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公开(公告)号：KR100700685B1
公开(公告)日：2007-03-28
申请号：KR1020050135311
申请日：2005-12-30
Applicant: 제일모직주식회사
Abstract: Provided are an acrylonitrile-butadiene-styrene resin composition which is improved in impact strength and is remarkably enhanced in low gloss without deterioration of mechanical strength, and a plastic molded product prepared by using the composition. The acrylonitrile-butadiene-styrene resin composition comprises 10-50 parts by weight of a graft acrylonitrile-butadiene-styrene polymer; 50-90 parts by weight of heat resistant styrene-acrylonitrile; and 0.5-5 parts by weight of a crosslinked styrene-acrylonitrile. Preferably, the graft acrylonitrile-butadiene-styrene polymer is obtained by copolymerizing 40-60 parts by weight of a polybutadiene rubber latex, 20-40 parts by weight of an aromatic vinyl compound and 0.1-40 parts by weight of a vinyl cyano compound.
Abstract translation: 本发明提供一种改善了冲击强度的丙烯腈 - 丁二烯 - 苯乙烯树脂组合物，并且在不损害机械强度的情况下在低光泽下显着提高，并且使用该组合物制备的塑料模塑制品。 丙烯腈 - 丁二烯 - 苯乙烯树脂组合物包含10-50重量份的接枝丙烯腈 - 丁二烯 - 苯乙烯聚合物; 50-90重量份耐热苯乙烯 - 丙烯腈; 和0.5-5重量份的交联苯乙烯 - 丙烯腈。 优选地，接枝丙烯腈 - 丁二烯 - 苯乙烯聚合物通过共聚40-60重量份聚丁二烯橡胶胶乳，20-40重量份芳族乙烯基化合物和0.1-40重量份乙烯基氰基化合物而获得。
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公开(公告)号：KR100539065B1
公开(公告)日：2005-12-26
申请号：KR1020040100170
申请日：2004-12-02
Applicant: 제일모직주식회사
Abstract: 본 발명에 따른 낮은 선팽창계수를 가지는 열가소성 아크릴로니트릴-부타디엔-스티렌(ABS) 수지 조성물은 (A) (a1)고무변성 그라프트 공중합체 10∼100 중량부와 (a2) 시안화 비닐 화합물과 방향족 비닐 화합물의 공중합체 0∼90 중량부로 이루어진 고무질 그라프트 공중합체 100 중량부; (B) 무수 말레인산이 포함된 비닐계 공중합체 1∼30 중량부; 및 (C) 반응성기를 가진 화합물로 유기화된 점토(clay) 광물 1∼20 중량부;로 이루어지는 것을 특징으로 하고, 상기 반응성기를 가진 화합물은 한쪽은 점토(clay) 광물과 이온교환반응을 할 수 있는 오늄이온을, 다른 한쪽은 라디칼중합이 가능한 반응성기를 가지고 있는 화합물 중에서 하나 이상 선택된 것을 특징으로 한다.
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公开(公告)号：KR100433572B1
公开(公告)日：2004-06-02
申请号：KR1020010065331
申请日：2001-10-23
Applicant: 제일모직주식회사
IPC: C08L55/02
Abstract: PURPOSE: Provided is a thermoplastic resin composition which comprises g-ABS(acrylonitrile-butadiene-styrene) resin and SAN(styrene-acrylonitrile copolymer) resin, and ethylene bis-stearoamide, and has excellent appearance quality such as surface gloss, impact resistance, and fluidity. CONSTITUTION: The composition comprises (A) 15-40 parts by weight of g-ABS resin consisting of (a1) the first g-ABS resin produced by using small particle size of rubber polymer having average particle diameter of 0.05-0.20 micrometers through emulsion graft polymerization, and (a2) the second g-ABS resin produced by using small particle size of rubber polymer having average particle diameter of 0.25-0.40 micrometers through emulsion graft polymerization, with the ratio((a1)and (a2)) of 20:80 to 80:20 wt%; (B) 60-85 parts by weight of SAN resin consisting of (b1) 10-70 parts by weight of first SAN resin having acrylonitrile content of 20-35% and weight average molecular weight of 110,000-140,000, and (b2) 90-30 parts by weight of second SAN resin having acrylonitrile content of 20-35% and weight average molecular weight of 80,000-100,000; and (C) 1-6 parts by weight of ethylene bis-stearoamide with respect to 100 parts by weight of the sum of components(A) and (B).
