cycloalkyl(1-4C)alkyl; aryl(3-6C)alkenyl; satd or unsatd 4-6 membered heterocyclyl or heterocyclyl(1-4C)alkyl where the heterocyclic rings includes 1 or 2 ring members selected from one O or S and one or two N and one or two NMe gps.; and carbocyclic or heterocyclic rings are opt substd by 1 or more halo, 1-4C alkyl or alkoxy, 1-2C haloalkyl or haloalkoxy, 3-6C cycloalkyl, aryl or aryloxy; R2 and R3 = H, halo, CN, NO2, 1-4C alkyl or alkoxy, 1-2C haloalkyl or haloalkoxy, or if on adjacent C atoms are together oxy(m)ethylideneoxy (opt substd on each C by 1 or 2 halo and/or Me); R4 = CN, Cl, Br, 1-6C alkoxy or alkylthio, 1-4C haloalkoxy, 1-4C alkoxy(1-4C)alkoxy, 3-6C cycloalkyl(1-2C)alkoxy, mon o or di(1-6C)alkylamino, 3-6C alkenyloxy or alkynyloxy, aryloxy or arylthio (aromatic rings opt substd by 1-3 of 1-4C(halo)alkyl, (halo)alkoxy or alkylthio, and additionally by halo atoms to a total no of 4 or 5 substits); R5 = NO2, CN, halo, 1-4C(halo)alkyl, (halo)alkoxy or alkylthio, phenyl or phenoxy (opt substd as aromatic rings in R4); or 2 R5 on adjacent C form a 1,3-butadiene-1,4-diyl gp. (i.e. a fused benzene ring), opt. substd by 1 or 2 halo, and opt. also by 1 or 2 of NO2, CN, halo, 1-4C haloalkyl, (halo)alkoxy or alkylthio; n = 0-4 (R5 same or different if n = 2 or more); Y = O, NH or NMe; R6 = H or 1-4C alkyl. Also new are intermediates of formulae (XI') and (IVb'). Y' = NH or NMe; R2 and R3 are above except that in (X1') they do not represent alkylenedioxy; in (IVb') Y is limited to Y'.

    New imino:oxy:phenyl:acetic acid derivatives
    89.
    发明专利
    New imino:oxy:phenyl:acetic acid derivatives 未知

    公开(公告)号：DE19622332A1

    公开(公告)日：1997-12-11

    申请号：DE19622332

    申请日：1996-06-04

    Applicant: BASF AG

    Inventor： GROTE THOMAS DR ,  SAUTER HUBERT DR ,  KIRSTGEN REINHARD DR ,  MUELLER RUTH DR ,  MUELLER BERND DR ,  OBERDORF KLAUS DR ,  GRAMMENOS WASSILIOS DR ,  GOETZ NORBERT DR ,  RACK MICHAEL DR ,  BAYER HERBERT DR ,  HARREUS ALBRECHT DR ,  ROEHL FRANZ DR ,  AMMERMANN EBERHARD DR ,  HARRIES VOLKER DR ,  LORENZ GISELA DR ,  STRATHMANN SIEGFRIED DR

