公开(公告)号：KR100886415B1

公开(公告)日：2009-03-02

申请号：KR1020070061787

申请日：2007-06-22

Applicant: 제일모직주식회사

Inventor： 문형랑 ,  김일진 ,  권기혜 ,  박재범 ,  공성호

IPC: C09K21/04 ,  B82B3/00 ,  B82Y40/00

Abstract: 본 발명에 따른 난연 특성을 갖는 나노입자는 (A) 히드록시기를 표면에 갖는 콜로이달 나노입자와 (B) 상기 히드록시기와 화학 결합이 가능한 작용기를 최소한 하나 이상을 갖는 인계 화합물을 반응시켜 나노입자의 표면에 상기 인계 화합물이 화학적으로 결합된 구조를 갖는 것을 특징으로 한다.
나노입자, 난연성, 히드록시기, 인계 화합물, 표면처리, 콜로이달 금속, 금속 산화물, 금속 수산화물

公开(公告)号：KR100762298B1

公开(公告)日：2007-10-04

申请号：KR1020060138133

申请日：2006-12-29

Applicant: 제일모직주식회사

Inventor： 권기혜 ,  김일진 ,  문형랑 ,  박재범 ,  공성호

IPC: C08K3/10 ,  C08K5/5415 ,  C08L101/00 ,  B82Y30/00

CPC classification number: C08K9/06

Abstract: A thermoplastic nanocomposite resin composition is provided to improve scratch resistance while maintaining good physical properties including processability, impact resistance and heat resistance, and to reduce the amount of inorganic fillers. A thermoplastic nanocomposite resin composition having improved scratch resistance comprises: (A) 100 parts by weight of a thermoplastic resin; and (B) 0.1-50 parts by weight of metal (oxide) nanoparticles surface-demineralized with a silane-based compound. The thermoplastic resin is selected from the group consisting of polycarbonate, polyolefin, polyvinyl chloride, polyphenylene ether, polyphenylene sulfide, polyester, polyamide, (meth)acrylate polymer, aromatic vinyl compound copolymer resin, rubber-modified aromatic vinyl graft copolymer resin, aromatic vinyl compound-vinyl cyanide compound copolymer resin and a mixture thereof.

Abstract translation: 提供热塑性纳米复合树脂组合物以改善耐刮擦性，同时保持包括加工性，耐冲击性和耐热性在内的良好的物理性能，并减少无机填料的量。 具有改善耐刮擦性的热塑性纳米复合材料树脂组合物包括：（A）100重量份的热塑性树脂; 和（B）0.1-30重量份用硅烷类化合物表面去矿化的金属（氧化物）纳米颗粒。 热塑性树脂选自聚碳酸酯，聚烯烃，聚氯乙烯，聚苯醚，聚苯硫醚，聚酯，聚酰胺，（甲基）丙烯酸酯聚合物，芳族乙烯基化合物共聚物树脂，橡胶改性芳族乙烯基接枝共聚物树脂，芳族乙烯基 化合物 - 乙烯基氰化合物共聚物树脂及其混合物。

公开(公告)号：KR100717514B1

公开(公告)日：2007-05-11

申请号：KR1020050135079

申请日：2005-12-30

Applicant: 제일모직주식회사

Inventor： 김일진 ,  권오성 ,  박재범

IPC: C08F8/00 ,  C08K3/00 ,  C08K3/12 ,  B82Y30/00

Abstract: 본 발명의 나노복합체는 (A) 비닐계 화합물 100 중량부에 (B) 히드록시기를 갖는 콜로이달 금속(산화물)을 관능기를 갖는 알콕시 실란 화합물로 표면처리하여 생성된 소수성이 증가된 표면 유기화된 콜로이달 금속(산화물) 나노입자 0.1∼50 중량부를 중합하여 나노입자 표면에 비닐계 화합물이 그라프트 중합된 형태로 제조된다. 상기로부터 제조된 나노복합체 100 중량부에 1∼99 중량부의 열가소성 수지를 혼합하여 열가소성 나노복합재 수지 조성물을 제조한다.
열가소성 나노복합체, 표면 유기화, 콜로이달 금속(산화물), 알콕시 실란 화합물

Abstract translation: 本发明的纳米复合材料包含（A）100重量份的乙烯基化合物，（B）具有羟基的胶体金属（氧化物）和具有​​官能团的烷氧基硅烷化合物， 0.1至50重量份的金属（氧化物）纳米颗粒聚合并接枝聚合在纳米颗粒的表面上。 将100重量份上述制备的纳米复合材料与1至99重量份的热塑性树脂混合以制备热塑性纳米复合树脂组合物。

