CHEMICAL METHOD FOR REMOVING COPPER SULPHIDE (CU2S) DEPOSITED ONTO CELLULOSE -BASED MATERIAL IN TRANSFORMER USING A COPPER COMPLEXANT
    4.
    发明申请
    CHEMICAL METHOD FOR REMOVING COPPER SULPHIDE (CU2S) DEPOSITED ONTO CELLULOSE -BASED MATERIAL IN TRANSFORMER USING A COPPER COMPLEXANT 审中-公开
    使用铜复合物将铜磷化物(CU2S)去除在变压器中的纤维素材料的化学方法

    公开(公告)号:WO2012107116A1

    公开(公告)日:2012-08-16

    申请号:PCT/EP2011/069503

    申请日:2011-12-02

    Abstract: A method for removing copper sulphide (Cu 2 S) deposited onto electrically insulating materials of components in an electrical apparatus,such as a transformer or a bushing, wherein normally present electrically insulating oil has been substantially removed, and on other surfaces of such apparatus, comprising the following steps: providing a chemical treatment solution comprising at least one non-polar solvent and at least one chelating agent being able of forming complexes with copper from the surface of Cu 2 S deposited onto the insulating material, said chelating agent containing free electrons capable of forming a complexation with Cu, being at least a bidentate, but preferably a multidentate, i.e. being able of forming complexes with Cu from more than one point in the chelating agent, and having a solubility in the non-polar solvent of at least 0,05mol/L to allow ex- traction of copper by solvation of the formed copper-chelating complex;and optionally additional components; subjecting the insulating material to the solution, preferably at a temperature of 30-130 °C,more preferably 50-90°C, for a predetermined time period, preferably 1 to 15 days, more preferably 3 to 7 days; and removing the chemical treatment solution from the insulating material.

    Abstract translation: 一种去除沉积在诸如变压器或套管的电气设备中的部件的电绝缘材料上的硫化铜(Cu2S)的方法,其中通常存在的电绝缘油已被基本上除去,并且在这种设备的其它表面上,包括 以下步骤:提供包含至少一种非极性溶剂和至少一种螯合剂的化学处理溶液,所述至少一种螯合剂能够从沉积在所述绝缘材料上的Cu2S的表面形成与铜的络合物,所述螯合剂含有能够形成 与Cu络合,至少是二齿的,但优选为多齿的,即能够在螯合剂中从多于一个点形成与Cu的络合物,并且在非极性溶剂中的溶解度至少为0.05mol / L以通过溶解所形成的铜 - 螯合络合物,以及任选的另外的组分来提供铜; 绝缘材料优选在30-130℃,更优选50-90℃的温度下进行预定时间,优选1至15天,更优选3至7天; 并从绝缘材料中除去化学处理溶液。

    METHOD FOR REMOVING COPPER SULPHIDE (CU2S) DEPOSITED ONTO CELLULOSE-BASED MATERIAL IN TRANSFORMER
    5.
    发明申请
    METHOD FOR REMOVING COPPER SULPHIDE (CU2S) DEPOSITED ONTO CELLULOSE-BASED MATERIAL IN TRANSFORMER 审中-公开
    用于去除在变压器中以纤维素为主的材料的铜硫化物(CU2S)的方法

    公开(公告)号:WO2011069757A1

    公开(公告)日:2011-06-16

    申请号:PCT/EP2010/066897

    申请日:2010-11-05

    Abstract: A method for removing copper sulphide (Cu 2 S) deposited onto electrically insulating materials of components in an electrical apparatus, such as a transformer or a bushing, wherein normally present electrically insulating oil has been substantially removed, and on other surfaces of such apparatus, comprising the following steps: providing a chemical treatment solution comprising a polar aprotic solvent, and preferably a chelating agent being able of forming complexes with copper from the surface of Cu 2 S deposited onto the insulating material, said chelating agent containing free electrons capable of forming a complexation with Cu, being at least a bidentate, but preferably a multidentate, i.e. being able of forming complexes with Cu from more than one point in the chelating agent, and having a solubility in the polar aprotic solvent of at least 5-10 -4 mol/L to allow extraction of copper by solvation of the formed copper-chelating complex; and optionally additional components, said chemical treatment solution being non-aqueous; subjecting the insulating material to the solution, preferably at a temperature of 30-130 °C, more preferably 50-90°C, for a predetermined time period, preferably 2 to 10 days, more preferably 3 to 7 days; and removing the chemical treatment solution from the insulating material.

    Abstract translation: 一种去除沉积在诸如变压器或衬套的电气设备中的部件的电绝缘材料上的硫化铜(Cu2S)的方法,其中通常存在的电绝缘油已被基本上除去,并且在这种设备的其它表面上,包括 以下步骤:提供包含极性非质子溶剂的化学处理溶液,并且优选能够与沉积在绝缘材料上的Cu2S的表面形成与铜形成络合物的螯合剂,所述螯合剂含有能够与Cu形成络合的自由电子 ,至少是二齿的,但优选是多齿的,即能够在螯合剂中从多于一个点形成与Cu的络合物,并且在极性非质子溶剂中的溶解度至少为5-10-4mol / L 通过溶解形成的铜螯合络合物来提取铜; 和任选的另外的组分,所述化学处理溶液是非水的; 绝缘材料优选在30-130℃,更优选50-90℃的温度下进行预定时间,优选2至10天,更优选3至7天; 并从绝缘材料中除去化学处理溶液。

    A VARIABLE INDUCTION DEVICE
    8.
    发明申请
    A VARIABLE INDUCTION DEVICE 审中-公开
    可变电感器件

    公开(公告)号:WO0175913A3

    公开(公告)日:2002-04-04

    申请号:PCT/EP0104405

    申请日:2001-04-02

    CPC classification number: H01F29/10

    Abstract: An induction device comprises a core (1) of magnetically permeable material, and is characterized in that the core comprises at least one component (3, 4, 5) comprising finely divided magnetic particles in a matrix of a dielectric material, and the inductance of the device is variable by changing the effective magnetic permeability of the at least one component. This can be achieved by replacing or moving the at least one component, which may be formed by uniting elongate members, some of which have a different magnetic permeability from others.

    Abstract translation: 一种感应装置包括一个导磁材料的芯体,其特征在于,该芯部包括至少一个包含介电材料的矩阵中的细分散的磁性颗粒的组件(3,4,5)和 通过改变至少一个部件的有效磁导率可以改变装置。 这可以通过更换或移动至少一个组件来实现,该组件可以通过将细长构件结合在一起而形成,细长构件中的一些与其它构件具有不同的磁导率。

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