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公开(公告)号:DE10260337A1
公开(公告)日:2004-07-08
申请号:DE10260337
申请日:2002-12-20
Applicant: BASF AG
Inventor: WIESE HARM , CENTNER ALEXANDER , KIRSCH STEFAN , SCHMIDT MARCO , PIETSCH INES , LAUBENDER MATTHIAS
IPC: B05D7/00 , B05D7/24 , C08F2/22 , C08F2/44 , C08F292/00 , C08K3/00 , C09D151/10 , C08J3/02 , C09D4/02 , C09D5/02
Abstract: Aqueous dispersions (I) of composite particles comprising a polymer and fine inorganic particulate prepared by radical polymerization of a mixture of ethylenically unsaturated monomers that contains at least one ethylenically unsaturated alkoxysilane monomer in an aqueous medium in the presence of a dispersed fine particulate inorganic solid and at least one dispersing agent are useful for the priming of mineral substrates.
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公开(公告)号:DE59810540D1
公开(公告)日:2004-02-12
申请号:DE59810540
申请日:1998-10-30
Applicant: BASF AG
Inventor: ZHAO CHENG-LI , SCHWARTZ MANFRED , BECHERT BERTOLD , WIESE HARM , HUEMMER WOLFGANG
IPC: C04B41/48 , C04B41/63 , C08F20/12 , C09D133/06 , C09D201/02
Abstract: An aqueous composition (I) containing a copolymer (II), formed of ethylenically unsaturated monomers, as a film forming component, is used for coating mineral based molded articles. The copolymer (II) has a glass transition temperature of 25-80 degrees C and the monomer contains 0.2-5.0 wt.% itaconic acid. Independent claims are included for: (i) the production of coated, mineral molded articles by application of (I) onto at least one surface of the article and drying; and (ii) the resulting coated, molded article.
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公开(公告)号:AT257464T
公开(公告)日:2004-01-15
申请号:AT98120594
申请日:1998-10-30
Applicant: BASF AG
Inventor: ZHAO CHENG-LI , SCHWARTZ MANFRED , BECHERT BERTOLD , WIESE HARM , HUEMMER WOLFGANG
IPC: C04B41/48 , C04B41/63 , C08F20/12 , C09D133/06 , C09D201/02
Abstract: An aqueous composition (I) containing a copolymer (II), formed of ethylenically unsaturated monomers, as a film forming component, is used for coating mineral based molded articles. The copolymer (II) has a glass transition temperature of 25-80 degrees C and the monomer contains 0.2-5.0 wt.% itaconic acid. Independent claims are included for: (i) the production of coated, mineral molded articles by application of (I) onto at least one surface of the article and drying; and (ii) the resulting coated, molded article.
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公开(公告)号:NO20030986L
公开(公告)日:2003-03-03
申请号:NO20030986
申请日:2003-03-03
Applicant: BASF AG
Inventor: SANDOR MARIO , SCHWARTZ MANFRED , BECHERT BERTOLD , WIESE HARM
Abstract: Moldings comprise a base element consisting of a cement-bound mineral material, which may be modified with polymers, and a mineral coating present on at least one of the main surfaces of the base element and comprising a polymer-modified mineral material which contains at least one clay mineral as the main component and at least one film-forming, hydrophobic polymer distributed in the mineral material.
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公开(公告)号:CA2449887A1
公开(公告)日:2003-01-03
申请号:CA2449887
申请日:2002-06-14
Applicant: BASF AG
Inventor: WIESE HARM , XUE ZHIJIAN
IPC: C08F2/24 , C08F2/44 , C08F292/00 , C08L51/10 , C09D5/02 , C09D151/10 , C09D157/00 , C09J157/00
Abstract: The invention relates to a method for producing an aqueous dispersion of particles (composite particles) composed of a polymer and a fine-particle inorganic solid. According to said method, at least one ethylenically unsaturated monomer is dispersed in an aqueous medium and is polymerized usi ng at least one radical polymerization initiator in the presence of at least on e dispersed, fine-particle inorganic solid and at least one anionic, cationic, non-ionic dispersent, in accordance with the radical aqueous emulsion polymerization method. In said method, a) a stable aqueous dispersion of the inorganic solid(s) is used, said dispersion being characterized in that it h as an initial concentration of >= 1 wt. %, (in relation to the aqueous dispe rsion of the inorganic solid(s)) and that one hour after production it still retai ns a dispersion of 90 wt. % of the original dispersed solid, the solid particle s of said stable aqueous dispersion having a diameter
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公开(公告)号:BR0014888A
公开(公告)日:2002-06-11
申请号:BR0014888
申请日:2000-10-10
Applicant: BASF AG
Inventor: XUE ZHIJIAN , WIESE HARM
IPC: C08F2/24 , C04B20/00 , C04B40/00 , C08F2/44 , C08F212/08 , C08F292/00 , C08L51/10 , C09D151/10 , C09J151/10
Abstract: A process for preparing an aqueous dispersion of particles composed of addition polymer and finely divided inorganic solid (composite particles), in which process a mixture of ethylenically unsaturated monomers is dispersely distributed in aqueous medium and is polymerized by the method of free-radical aqueous emulsion polymerization by means of at least one free-radical polymerization initiator in the presence of at least one dispersely distributed, finely divided inorganic solid and at least one dispersant.
