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公开(公告)号：KR1020100128047A
公开(公告)日：2010-12-07
申请号：KR1020090046479
申请日：2009-05-27
Applicant: 성균관대학교산학협력단 , 한국화학연구원
IPC: C07F9/6509 , C08K5/5399 , C08L25/04 , C08L55/02
CPC classification number: C07F9/650952 , C08K5/5399 , C08L2201/02 , C08L2666/84 , C09K21/12
Abstract: PURPOSE: A novel phosphorus piperazine and thermoplastic resin composition containing the same are provided to produce flame retardant thermoplastic resin with environmentally-friendly characteristics. CONSTITUTION: A phosphorus piperazine is denoted by chemical formula 1. The phosphorus piperazine compound is prepared by reacting the piperazine with a phosphorus compound of chemical formula 2 and adding tertiary amine. A flame retardant thermoplastic resin composition contains 100 weight parts of alloy of ABS resin, EVA resin, resin copolymer thereof, or a resin thereof and 10-50 weight parts of phosphorus piperazine compound.
Abstract translation: 目的：提供一种新型磷哌嗪和含有它们的热塑性树脂组合物，以制备具有环保特性的阻燃热塑性树脂。 构成：磷哌嗪由化学式1表示。通过使哌嗪与化学式2的磷化合物反应并加入叔胺制备磷哌嗪化合物。 阻燃热塑性树脂组合物含有100重量份的ABS树脂，EVA树脂，其树脂共聚物或其树脂和10-50重量份的磷哌嗪化合物的合金。
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公开(公告)号：KR101064667B1
公开(公告)日：2011-09-15
申请号：KR1020090046479
申请日：2009-05-27
Applicant: 성균관대학교산학협력단 , 한국화학연구원
IPC: C07F9/6509 , C08K5/5399 , C08L25/04 , C08L55/02
Abstract: 본 발명은 하기 화학식 1로 표시되는 신규 인계 피페라진 화합물, 그 제조방법, 및 상기 화합물을 포함하는 열가소성 수지 조성물을 제공한다. 본 발명에 따른 화합물을 열가소성 수지에 적용할 경우, 연소시 환경오염이 없는 친환경적 특성 및 우수한 난연성을 갖는 난연성 열가소성 수지를 제공할 수 있다.
[화학식 1]
(상기 식에서, R
1 과 R
2 는 서로 같거나 다르며, 탄소 수 1~6개의 알킬, 알콕시, 또는 탄소 수 6~12개의 아릴기임)
난연제, 열가소성 수지, 인계 유기 화합물, 인계 난연제, 인계 피페라진, 피페라진디일-N,N'-비스(포스포아미데이트)-
公开(公告)号：KR1020100128046A
公开(公告)日：2010-12-07
申请号：KR1020090046477
申请日：2009-05-27
Applicant: 성균관대학교산학협력단 , 한국화학연구원
Abstract: PURPOSE: A phenylene phosphoramidate compound, a manufacturing method thereof, and a flame-retardant thermoplastic resin composition containing thereof are provided to secure the fire retardant property to various thermoplastic resins with the small amount of phenylene phosphoramidate compound. CONSTITUTION: A phenylene phosphoramidate compound is marked with chemical formula 1. In the chemical formula 1, R1 and R2 are selected from the group consisting of alkyl or alkoxy with 1~6 carbons, and aryl or aryloxy with 6~12 carbons. A flame-retardant thermoplastic resin composition contains the following: 100 parts of an acrylonitrile butadiene styrene resin, an ethylene-vinyl acetate resin, their copolymers, and their alloy by weight; and 10~50 parts of phenylene phosphoramidate compound by weight.