    IPC: C07C251/60 ,  A01N37/18 ,  A01N37/40 ,  C07C57/58

    Abstract: 2-Iminooxyphenylacetic acid derivatives of formula (I) and their salts are new. R = C(CO2Me)=NOMe, C(CONHMe)=NOMe, C(CONH2)=NOMe, C(CO2Me)=COMe or C(CO2Me)=CHMe; R2 = CN, NO2, halo, 1-4C alkyl, 1-4C haloalkyl or 1-4C alkoxy; m = 0-2; R3 = H, CN, OH, halo, 1-6C alkyl (optionally substituted by halo or 1-6C alkoxy) 1-6C alkoxy, 1-6C haloalkoxy, 1-6C alkylthio, cyclopropyl, 2-6C alkenyl, or aryloxy-1-6C alkyl, benzyl or benzyloxy (all optionally ring-substituted by 1-3 CN, NO2, halo, 1-6C alkyl, 1-6C alkoxy, 1-6C haloalkyl or 1-6C haloalkoxy) or C(Me)=N-Y-Ra; Ra = 1-6C alkyl; Y = O, NH or NRa; R4 = H, CN, -Qp-C(R5)=N-Y'-R6 or -Q-O-N=CR7R8; or alkyl, alkenyl, alkynyl, cycloalkyl, heterocyclyl, aryl, heteroaryl, alkoxy, alkenyloxy, alkynyloxy, cycloalkoxy, heterocyclyloxy, aryloxy, heteroaryloxy, arylthio or heteroarylthio (all optionally substituted); or CR3R4 = 4-8 membered ring containing C atoms an optionally 1 or 2 of O, S, NH and/or N(1-4C alkyl) (optionally substituted on C by halo, 1-6C alkyl or 1-4C alkoxyimino), provided R3 and R4 are not both bonded to C via hetero atoms; Q = bond, CH2, CH(Me), CH(Et) or 1,1-cyclopropyl; p = 0 or 1; Y' = O, NH or N(1-4C alkyl); R5 = as for R3 or optionally substituted cycloalkoxy, heterocyclyloxy, aryloxy, heteroaryloxy, arylthio or heteroarylthio; R6 = optionally substituted 1-10C alkyl, 3-6C cycloalkyl, 2-10C alkenyl, 2-10C alkynyl, 1-10C alkylcarbonyl, 2-10C alkenylcarbonyl, 2-10C alkynylcarbonyl, 1-10C alkylsulphonyl, aryl, heteroaryl, arylcarbonyl, heteroarylcarbonyl, arylsulphonyl or heteroarylsulphonyl; R7, R8 = Me, Et, Ar or CH2Ar; Ar = phenyl (optionally mono-, di- or trisubstituted by CN, NO2, halo, 1-6C alkyl, 1-6C alkoxy, 1-6C haloalkyl or 1-6C haloalkoxy.

    New imino:oxy-substituted phenyl:acetic acid derivatives
    90.
    发明专利
    New imino:oxy-substituted phenyl:acetic acid derivatives 未知

    公开(公告)号：DE19548370A1

    公开(公告)日：1997-07-03

    申请号：DE19548370

    申请日：1995-12-27

    Applicant: BASF AG

    Inventor： GROTE THOMAS DR ,  SAUTER HUBERT DR ,  KIRSTGEN REINHARD DR ,  BAYER HERBERT DR ,  MUELLER RUTH DR ,  MUELLER BERND DR ,  OBERDORF KLAUS DR ,  GRAMMENOS WASSILIOS DR ,  GOETZ NORBERT DR ,  RACK MICHAEL DR ,  HARREUS ALBRECHT DR ,  ROEHL FRANZ DR ,  AMMERMANN EBERHARD DR ,  HARRIES VOLKER DR ,  LORENZ GISELA DR ,  STRATHMANN SIEGFRIED DR

    IPC: A01N37/38 ,  A01N37/50 ,  C07C251/60 ,  C07C251/56 ,  A01N35/10 ,  A01N37/10 ,  A01N37/34 ,  A01N41/04 ,  A01N43/78 ,  C07C249/12 ,  C07C249/14 ,  C07C251/58 ,  C07C255/61 ,  C07C257/06