公开(公告)号：KR100539374B1

公开(公告)日：2005-12-27

申请号：KR1020040095148

申请日：2004-11-19

Applicant: 제일모직주식회사

Inventor： 박재범 ,  하두한

IPC: C08F279/04 ,  C08F2/24

Abstract: 본 발명의 열가소성 수지의 제조방법은 고무질 중합체 10∼30 중량부에 이온교환수를 투입하고, 스티렌 단량체 7∼10 중량부, 아크릴로니트릴 단량체 2∼6 중량부 및 분자량 조절제를 혼합하여 투입하고, 유화제를 투입한 후 교반하면서 승온한 후 중합 개시제를 투입하여 1차 그라프트 공중합체 라텍스를 제조하는 제1단계; 상기 1차 그라프트 공중합체 라텍스의 존재 하 아크릴로니트릴 단량체 15∼25 중량부, α-메틸스티렌 단량체 40∼55 중량부, 분자량 조절제 및 중합 개시제를 투입하여 2차 그라프트 공중합체 라텍스를 제조하는 제2단계; 및 상기 2차 그라프트 공중합체 라텍스에 할로겐계 화합물 5∼15 중량부를 투입하고 교반한 후, 응집시키는 제3단계로 이루어지는 것을 특징으로 한다.

公开(公告)号：KR100455101B1

公开(公告)日：2004-11-06

申请号：KR1020010073352

申请日：2001-11-23

Applicant: 제일모직주식회사

Inventor： 박재범 ,  하두한 ,  임용환 ,  김경수

IPC: C08F279/04

Abstract: PURPOSE: A process for preparing a SAN(acrylonitrile-butadiene-styrene) graft copolymer of core-shell structure having excellent appearance and whiteness and high rubber content is provided. CONSTITUTION: The process for preparing a SAN graft copolymer comprises the steps of: introducing ion exchanged water into which a water soluble initiator is dissolved, and an emulsifier into a polybutadiene elastomeric polymer having an average particle diameter of 0.28 to 0.33 micrometers and gel content of 75 to 85 wt%; heating the mixture to 55 to 65 deg.C in order to swell the water soluble initiator into the elastomeric polymer and in order to decompose to form a radical gradually; introducing continuously an aromatic vinyl compound and an unsaturated nitrile compound which are the monomers to be grafted onto the elastomeric polymer, an emulsifier and a molecular weight modifier; heating the mixture to the final temperature of 75 to 85 deg.C and terminating the polymerization when the conversion is 95 to 98% and solid content is 40 to 44 wt% to obtain a SAN graft copolymer latex; and then introducing a solidifying agent consisting of an aqueous acid solution and aqueous salt solution to solidify the SAN graft copolymer resin.

Abstract translation: 目的：提供一种制备具有优异外观和白度以及高橡胶含量的核 - 壳结构的SAN（丙烯腈 - 丁二烯 - 苯乙烯）接枝共聚物的方法。 构成：用于制备SAN接枝共聚物的方法包括以下步骤：将溶解有水溶性引发剂的离子交换水和乳化剂引入平均粒径为0.28-0.33微米的聚丁二烯弹性体聚合物中， 75至85重量％; 加热混合物至55-65℃以使水溶性引发剂溶胀到弹性体聚合物中并逐渐分解形成自由基; 将作为待接枝单体的芳族乙烯基化合物和不饱和腈化合物连续引入弹性体聚合物，乳化剂和分子量调节剂; 加热至75〜85℃的最终温度，当转化率为95〜98％，固含量为40〜44wt％时，终止聚合，得到SAN接枝共聚物胶乳; 然后引入由酸水溶液和盐水溶液组成的固化剂以固化SAN接枝共聚物树脂。

公开(公告)号：KR100469865B1

公开(公告)日：2005-02-02

申请号：KR1020010086184

申请日：2001-12-27

Applicant: 제일모직주식회사

Inventor： 하두한 ,  박재범 ,  나희석

IPC: C08F279/04

Abstract: PURPOSE: A thermoplastic resin composition and its preparation method are provided, to improve the weather resistance and the impact resistance by employing a graft copolymer containing two different kinds of rubbery polymers. CONSTITUTION: The method comprises the steps of adding a graft monomer mixture of an aromatic vinyl monomer and an unsaturated nitrile monomer in the presence of an acryl-based rubber latex having a gel content of 85-96 wt% and an average particle diameter of 0.12-0.23 micrometers, adding an emulsifier, a polymerization initiator and an ion exchange water with stirring, heating the mixture with stirring to 50-65 deg.C, stirring the mixture for 10-30 min, and adding an oxidation-reduction catalyst at 60-80 deg.C to prepare a first graft latex until the conversion rate reaches 95 % or more; adding a butadiene-based rubbery polymer latex having a gel content of 60-80 wt% and an average particle diameter of 0.30-0.40 micrometers and a graft monomer mixture in the presence of the obtained first graft latex, increasing the temperature to 50-65 deg.C, adding a molecular weight controlling agent, stirring the mixture for 10-30 min, and adding a polymerization initiator at 60-80 deg.C to prepare a second graft latex until the conversion rate reaches 95 % or more; and continuously adding a graft monomer, a molecular weight controlling agent and a polymerization initiator for 2-4 hours at 65-80 deg.C to prepare a resin composition having the final polymerization conversion rate of 94-98 % and a solid content of 39-43 wt%.