Abstract translation: 本发明提供一种热塑性树脂组合物，其包含g-ABS（丙烯腈 - 丁二烯 - 苯乙烯）树脂和SAN（苯乙烯 - 丙烯腈共聚物）树脂以及亚乙基双硬脂酰胺，并且具有优异的外观品质如表面光泽，耐冲击性， 和流动性。 构成：该组合物包含（A）15-40重量份g-ABS树脂，其由（a1）通过使用小粒度的平均粒径为0.05-0.20微米的橡胶聚合物制得的第一种g- 接枝聚合，和（a2）通过乳液接枝聚合使用小粒度的平均粒径为0.25-0.40微米的橡胶聚合物制备的第二g-ABS树脂，其中（（a1）和（a2））为20 ：80至80:20重量％; （B）60-85重量份SAN树脂，其由（b1）10-70重量份丙烯腈含量为20-35％且重均分子量为110,000-140,000的第一SAN树脂和（b2）90 -30重量份丙烯腈含量为20-35％且重均分子量为80,000-100,000的第二SAN树脂; 和（C）相对于100重量份的组分（A）和（B）的总和为1〜6重量份的亚乙基双硬脂酰胺。
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公开(公告)号：KR1020030095538A
公开(公告)日：2003-12-24
申请号：KR1020020032785
申请日：2002-06-12
Applicant: 제일모직주식회사
CPC classification number: C08L55/02 , C08J2300/22 , C08L25/12 , C08L2201/08 , C08L2205/025
Abstract: PURPOSE: Provided is a thermoplastic resin composition, which has excellent impact resistance as well as improved chemical resistance against acetic acid suitable to be used in an electronic or automobile component and a construction material. CONSTITUTION: The thermoplastic resin composition comprises (A) 20-40 parts by weight of a g-ABS resin obtained by emulsion graft polymerization of a rubbery polymer having an average particle diameter of 0.25-0.40 micrometers; and (B) 60-80 parts by weight of a SAN copolymer resin consisting of (b1) 50-100 wt% of a SAN resin having an acrylonitrile content of 22-26% and a weight average molecular weight of 130,000-170,000 and (b2) 0-50 wt% of a SAN resin having an acrylonitrile content of 24-29% and a weight average molecular weight of 80,000-110,000.
Abstract translation: 目的：提供一种热塑性树脂组合物，其具有优异的耐冲击性以及改善适用于电子或汽车部件和建筑材料中的乙酸的耐化学性。 构成：热塑性树脂组合物包含（A）20-40重量份通过乳液接枝聚合得到的具有平均粒径为0.25-0.40微米的橡胶状聚合物的g-ABS树脂; 和（B）60-80重量份由（b1）50-100重量％的丙烯腈含量为22-26重量％和重均分子量为130,000-170,000的SAN树脂组成的SAN共聚物树脂和（ b2）0-50重量％的丙烯腈含量为24-29％，重均分子量为80,000-1100,000的SAN树脂。
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Patent Agency Ranking
公开(公告)号：KR101466148B1
公开(公告)日：2014-11-27
申请号：KR1020100091071
申请日：2010-09-16
Applicant: 제일모직주식회사
Abstract: (A) 아크릴계 화합물을 포함하는 고무 코어를 포함하는 코어-쉘 구조의 아크릴계 공중합체; 및 (B) 실리콘계 화합물 및 아크릴산 알킬 에스테르 화합물을 포함하는 고무 코어를 포함하고, 메타크릴산 알킬 에스테르 화합물, 방향족 비닐 화합물 및 불포화 니트릴 화합물을 포함하는 쉘이 그라프트되어 형성된 코어-쉘 구조의 충격보강제를 포함하는 아크릴계 열가소성 수지 조성물이 제공된다.
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公开(公告)号：KR1020120072972A
公开(公告)日：2012-07-04
申请号：KR1020100134928
申请日：2010-12-24
Applicant: 제일모직주식회사
CPC classification number: C08L33/08 , C08L33/18 , C08L35/06 , C08L51/003 , C08L51/04 , C08L2205/03 , C08L35/08
Abstract: PURPOSE: An acrylic resin composition is provided to enhance weatherability, scratch resistance, surface gloss property, and heat resistance, thereby applying to various molded products including plastic external products. CONSTITUTION: An acrylic resin composition comprises a first core-shell structure acrylic copolymers which includes dual layer rubber, a second core-shell structure acrylic copolymer which includes monolayer rubber, a heat-resistant copolymer of vinyl cyanide compound and aromatic vinyl compound which includes α-methyl styrene, phenyl N-substituted maleimide, or a combination thereof, and polyalkyl(meth)acrylate which has average molecular weight of 20,000-30,000 g/mol. The dual layer rubber has average particle diameter of 0.1-0.5 micron.