    Abstract: 2-(2-(Iminooxy)-phenyl)-2-(methoxyimino, methoxymethylene or ethylidene)-acetic acid amide or methyl ester derivatives of formula (I) and their salts are new. R = (a) -C(=NOMe)-COOMe, (b) -C(=NOMe)-CONHMe, (c) -C(=NOMe)-CONH2, (d) -C(=CHOMe)-COOMe or (e) -C(=CHMe)-COOMe; R = CN, NO2, CF3, halogen, 1-4C alkyl or 1-4C alkoxy; m = 0-2; R = H, OH, cyclopropyl, halogen, 1-4C alkyl, CN, 1-4C alkoxy or 1-4C alkylthio; R = 1-8C alkyl, 2-8C alkenyl, 2-8C alkynyl, 3-8C cycloalkyl, aryl or heteroaryl (all optionally partially or completely halogenated or substituted by 1-3 of CN, NO2, OH, SH, NH2, COOH, CONH2, CSNH2, halogen, alkyl, haloalkyl, alkylsulphonyl, alkylsulphoxyl, 3-6C cycloalkyl, alkoxy, haloalkoxy, alkoxycarbonyl, alkylthio, mono- or dialkylamino, mono- or dialkylaminocarbonyl, mono- or dialkylaminothiocarbonyl, alkenyl, alkenyloxy, benzyl, benzyloxy, aryl, aryloxy, heteroaryl and heteroaryloxy); or R -Y-N=C(R )-; R = (i) H; (ii) 1-10C alkyl, 3-6C cycloalkyl, 2-10C alkenyl, 3-10C alkynyl, (1-10C) alkylcarbonyl, (2-10C) alkenylcarbonyl, (3-10C) alkynylcarbonyl or (1-10C) alkylsulphonyl (all optionally partially or completely halogenated or substituted by 1-3 of CN, NO2, OH, SH, NH2, COOH, CONH2, CSNH2, halogen, alkyl, haloalkyl, alkylsulphonyl, alkylsulphoxyl, 3-6C cycloalkyl, alkoxy, haloalkoxy, alkoxycarbonyl, alkylthio, mono- or dialkylamino, mono- or dialkylaminocarbonyl, mono- or dialkylaminothiocarbonyl, alkenyl, alkenyloxy, benzyl, benzyloxy, aryl, aryloxy, arylthio, heteroaryl, heteroaryloxy and heteroarylthio (where aromatic or heteroaromatic moieties are themselves optionally partially or completely halogenated or substituted by 1-3 of CN, NO2, OH, SH, NH2, COOH, CONH2, CSNH2, halogen, alkyl, haloalkyl, alkylsulphonyl, alkylsulphoxyl, 3-6C cycloalkyl, alkoxy, haloalkoxy, alkoxycarbonyl, alkylthio, mono- or dialkylamino, mono- or dialkylaminocarbonyl, mono- or dialkylaminothiocarbonyl, alkenyl, alkenyloxy, benzyl, benzyloxy, aryl, aryloxy, arylthio, heteroaryl, heteroaryloxy, heteroarylthio and -C(=NOR )-An-R )); or (iii) aryl, heteroaryl, arylcarbonyl, heteroarylcarbonyl, arylsulphonyl or heteroarylsulphonyl (all optionally partially or completely halogenated or substituted by 1-3 of CN, NO2, OH, SH, NH2, COOH, CONH2, CSNH2, halogen, alkyl, haloalkyl, alkylcarbonyl, alkylsulphonyl, alkylsulphoxyl, 3-6C cycloalkyl, alkoxy, haloalkoxy, alkoxycarbonyl, alkylthio, mono- or dialkylamino, mono- or dialkylaminocarbonyl, mono- or dialkylaminothiocarbonyl, alkenyl, alkenyloxy, benzyl, benzyloxy, aryl, aryloxy, heteroaryl, heteroaryloxy and -C(=NOR )-An-R ); A = O, S, NH or N(alkyl); n = 0 or 1; R ,R = H or alkyl; R = H, OH, halogen or as R ; Y = O or NR ; R = H or alkyl; unless specified otherwise alkyl moieties have 1-6C and alkenyl moieties 2-6C. Intermediates of formulae (IV) and (IIA) are also new. R = 1-8C alkyl; X = F or other nucleofugeous leaving group.

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