Abstract translation: 目的：提供一种热塑性树脂组合物及其制备方法，通过采用含有两种不同橡胶状聚合物的接枝共聚物来改善耐候性和耐冲击性。 组成：该方法包括在凝胶含量为85-96wt％，平均粒径为0.12的丙烯酰基橡胶胶乳存在下加入芳族乙烯基单体和不饱和腈单体的接枝单体混合物 -0.23微米，搅拌下加入乳化剂，聚合引发剂和离子交换水，搅拌下加热至50-65℃，搅拌10-30分钟，在60℃下加入氧化还原催化剂 制备第一接枝胶乳直至转化率达到95％或更高; 在所得第一接枝胶乳存在下，添加凝胶含量为60-80重量％且平均粒径为0.30-0.40微米的丁二烯基橡胶状聚合物胶乳和接枝单体混合物，将温度升高至50-65℃ 加入分子量控制剂，搅拌10-30分钟，加入60-80℃的聚合引发剂，制备第二接枝胶乳，直至转化率达到95％以上; 在65-80℃下连续加入接枝单体，分子量控制剂和聚合引发剂2-4小时，以制备最终聚合转化率为94-98％且固体含量为39的树脂组合物 -43重量％。

公开(公告)号：KR1020040057046A

公开(公告)日：2004-07-02

申请号：KR1020020080630

申请日：2002-12-17

Applicant: 제일모직주식회사

Inventor： 박재범 ,  하두한

IPC: C08F253/00

CPC classification number: C08F236/10 ,  C08F2/24 ,  C08F2/38

Abstract: PURPOSE: A method for preparing a polystyrene-based impact modifier and a thermoplastic polystyrene resin containing the impact modifier prepared by the method are provided, to improve the impact strength of an impact modifier without deterioration of the fluidity and gloss of final products. CONSTITUTION: The method comprises the steps of injecting a styrene-based monomer and 30-60 parts by weight of a butadiene rubbery latex having an average diameter of 0.28-0.33 micrometers and a gel content of 75-85 % to a reactor, injecting a molecular weight controller, an emulsifier and an ion exchange water to the reactor, heating the reactor with stirring, and injecting an oil-soluble polymerization initiator to prepare a first graft copolymer latex by polymerizing them until a polymerization conversion rate reaches 93% or more; and injecting a redox-based initiator, a styrene-based monomer and a molecular weight controller to the reactor continuously over 2-5 hours in the presence of the first graft copolymer latex to prepare a second graft copolymer latex.

Abstract translation: 目的：提供一种制备聚苯乙烯类抗冲击改性剂和含有通过该方法制备的抗冲改性剂的热塑性聚苯乙烯树脂的方法，以改善抗冲改性剂的冲击强度，而不会降低最终产品的流动性和光泽。 方法：该方法包括以下步骤：向反应器注入苯乙烯基单体和30-60重量份平均直径为0.28-0.33微米，凝胶含量为75-85％的丁二烯橡胶胶乳，注入 分子量控制器，乳化剂和离子交换水加入到反应器中，在搅拌下加热反应器，注入油溶性聚合引发剂以通过聚合反应制备第一接枝共聚物胶乳直至聚合转化率达到93％以上; 在第一接枝共聚物胶乳存在下，在2-5小时内连续注入氧化还原型引发剂，苯乙烯类单体和分子量控制剂，制备第二接枝共聚物胶乳。

