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公开(公告)号：KR1020130057795A
公开(公告)日：2013-06-03
申请号：KR1020110123722
申请日：2011-11-24
Applicant: 제일모직주식회사
Abstract: 본발명의일 구현예에서아크릴계고무상중합체에방향족비닐계단량체, 상기방향족비닐계단량체와공중합할수 있는단량체또는이들의조합이그라프트중합된공중합체인그라프트아크릴계공중합체(A); 방향족비닐-시안화비닐계공중합체(B); 및폴리알킬(메타)아크릴레이트수지(C)를포함하는열가소성수지를제공한다. 상기방향족비닐-시안화비닐계공중합체(B)는시안화비닐화합물을포함하고, 상기시안화비닐화합물은상기방향족비닐-시안화비닐계공중합체(B) 총량에대해 5 내지 25 중량%로포함될수 있다.
Abstract translation: 目的：提供热塑性树脂组合物以具有优异的耐候性和耐擦伤性，并获得高透明度。 构成：热塑性树脂组合物包含接枝丙烯酸共聚物，芳族乙烯基 - 氰化物乙烯基共聚物和（甲基）丙烯酸烷基酯树脂。 芳族乙烯基氰化物乙烯基共聚物包含5-25重量％的衍生自氰化乙烯基化合物的单元。 热塑性树脂组合物包含100.0重量份的接枝丙烯酸共聚物和50-200重量份的芳族乙烯基 - 氰化物乙烯基共聚物。
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公开(公告)号：KR1020120072972A
公开(公告)日：2012-07-04
申请号：KR1020100134928
申请日：2010-12-24
Applicant: 제일모직주식회사
CPC classification number: C08L33/08 , C08L33/18 , C08L35/06 , C08L51/003 , C08L51/04 , C08L2205/03 , C08L35/08
Abstract: PURPOSE: An acrylic resin composition is provided to enhance weatherability, scratch resistance, surface gloss property, and heat resistance, thereby applying to various molded products including plastic external products. CONSTITUTION: An acrylic resin composition comprises a first core-shell structure acrylic copolymers which includes dual layer rubber, a second core-shell structure acrylic copolymer which includes monolayer rubber, a heat-resistant copolymer of vinyl cyanide compound and aromatic vinyl compound which includes α-methyl styrene, phenyl N-substituted maleimide, or a combination thereof, and polyalkyl(meth)acrylate which has average molecular weight of 20,000-30,000 g/mol. The dual layer rubber has average particle diameter of 0.1-0.5 micron.
Abstract translation: 目的：提供丙烯酸树脂组合物以提高耐候性，耐刮擦性，表面光泽性和耐热性，从而适用于包括塑料外部产品在内的各种成型产品。 构成：丙烯酸树脂组合物包括第一核 - 壳结构丙烯酸共聚物，其包括双层橡胶，包括单层橡胶的第二核 - 壳结构丙烯酸共聚物，乙烯基氰化合物和芳族乙烯基化合物的耐热共聚物，其包括α 甲基苯乙烯，苯基N-取代的马来酰亚胺或其组合，以及平均分子量为20,000-30,000g / mol的（甲基）丙烯酸烷基酯。 双层橡胶的平均粒径为0.1-0.5微米。
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公开(公告)号：KR1020120055318A
公开(公告)日：2012-05-31
申请号：KR1020100116995
申请日：2010-11-23
Applicant: 제일모직주식회사
Abstract: PURPOSE: A thermoplastic resin composition is provided to have excellent thermal stability and weather resistance, thereby utilizing for molded product like electric and electronic components using outdoor, vehicle components, construction components, sports equipment, etc. CONSTITUTION: A thermoplastic resin composition comprises 100 parts by weight of acrylic resin containing acrylic graft copolymer containing acrylic rubber, 0.1-0.7 parts by weight of phosphorous antioxidant, and 0.1-1.0 parts by weight of a hindered amine-based photostabilizer. The phosphorous antioxidant comprises triphenyl phosphite, triisodecyl phosphite, diphenyl-iso-octyl-phosphite, tris(2,4-t-butylphenyl)phosphite, tris(nonylphenyl)phosphite, distearyl-pentaerythritol-diphosphate or their combinations thereof. The hindered amine-based photostabilizer comprises bis(2,2,6,6-teramethyl-4piperidyl)sebacate, tetrakis (2,2,6,6-tetramethyl-4-piperidyl)-1,2,3,4-butane tetra carboxylate, 2,4-dichloro-6-(1,1,3,3-tetramethylbutyl amino)-1,3,5-triazine, and a poly condensated material of N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)hexamethylenediamine, or combinations thereof.