Abstract translation: 目的：提供亚苯基氨基磷酸酯化合物及其制造方法以及含有它们的阻燃性热塑性树脂组合物，以将少量的亚苯基氨基磷酸酯化合物的阻燃性确保为各种热塑性树脂。 化学式1中，R1和R2选自碳原子数为1〜6的烷基或烷氧基，碳原子数为6〜12的芳基或芳氧基。 阻燃热塑性树脂组合物含有以下物质：100份丙烯腈 - 丁二烯 - 苯乙烯树脂，乙烯 - 乙酸乙烯酯树脂，它们的共聚物和它们的合金重量; 和10〜50份亚苯基氨基磷酸酯化合物。
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公开(公告)号：KR101975277B1
公开(公告)日：2019-05-07
申请号：KR1020170112762
申请日：2017-09-04
Applicant: 성균관대학교산학협력단
IPC: C07F9/6574 , C08L69/00 , C08K5/5333 , C08K5/521
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5.发明授权내변색성과 내열성이 우수한 비할로겐 난연제 및 비할로겐 난연조제를 함유하는 폴리시클로헥실렌디메틸렌테레프탈레이트 수지 조성물 有权耐色性和高耐热性含有非卤素阻燃剂和非卤素阻燃助剂的聚环己基 - 二甲基对苯二甲酸乙二醇酯树脂组合物
公开(公告)号：KR101578604B1
公开(公告)日：2015-12-17
申请号：KR1020140046003
申请日：2014-04-17
Applicant: 성균관대학교산학협력단
IPC: C08L67/02 , C08K5/5373 , C08L67/03 , C08K3/00
CPC classification number: C08K5/52 , C08K5/5313 , C08K5/5317 , C08K5/5333 , C08K7/14 , C08L67/02
Abstract: 본발명은폴리시클로헥실렌디메틸렌테레프탈레이트수지조성물에관한것으로, 더욱상세하게는비스(2,6,7-트리옥사-1-포스파바이사이클로[2,2,2]-옥테인-1-옥소-4-하이드록시메틸) 페닐포스포네이트(Bis(2,6,7-trioxa-1-phosphabicyclo[2.2.2]octane-1-oxo-4-hydroxymethyl) phenylphosphonate)의비할로겐난연조제를함유함으로써경제적이면서도난연성및 내변색성이우수한폴리시클로헥실렌디메틸렌테레프탈레이트수지조성물에관한것이다. 나아가상기본 발명에따른수지조성물의특성을이용한난연성성형품은디스플레이를포함한각종전기전자부품이나, 자동차부품으로사용될수 있다.
Abstract translation: 本发明涉及一种聚环己基 - 二亚甲基对苯二甲酸乙二醇酯树脂组合物，更具体地说涉及一种含有非卤素阻燃助剂的经济，高耐色，阻燃的聚环己基 - 三氧杂-1-磷[2.2.2]辛烷-1-氧代-4-羟甲基）苯基膦。 此外，使用本发明的树脂组合物的特征的阻燃成型体可以用作包括显示器或汽车部件在内的各种电气和电子部件。
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Patent Agency Ranking6.发明公开내변색성과 내열성이 우수한 비할로겐 난연제 및 비할로겐 난연조제를 함유하는 폴리시클로헥실렌디메틸렌테레프탈레이트 수지 조성물 有权耐高温和耐高温聚环氧乙烯二甲基二硅氧烷树脂组合物含有非卤化物阻燃剂和非卤化物阻燃剂
公开(公告)号：KR1020150120148A
公开(公告)日：2015-10-27
申请号：KR1020140046003
申请日：2014-04-17
Applicant: 성균관대학교산학협력단
IPC: C08L67/02 , C08K5/5373 , C08L67/03 , C08K3/00
CPC classification number: C08K5/52 , C08K5/5313 , C08K5/5317 , C08K5/5333 , C08K7/14 , C08L67/02 , C08K3/00 , C08K5/5373 , C08L67/03
Abstract: 본발명은폴리시클로헥실렌디메틸렌테레프탈레이트수지조성물에관한것으로, 더욱상세하게는비스(2,6,7-트리옥사-1-포스파바이사이클로[2,2,2]-옥테인-1-옥소-4-하이드록시메틸) 페닐포스포네이트(Bis(2,6,7-trioxa-1-phosphabicyclo[2.2.2]octane-1-oxo-4-hydroxymethyl) phenylphosphonate)의비할로겐난연조제를함유함으로써경제적이면서도난연성및 내변색성이우수한폴리시클로헥실렌디메틸렌테레프탈레이트수지조성물에관한것이다. 나아가상기본 발명에따른수지조성물의특성을이용한난연성성형품은디스플레이를포함한각종전기전자부품이나, 자동차부품으로사용될수 있다.