公开(公告)号：KR1020030056087A

公开(公告)日：2003-07-04

申请号：KR1020010086247

申请日：2001-12-27

Applicant: 제일모직주식회사

Inventor： 하두한 ,  박재범 ,  나희석

IPC: C08F279/04

CPC classification number: C08F279/04 ,  C08F2/38

Abstract: PURPOSE: A method for preparing an acrylonitrile-butadiene-styrene (ABS) graft copolymer is provided, to improve the impact resistance and the fluidity of an ABS resin by optimizing a rubber content, a particle size of rubber, a degree of grafting and an acrylonitrile content. CONSTITUTION: The method comprises the steps of injecting 50-70 parts by weight of a rubbery polymer latex having an average particle diameter of 0.28-0.35 micrometers and a gel content of 75-85 %, and 10-40 wt% of 50-30 parts by weight of a graft monomer mixture comprising styrene and acrylonitrile, injecting a molecular weight controlling agent, a reducing agent, an emulsifier and an ion exchange water with stirring and heating the reactor, and adding a catalyst mixture to the reactor to prepare a first graft copolymer latex until the polymerization conversion rate reaches 90-96 %; and adding the remaining graft monomer mixture and a molecular weight controlling agent to the obtained graft copolymer latex, and continuously adding a polymerization initiator for 2-5 hours to prepare a second graft copolymer latex. Preferably the reducing agent is dextrose.

Abstract translation: 目的：提供一种制备丙烯腈 - 丁二烯 - 苯乙烯（ABS）接枝共聚物的方法，通过优化橡胶含量，橡胶的粒度，接枝度和接枝共聚物的形式，提高ABS树脂的耐冲击性和流动性 丙烯腈含量。 方案：该方法包括以下步骤：注入50-70重量份平均粒径为0.28-0.35微米，凝胶含量为75-85％的橡胶状聚合物胶乳和50-40重量％的50-30重量％ 重量的包含苯乙烯和丙烯腈的接枝单体混合物，在搅拌和加热反应器的同时注入分子量控制剂，还原剂，乳化剂和离子交换水，并向反应器中加入催化剂混合物以制备第一 接枝共聚物胶乳直至聚合转化率达到90-96％; 并将剩余的接枝单体混合物和分子量控制剂加入到所获得的接枝共聚物胶乳中，并连续加入聚合引发剂2-5小时以制备第二接枝共聚物胶乳。 优选地，还原剂是葡萄糖。

公开(公告)号：KR1020080112840A

公开(公告)日：2008-12-26

申请号：KR1020070061787

申请日：2007-06-22

Applicant: 제일모직주식회사

Inventor： 문형랑 ,  김일진 ,  권기혜 ,  박재범 ,  공성호

IPC: C09K21/04 ,  B82B3/00 ,  B82Y40/00

Abstract: Nanoparticles having flame retardancy and a preparation method thereof are provided to ensure excellent fire retardancy while maintaining the stabilized property of resin. Nanoparticles having flame retardancy has a structure that a phosphorus compound is chemically bonded on the surface of nano particles by reacting (A) colloidal nano particles having -OH on the surface and (B) a phosphorus compound having at least one functional group capable of being chemically bonded with the -OH group. The average particle diameter of the colloidal nano particles(A) is 1~300 nm, the surface area is 1~1000 m^2 / g, the number of -OH of the particle surface is 101~107 per a particle and pH is 1~12.

Abstract translation: 提供具有阻燃性的纳米颗粒及其制备方法，以确保优异的阻燃性，同时保持树脂的稳定性。 具有阻燃性的纳米粒子具有磷化合物通过使（A）表面具有-OH的胶态纳米粒子与（B）具有至少一个官能团的磷化合物反应而在纳米粒子表面化学键合的结构 与-OH基团化学键合。 胶体纳米粒子（A）的平均粒径为1〜300nm，表面积为1〜1000m 2 / g，粒子表面的-OH数为101〜107，pH为 1〜12。

公开(公告)号：KR100567406B1

公开(公告)日：2006-04-04

申请号：KR1020020080630

申请日：2002-12-17

Applicant: 제일모직주식회사

Inventor： 박재범 ,  하두한

IPC: C08F253/00

Abstract: 본 발명의 폴리스티렌계 충격보강제의 제조방법은 평균입자직경이 0.28 내지 0.33㎛이고 겔 함량이 75 내지 85%인 부타디엔 고무질 라텍스 30 내지 60 중량부에 스티렌계 단량체를 반응기에 투입하고, 분자량조절제, 유화제 및 이온교환수를 투입, 교반하면서 반응기를 승온시킨 후, 지용성 중합개시제를 투입하여 중합전환율이 93% 이상에 이르도록 1차 그라프트 공중합체 라텍스를 제조하는 제1단계; 및 상기 1차 그라프트 공중합체 라텍스 존재 하에 레독스계 개시제, 스티렌계 단량체 및 분자량조절제를 2 내지 5 시간에 걸쳐 연속적으로 투입하여 2차 그라프트 공중합체 라텍스를 제조하는 제2단계로 이루어진다.
열가소성 폴리스티렌 수지(HIPS), , 내충격성, 유동성, 광택도, 스티렌, 부타디엔, 단량체, 공중합체