Abstract translation: 目的：提供丙烯酸树脂组合物以提高耐候性，耐刮擦性，表面光泽性和耐热性，从而适用于包括塑料外部产品在内的各种成型产品。 构成：丙烯酸树脂组合物包括第一核 - 壳结构丙烯酸共聚物，其包括双层橡胶，包括单层橡胶的第二核 - 壳结构丙烯酸共聚物，乙烯基氰化合物和芳族乙烯基化合物的耐热共聚物，其包括α 甲基苯乙烯，苯基N-取代的马来酰亚胺或其组合，以及平均分子量为20,000-30,000g / mol的（甲基）丙烯酸烷基酯。 双层橡胶的平均粒径为0.1-0.5微米。
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公开(公告)号：KR1020120055318A
公开(公告)日：2012-05-31
申请号：KR1020100116995
申请日：2010-11-23
Applicant: 제일모직주식회사
Abstract: PURPOSE: A thermoplastic resin composition is provided to have excellent thermal stability and weather resistance, thereby utilizing for molded product like electric and electronic components using outdoor, vehicle components, construction components, sports equipment, etc. CONSTITUTION: A thermoplastic resin composition comprises 100 parts by weight of acrylic resin containing acrylic graft copolymer containing acrylic rubber, 0.1-0.7 parts by weight of phosphorous antioxidant, and 0.1-1.0 parts by weight of a hindered amine-based photostabilizer. The phosphorous antioxidant comprises triphenyl phosphite, triisodecyl phosphite, diphenyl-iso-octyl-phosphite, tris(2,4-t-butylphenyl)phosphite, tris(nonylphenyl)phosphite, distearyl-pentaerythritol-diphosphate or their combinations thereof. The hindered amine-based photostabilizer comprises bis(2,2,6,6-teramethyl-4piperidyl)sebacate, tetrakis (2,2,6,6-tetramethyl-4-piperidyl)-1,2,3,4-butane tetra carboxylate, 2,4-dichloro-6-(1,1,3,3-tetramethylbutyl amino)-1,3,5-triazine, and a poly condensated material of N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine, or combinations thereof.
Abstract translation: 目的：提供热塑性树脂组合物以具有优异的热稳定性和耐候性，从而利用户外，车辆部件，建筑部件，运动器材等的电气和电子部件等模制产品。构成：热塑性树脂组合物包含100份 的丙烯酸树脂，含有丙烯酸橡胶的丙烯酸接枝共聚物，0.1-0.7重量份的磷抗氧化剂和0.1-1.0重量份的受阻胺类光稳定剂。 磷抗氧化剂包括亚磷酸三苯酯，亚磷酸三异癸酯，亚磷酸二苯基 - 异辛酯，亚磷酸三（2,4-叔丁基苯基）酯，亚磷酸三（壬基苯基）酯，二硬脂基 - 季戊四醇二磷酸酯或它们的组合。 受阻胺类光稳定剂包括双（2,2,6,6-四甲基-4-哌啶基）癸二酸酯，四（2,2,6,6-四甲基-4-哌啶基）-1,2,3,4-丁烷四 羧酸盐，2,4-二氯-6-（1,1,3,3-四甲基丁基氨基）-1,3,5-三嗪，以及N，N'-双（2,2,6， 六甲基-4-哌啶基）六亚甲基二胺或其组合。
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公开(公告)号：KR100831083B1
公开(公告)日：2008-05-20
申请号：KR1020050130789
申请日：2005-12-27
Applicant: 제일모직주식회사
Abstract: 본 발명은 (A) 폴리에스테르 수지 30∼70 중량부; (B) 폴리카보네이트 수지 30∼60 중량부; (C) 스티렌계 공중합체 10∼40 중량부; 및 (D) 상기 (A)＋(B)＋(C)의 기초수지 100 중량부에 대하여 아크릴변성 폴리테트라플루오르에틸렌 0.5∼2 중량부로 이루어지며, 기계적 강도와 내충격성이 뛰어나고 용융장력이 우수하여 대형 블로우 성형품의 적용이 가능한 폴리에스테르계 열가소성 수지 조성물에 관한 것이다.
폴리에스테르 수지, 폴리카보네이트 수지, 스티렌계 공중합체, 아크릴변성 폴리테트라플루오르에틸렌, 고용융장력-
公开(公告)号：KR100781963B1
公开(公告)日：2007-12-06
申请号：KR1020060138390
申请日：2006-12-29
Applicant: 제일모직주식회사
Abstract: A thermoplastic resin composition, a pellet extruded from the composition, and a construction material or an interior and exterior material for automobiles prepared from the composition are provided to improve extensional viscosity, foaming extrusion characteristics, heat resistance and impact strength. A thermoplastic resin composition comprises 100 parts by weight of a resin composition which comprises 20-40 parts by weight of a rubber graft copolymer, 50-70 parts by weight of a copolymer of an aromatic vinyl cyano compound and a cyanovinyl compound containing alpha-methylstyrene having a weight average molecular weight of 100,000-200,000, and 1-10 parts by weight of a copolymer of maleic anhydride, N-substituted maleimide, a cyanovinyl compound and an aromatic vinyl compound; and 1-5 parts by weight of a copolymer of a cyanovinyl compound and an aromatic vinyl cyano compound having a weight average molecular weight of 3,000,000-6,000,000.
Abstract translation: 提供热塑性树脂组合物，从组合物挤出的颗粒，以及由组合物制备的用于汽车的建筑材料或内部和外部材料，以改善拉伸粘度，发泡挤出特性，耐热性和冲击强度。 热塑性树脂组合物包含100重量份的树脂组合物，其包含20-40重量份的橡胶接枝共聚物，50-70重量份的芳族乙烯基氰基化合物和含有α-甲基苯乙烯的氰基乙烯基化合物的共聚物 重均分子量为100,000-200,000，1-10重量份马来酸酐，N-取代马来酰亚胺，氰乙烯基化合物和芳族乙烯基化合物的共聚物; 和1-5重量份的重均分子量为3,000,000-6,000,000的氰基乙烯基化合物和芳族乙烯基氰基化合物的共聚物。
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