Abstract translation: 本发明涉及聚环己基 - 二甲基对苯二甲酸乙二醇酯树脂组合物。 更具体地说，本发明涉及一种聚环己基 - 二甲基对苯二甲酸乙二醇酯树脂组合物，其包含双（2,6,7-三氧杂-1-磷杂双环[2.2.2]辛烷-1-氧代 - 4-羟甲基）苯基膦酸酯，因此是经济的并且具有优异的阻燃性和阻燃性。 此外，通过使用根据本发明的树脂组合物的性质制造的阻燃成型产品可以用作各种电气或电子设备，例如显示器或汽车部件。
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公开(公告)号：KR1020100116419A
公开(公告)日：2010-11-01
申请号：KR1020090035107
申请日：2009-04-22
Applicant: 한국화학연구원
CPC classification number: H01M4/926 , B01J23/42 , B01J37/16 , H01M2004/8689 , H01M2008/1095 , Y02E60/521
Abstract: PURPOSE: A manufacturing method of a Pt/C cathode catalyst for a fuel cell is provided to effectively manufacture the catalyst with the excellent oxygen reduction reaction activity and the minimized platinum carrying amount. CONSTITUTION: A manufacturing method of a Pt/C cathode catalyst for a fuel cell comprises the following steps: mixing a carbon supporter and a platinum metal precursor inside a solvent, and reducing the mixture to carry 15~25wt% of platinum particles on the carbon supporter; and heat-processing the carbon supporter in 400~600 deg C to make the size of the platinum particles of 2~6 nanometers, and the full width at half maximum of 0.8~1.2 degrees.
Abstract translation: 目的：提供一种用于燃料电池的Pt / C阴极催化剂的制造方法，以有效地制造具有优异的氧还原反应活性和最小化铂载量的催化剂。 构成：用于燃料电池的Pt / C阴极催化剂的制造方法包括以下步骤：将碳载体和铂金属前体混合在溶剂内，并将该混合物还原为在载体上携带15〜25wt％的铂颗粒 支持者; 并在400〜600摄氏度下对碳载体进行加热处理，使铂粒子的尺寸为2〜6纳米，半宽度为0.8〜1.2度。
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公开(公告)号：KR100555021B1
公开(公告)日：2006-03-03
申请号：KR1020030060178
申请日：2003-08-29
Applicant: 한국화학연구원 , 크리스탈지노믹스(주)
IPC: C07D241/44
Abstract: 발명은 하기 화학식 1의 퀴녹살린 유도체, 이의 제조방법 및 이를 함유하는 항암 조성물에 관한 것으로, 본 발명의 퀴녹살린 유도체는 히스톤 디아세틸라제의 효소활성을 효과적으로 억제하여 종양세포의 증식을 억제할 수 있다.
