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Patent Agency Ranking
公开(公告)号：KR1020140085974A
公开(公告)日：2014-07-08
申请号：KR1020120155910
申请日：2012-12-28
Applicant: 고등기술연구원연구조합
IPC: C07D403/12 , C07D233/84 , C10G1/00
Abstract: Disclosed is a method for synthesizing an ionic liquid for dissolving coal. The method for synthesizing an ionic liquid for dissolving coal disclosed according to an embodiment of the present invention comprises the steps of: (S100) dissolving a first precursor in methylene chloride at an appropriate ratio in order to be cooled; (S200) injecting tosyl chloride and potassium hydroxide in the solution; (S300) agitating the solution at room temperature after a particular period of time in order to be changed into a white suspension, washing a filtrate several times with distilled water in a filtering process, removing the moisture of an organic layer, and performing vacuum concentration; (S400) synthesizing a second precursor which is a white solid through a plurality of column chromatography techniques; (S500) injecting methylimidazole in the second precursor in order to be mixed into a solvent which is also a reagent; (S600) performing a reflux process at an appropriate temperature; and (S700) obtaining a plurality of final ionic liquids by washing layer-separated oil with anhydrous ether dozens of times.
Abstract translation: 公开了一种合成用于溶解煤的离子液体的方法。 根据本发明实施方案的合成溶解煤的离子液体的方法包括以下步骤：（S100）以适当的比例将第一前体溶解在二氯甲烷中以便冷却; （S200）在溶液中注入甲苯磺酰氯和氢氧化钾; （S300）在特定时间后在室温下搅拌溶液，以便变成白色悬浮液，在过滤过程中用蒸馏水洗涤滤液数次，除去有机层的水分，并进行真空浓缩 ; （S400）通过多个柱色谱技术合成作为白色固体的第二前体; （S500）在第二前体中注入甲基咪唑以便混合到也是试剂的溶剂中; （S600）在适当的温度下进行回流处理; 和（S700）通过用无水乙醚洗涤分层的油几十次获得多个最终的离子液体。
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公开(公告)号：KR101508710B1
公开(公告)日：2015-04-06
申请号：KR1020120155910
申请日：2012-12-28
Applicant: 고등기술연구원연구조합
IPC: C07D403/12 , C07D233/84 , C10G1/00
Abstract: 석탄용해용이온성액체합성법을개시한다. 본발명의일 실시예에따라개시된석탄용해용이온성액체합성법은 1차전구체를메틸렌클로라이드에적절한비율로용해시켜냉각하는과정(S100); 상기용해액에토실클로라이드와포타슘하이드록사이드를투입하는과정(S200); 일정시간의경과후, 상온에서교반시켜, 희색현탁액으로변화시킨다음, 여과과정에서여액을증류수로수차례세척한후, 유기층에대하여수분을제거시킨후 감압농축하는과정(S300); 복수의컬럼크로마토그래피법으로흰색고체의 2차전구체를합성하는과정(S400); 상기 2차전구체에메틸이미다졸을주입하여용매겸시약으로혼합시키는과정(S500); 적절한온도에서환류시키는과정(S600); 및층분리된오일을무수에테르로수십차례세척하여복수의최종이온성액체를얻는과정(S700)을포함한다.
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公开(公告)号：KR101489852B1
公开(公告)日：2015-02-09
申请号：KR1020120146355
申请日：2012-12-14
Applicant: 고등기술연구원연구조합
Abstract: 개시된 합성가스내 황 회수 방법은 복수개의 탈황/재생 반응기의 각각에 고정된 촉매에 황화합물이 흡착되도록 상기 황성분을 포함하는 상기 합성가스가 유입되는 탈황 반응을 거쳐, 상기 황성분이 제거된 정제된 합성가스를 배출하는 공정과, 상기 탈황/재생 반응기의 촉매에 흡착된 상기 황화합물의 산화를 위해 산소가 공급되는 재생 반응을 거쳐, 상기 촉매의 산화반응에 의해 이산화황으로 전환되어 배출하는 공정과, 상기 재생 반응을 거쳐 산화된 상기 황화합물을 황 회수 반응기로 공급하는 공정과, 상기 황 회수 반응기에서 환원반응에 의해 이산화황이 황으로의 전환반응이 일어나도록 환원제를 공급하여 상기 황이 고체로서 분리되는 공정과, 상기 분리된 원소 황을 회수하도록 배출하는 공정을 포함한다.
