Monomers for preparing arylamine-substituted poly(arylene-vinylenes)
    1.
    发明授权
    Monomers for preparing arylamine-substituted poly(arylene-vinylenes) 有权
    用于制备芳基胺取代的聚(亚芳基 - 烯烃)的单体

    公开(公告)号:US6372881B2

    公开(公告)日:2002-04-16

    申请号:US91292701

    申请日:2001-07-24

    Inventor: PEI QIBING

    Abstract: The invention provides novel conjugated polymers comprised of arylamine-substituted poly(arylene vinylenes). The polymers have the general structure (I)wherein: Ar is arylene, heteroarylene, substituted arylene or substituted heteroarylene containing one to three aromatic rings; R1 is an arylamine substituent having the formula -Ar1-N(R4R5) wherein Ar1 is as defined for Ar and R4 and R5 are independently hydrocarbyl, substituted hydrocarbyl, heteroatom-containing hydrocarbyl, or substituted heteroatom-containing hydrocarbyl, or together form a cyclic group; and R2 and R3 are independently selected from the group consisting of hydrido, halo and cyano, or may be as defined for R4 and R5, or may together form a triple bond. Monomeric precursors and methods of synthesizing the precursors are also provided, as are electroluminescence and other devices containing a polymer of the invention.

    Abstract translation: 本发明提供由芳基胺取代的聚(亚芳基乙烯基)构成的新型共轭聚合物。 聚合物具有通式(I),其中:Ar是亚芳基,亚杂芳基,取代的亚芳基或含1至3个芳环的取代的亚杂芳基; R1是具有式-Ar1-N(R4R5)的芳基胺取代基,其中Ar1如对Ar和R4所定义,R5独立地是烃基,取代的烃基,含杂原子的烃基或取代的含杂原子的烃基,或一起形成环状 组; 并且R 2和R 3独立地选自氢,卤素和氰基,或可以如R4和R5所定义,或者可以一起形成三键。 还提供单体前体和合成前体的方法,电致发光和含有本发明聚合物的其它装置也是如此。

    READY RESPONSE MICROSENSOR FOR GASEOUS AND VAPOROUS OBJECT

    公开(公告)号:JPS6488245A

    公开(公告)日:1989-04-03

    申请号:JP17384588

    申请日:1988-07-14

    Abstract: PURPOSE: To achieve a prompt response by providing a substrate with an opening, a gas transmission detection electrode, and an additional electrode that contacts an electrolyte and is electrically insulated from the detection electrode and enabling a gas to be analyzed to reach the electrolyte at a gas phase. CONSTITUTION: A passage 18 is formed between surfaces 14 and 16 of a substrate 12, a gas transmission detection electrode 20 is arranged across the passage 18, and an electrolyte 26 is brought into contact with a dielectric layer 22 and a surface side 21 of the electrode 20. Also, a porous member 30 is arranged closer to the electrode 20 within the passage 18, at the same time a counter electrode 24 is arranged so that it contacts the electrolyte 26 and is insulated from the electrode 20, and a capsule is formed by a means 28. Then, for responding to various kinds of gas-shaped objects, the structure of the electrolyte 26 and the size of a hole in the electrode 20 are selected and a gas to be analyzed is passed through the hole of the electrode 20 in gaseous phase, thus achieving an extremely fast response time and a long life.

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