상기 식에서,
R
1 은 히드록시, 할로겐, 알킬옥시, 알킬, 아미노, 알킬아미노, 카르복실, 니트로, 아미드 및 술폰으로 이루어진 군으로부터 선택된 하나 이상의 치환체로 치환되거나 치환되지 않은, 아릴, 헤테로아릴 또는 C
3-8 사이클로알킬이고, 이때 상기 헤테로아릴은 고리 중에 질소, 황 또는 산소를 하나 이상 포함하며;
R
2 는 수소 또는 아릴알킬이고;
A는 O, S, CH
2 , 술폰(SO
2 ), 술폭사이드(SO), CONH, NHCO, NX 또는 NXSO
2 (이때, X는 수소, C
1-5 알킬, 또는 독립적으로 상기 R
1 과 동일하게 정의된다)이고;
n은 0, 1, 2 또는 3이다.-
公开(公告)号：KR1020050023107A
公开(公告)日：2005-03-09
申请号：KR1020030060178
申请日：2003-08-29
Applicant: 한국화학연구원 , 크리스탈지노믹스(주)
IPC: C07D241/44
Abstract: PURPOSE: Quinoxaline derivatives and a preparation method thereof are provided, which derivatives have inhibitory activity against histone deacetylase, which removes an acetyl group from the lysine tail in the N-terminal of histone, by selectively inducing the terminal differentiation of the tumor cells, and thus by inhibiting the growth of tumor cells. CONSTITUTION: The quinoxaline derivatives represented by formula (1) are provided, wherein R1 is aryl, heteroaryl or C3-C8 cycloalkyl which is optionally substituted by one or more substituents selected from hydroxy, halogen, alkyloxy, alkyl, amino, alkylamino, carboxyl, nitro, amide and sulfone in which the heteroaryl contains one or more elements selected from nitrogen, sulfur and oxygen in a ring; R2 is hydrogen or arylalkyl; A is O, S, CH2, sulfone(SO2), sulfoxide(SO), CONH, NHCO, NX or NXSO2 in which X is hydrogen, C1-5 alkyl or independently the same as R1; and n is 0, 1, 2 or 3. The method for preparing a compound of formula (2) comprises the steps of: (a) acylation of 2-bromo arylalkyl carboxylic acid of formula (6) with 3,4-diamino benzoic ester of formula (7) in an aprotic solvent to prepare a compound of formula (8); (b) cyclization of the compounds of formula (8) in the presence of inorganic salts to prepare quinoxaline ester of formula (9); (c) treating the quinoxaline ester of formula (9) with hydroxide salts to prepare an organic acid of formula (10); and (d) acylation of the organic acid of formula (10) with the protected hydroxyl amine and hydrogenating the reaction product in the presence of palladium, wherein Y is O, S, CH2, SO2, SO or NX.
Abstract translation: 目的：提供喹喔啉衍生物及其制备方法，该衍生物通过选择性诱导肿瘤细胞的末端分化而对组蛋白脱乙酰酶具有抑制活性，其通过选择性诱导肿瘤细胞的末端分化而从组蛋白的N末端的赖氨酸尾部除去乙酰基， 从而通过抑制肿瘤细胞的生长。 组成：提供由式（1）表示的喹喔啉衍生物，其中R 1是芳基，杂芳基或任选被一个或多个选自羟基，卤素，烷氧基，烷基，氨基，烷基氨基，羧基， 硝基，酰胺和砜，其中杂芳基在环中含有一个或多个选自氮，硫和氧的元素; R2是氢或芳基烷基; A是O，S，CH2，砜（SO2），亚砜（SO），CONH，NHCO，NX或NXSO2，其中X是氢，C1-5烷基或与R1独立地相同; 制备式（2）化合物的方法包括以下步骤：（a）将式（6）的2-溴芳基烷基羧酸与3,4-二氨基苯甲酸 （7）的酯在非质子溶剂中制备式（8）的化合物; （b）在无机盐存在下环化式（8）化合物以制备式（9）的喹喔啉酯; （c）用氢氧化物盐处理式（9）的喹喔啉酯以制备式（10）的有机酸; 和（d）用保护的羟基胺酰化式（10）的有机酸，并在钯存在下氢化反应产物，其中Y是O，S，CH 2，SO 2，SO或NX。
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公开(公告)号：KR102087376B1
公开(公告)日：2020-03-10
申请号：KR1020180083400
申请日：2018-07-18
Applicant: 성균관대학교산학협력단
IPC: C07F9/6574 , C08K5/527 , C08L69/00 , C08K5/00
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