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公开(公告)号:DE10024561A1
公开(公告)日:2001-11-22
申请号:DE10024561
申请日:2000-05-18
Applicant: BASF AG
Inventor: XUE ZHIJIAN , WIESE HARM
IPC: B01D39/20 , B01D71/02 , B01J20/02 , B01J20/281 , B01J20/30 , B01J21/08 , B01J23/06 , B01J32/00 , B01J35/06 , B01J37/00 , B01J37/02 , C01B33/12 , C04B38/00 , C04B38/06
Abstract: Production of porous inorganic solid materials from an aqueous dispersion of particles consisting of a polymer and a finely divided inorganic solid, comprising introducing the dispersion into an open mold or onto a surface, drying at a temperature at least equal to its minimum film-forming temperature, and heating the resulting film to convert the polymer to gaseous products, is new.
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公开(公告)号:DE19950464A1
公开(公告)日:2001-04-26
申请号:DE19950464
申请日:1999-10-20
Applicant: BASF AG
Inventor: XUE ZHIJIAN , WIESE HARM
IPC: C04B20/00 , C04B40/00 , C08F2/22 , C08F2/44 , C08F212/08 , C08L51/10 , C09D151/10 , C09J151/10 , C04B24/24 , C09J139/00 , C09D139/00 , C09J133/00 , C09D133/00
Abstract: Production of an aqueous dispersion of particles comprising a polymer and a fine particulate inorganic solid (composite particles) comprises emulsion polymerization of a mixture of ethylenically unsaturated monomers in an aqueous medium by means of a radical polymerization inhibitor in the presence of a dispersed fine particulate inorganic solid and a dispersing agent. Production of an aqueous dispersion (I) of particles comprising a polymer and a fine particulate inorganic solid (composite particles) comprises emulsion polymerization of a mixture of ethylenically unsaturated monomers in an aqueous medium by means of a radical polymerization inhibitor in the presence of at least one dispersed fine particulate inorganic solid and a dispersing agent. The process is effected using (A) a stable aqueous dispersion of an inorganic solid having an initial solids concentration of at least 1 wt.% and whereby more than 90 wt.% of the original dispersed solid remains in dispersed form one hour after its preparation and having a weight average diameter of no greater than 100 nm. (B) the dispersed solid particles have an electrophoretic mobility that is different to the null point in an aqueous standard alkali chloride solution at a pH corresponding to the pH of the aqueous reaction medium at the start of the emulsion polymerzation and (C) the mixture of ethylenically unsaturated monomers comprises greater than 0 wt.% to no greater than 4 wt.% of a monomer (A) that either contains at least an acid group and/or corresponding anion if the dispersed solid inorganic particles have a positive electrophoretic mobility or contain an amino-, amido-, ureido- or N-heterocyclic group and/or an alkylated ammonium derivative protonated at the nitrogen group if the dispersed solid inorganic particles have a negative electrophoretic mobility. Independent claims are included for (i) the aqueous dispersion (I) of composite particles, and (ii) a composite particle powder prepared by drying of the aqueous dispersion (I).
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公开(公告)号:CA2387816A1
公开(公告)日:2001-04-26
申请号:CA2387816
申请日:2000-10-10
Applicant: BASF AG
Inventor: XUE ZHIJIAN , WIESE HARM
IPC: C08F2/24 , C04B20/00 , C04B40/00 , C08F2/44 , C08F212/08 , C08F292/00 , C08L51/10 , C09D151/10 , C09J151/10
Abstract: The invention relates to a method for producing an aqueous dispersion of particles (composite particles) that are made up of polymers and inorganic solid matter which consist of fine particles. A mixture of ethylenically unsaturated monomers is dispersely distributed in an aqueous medium and is polymerised according to the method of the radical aqueous emulsion polymerisation in the presence of at least one dispersely distributed inorganic solid matter which consists of fine particles and at least one dispersing means using at least one radical polymerisation initiator.
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