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公开(公告)号：KR1020140078039A
公开(公告)日：2014-06-25
申请号：KR1020120146355
申请日：2012-12-14
Applicant: 고등기술연구원연구조합
CPC classification number: B01D53/48 , B01D53/86 , B01D53/90 , B01D53/96 , B01D2251/202 , C01B17/021
Abstract: Disclosed is a method for collecting sulfur from a synthetic gas. The method comprises the steps of performing desulfurization by which the synthetic gas including sulfur components is fed so that sulfur compounds are attached on a catalyst that is fixed to each of multiple desulfurization/reproduction reactors and discharging a purified synthetic gas from which the sulfur components are removed; performing reproduction by which oxygen is supplied so that the sulfur compounds attached on the catalyst of the desulfurization/reproduction reactors are oxidized and discharging sulfur dioxide that is converted from the sulfur compounds by means of the oxidation of the catalyst; supplying the sulfur compounds that are oxidized through the reproduction to a sulfur collecting reactor; separating sulfur as a solid by supplying a reducing agent so that the sulfur dioxide is converted into sulfur through reduction in the sulfur collecting reactor; and discharging the separated elemental sulfur in order to be collected.
Abstract translation: 公开了从合成气体中收集硫的方法。 该方法包括以下步骤：进行脱硫，通过该脱硫，含有硫成分的合成气体被供给，使得硫化合物附着在固定于多个脱硫/再生反应器中的催化剂上，并排出硫成分为 删除; 进行供给氧的再生，使得附着在脱硫/再生反应器的催化剂上的硫化合物被氧化并排出通过催化剂的氧化从硫化合物转化的二氧化硫; 将通过再生产氧化的硫化合物供应给硫收集反应器; 通过供给还原剂将硫作为固体分离，从而通过硫采集反应器中的还原将二氧化硫转化为硫; 并排出分离的元素硫以便收集。
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公开(公告)号：KR100859743B1
公开(公告)日：2008-09-24
申请号：KR1020070055982
申请日：2007-06-08
Applicant: 고등기술연구원연구조합
CPC classification number: B01J37/031 , B01J21/04 , B01J23/06 , B01J23/72 , C07C41/01
Abstract: A method for preparing a Cu-Zn-Al based hybrid catalyst, the Cu-Zn-Al based hybrid catalyst prepared by the method, and a method for directly synthesizing dimethylether from syngas using the Cu-Zn-Al based hybrid catalyst are provided, wherein the Cu-Zn-Al based hybrid catalyst synthesizes dimethylether at high purity and high yield from syngas by maintaining excellent activity compared to existing hybrid catalysts. A method for preparing a Cu-Zn-Al based hybrid catalyst comprises the steps of: (1) dissolving copper(II) acetate(Cu(C2H3O2)2) and zinc acetate(Zn(C2H3O2)2) into water to form an aqueous Cu-Zn precursor solution; (2) adding an ammonium carbonate((NH4)2CO3) precipitant into the aqueous Cu-Zn precursor solution of the step(1) at a rate of 3 to 15 ml/min to coprecipitate Cu and Zn; and (3) filtering, cleaning, drying, and firing a sediment produced in the step(2) to obtain a Cu-Zn based oxide, and mixing the Cu-Zn based oxide with gamma-alumina(gamma-Al2O3). The copper(II) acetate and zinc acetate are used in the amount satisfying a Cu to Zn mole ratio of 5 to 9:1 to 5 in the step(1). The ammonium carbonate precipitant is added into the aqueous Cu-Zn precursor solution at a rate of 4.5 to 10 ml/min in the step(2). The ammonium carbonate precipitant is added in the form of an aqueous solution with a concentration of 1 to 3 M in the step(2). Further, a mixing ratio of the Cu-Zn based oxide and the gamma-alumina is 4 to 6:6 to 4.
Abstract translation: 提供了一种制备Cu-Zn-Al系杂合催化剂的方法，通过该方法制备的Cu-Zn-Al系混合催化剂和使用Cu-Zn-Al系混合催化剂从合成气中直接合成二甲醚的方法， 其中基于Cu-Zn-Al的杂化催化剂通过与现有的混合催化剂相比保持优异的活性，从合成气合成高纯度的二甲醚和高收率。 制备Cu-Zn-Al系杂合催化剂的方法包括以下步骤：（1）将乙酸铜（II）（Cu（C 2 H 3 O 2）2）和乙酸锌（Zn（C 2 H 3 O 2）2）溶解在水中形成水 Cu-Zn前体溶液; （2）以3〜15ml / min的速度将碳酸铵（（NH 4）2 CO 3）沉淀剂加入步骤（1）的Cu-Zn前体水溶液中以共沉淀Cu和Zn; （3）过滤，清洗，干燥和烧制步骤（2）中产生的沉淀物，得到Cu-Zn基氧化物，并将Cu-Zn基氧化物与γ-氧化铝（γ-Al 2 O 3）混合。 在步骤（1）中，乙酸铜（II）和乙酸锌是以满足Cu-Zn摩尔比为5至9:1至5的量使用的。 在步骤（2）中，以4.5-10ml / min的速率将碳酸铵沉淀剂加入到Cu-Zn前体水溶液中。 在步骤（2）中，以浓度为1至3M的水溶液的形式加入碳酸铵沉淀剂。 此外，Cu-Zn基氧化物和γ-氧化铝的混合比为4〜6：6〜4。
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