Abstract translation: 目的：提供热塑性树脂组合物以具有优异的热稳定性和耐候性，从而利用户外，车辆部件，建筑部件，运动器材等的电气和电子部件等模制产品。构成：热塑性树脂组合物包含100份 的丙烯酸树脂，含有丙烯酸橡胶的丙烯酸接枝共聚物，0.1-0.7重量份的磷抗氧化剂和0.1-1.0重量份的受阻胺类光稳定剂。 磷抗氧化剂包括亚磷酸三苯酯，亚磷酸三异癸酯，亚磷酸二苯基 - 异辛酯，亚磷酸三（2,4-叔丁基苯基）酯，亚磷酸三（壬基苯基）酯，二硬脂基 - 季戊四醇二磷酸酯或它们的组合。 受阻胺类光稳定剂包括双（2,2,6,6-四甲基-4-哌啶基）癸二酸酯，四（2,2,6,6-四甲基-4-哌啶基）-1,2,3,4-丁烷四 羧酸盐，2,4-二氯-6-（1,1,3,3-四甲基丁基氨基）-1,3,5-三嗪，以及N，N'-双（2,2,6， 六甲基-4-哌啶基）六亚甲基二胺或其组合。
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公开(公告)号：KR101466151B1
公开(公告)日：2014-11-27
申请号：KR1020100140558
申请日：2010-12-31
Applicant: 제일모직주식회사
CPC classification number: C08F285/00 , C08K5/005 , C08L25/12 , C08L2205/02 , C08L51/04 , C08F212/08 , C08F220/44
Abstract: (A) 평균입경이 0.1 내지 0.30 ㎛인 고무를 포함하는 코어-쉘 구조의 제1 아크릴계 공중합체, (B) 평균입경이 0.35 내지 0.6 ㎛인 고무를 포함하는 코어-쉘 구조의 제2 아크릴계 공중합체, (C) 비닐계 공중합체, (D) UV 안정제 및 (E) UV 흡수제를 포함하는 아크릴계 수지 조성물, 및 이를 이용한 성형품이 제공된다.
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Patent Agency Ranking
公开(公告)号：KR1020120078299A
公开(公告)日：2012-07-10
申请号：KR1020100140558
申请日：2010-12-31
Applicant: 제일모직주식회사
CPC classification number: C08F285/00 , C08K5/005 , C08L25/12 , C08L2205/02 , C08L51/04 , C08F212/08 , C08F220/44
Abstract: PURPOSE: An acrylic resin composition is provided to have excellent colorability, impact resistnace, weatherability, and high gloss, thereby capable of being used for various molded products, especially for plastic exterior products like electric and electronic components, vehicle components, etc. CONSTITUTION: An acrylic resin composition comprises a first acrylic copolymer of core-shell structure comprising rubber of which average particle diameter is 0.1-0.30, a second acrylic copolymer of core-shell structure comprising rubber of which average particle diameter is 0.35-0.6 micron, a vinyl copolymer, a UV stabilizer, and a UV absorber. The rubber comprised in the first acrylic copolymer has bilayered structure comprising an inner layer comprising an acrylic compound, and a copolymer of an aromatic vinyl compound, and an outer layer comprising an acrylic compound.
Abstract translation: 目的：提供丙烯酸树脂组合物以具有优异的着色性，抗冲击性，耐候性和高光泽度，从而能够用于各种模制产品，特别是用于诸如电气和电子部件，车辆部件等的塑料外部产品。构成： 丙烯酸树脂组合物包含由包含平均粒径为0.1-0.30的橡胶的核 - 壳结构的第一丙烯酸共聚物，包含平均粒径为0.35-0.6微米的橡胶的核 - 壳结构的第二丙烯酸共聚物，乙烯基 共聚物，UV稳定剂和UV吸收剂。 包含在第一丙烯酸共聚物中的橡胶具有双层结构，其包含包含丙烯酸化合物的内层和芳族乙烯基化合物的共聚物和包含丙烯酸类化合物的外层。
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公开(公告)号：KR1020140064472A
公开(公告)日：2014-05-28
申请号：KR1020120131863
申请日：2012-11-20
Applicant: 제일모직주식회사
Abstract: The present invention relates to a resin composition and a molded article manufacture by the same. The resin composition includes an acrylic graft copolymer, a styrene-based copolymer, and an inorganic additive. The inorganic additive is metal oxide, metal hydroxide or combination thereof and has an average particle size of 0.1 to 50 μm. The resin composition contains 0.01-5 parts by weight of the inorganic additive in respect with 100 parts by weight of the acrylic graft copolymer and the styrene-based copolymer.
Abstract translation: 本发明涉及一种树脂组合物及其制造方法。 树脂组合物包括丙烯酸接枝共聚物，苯乙烯基共聚物和无机添加剂。 无机添加剂是金属氧化物，金属氢氧化物或其组合，其平均粒径为0.1〜50μm。 相对于100重量份的丙烯酸接枝共聚物和苯乙烯系共聚物，树脂组合物含有0.01-5重量份的无机添加剂。
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公开(公告)号：KR101531613B1
公开(公告)日：2015-06-25
申请号：KR1020110123722
申请日：2011-11-24
Applicant: 제일모직주식회사
Abstract: 본발명의일 구현예에서아크릴계고무상중합체에방향족비닐계단량체, 상기방향족비닐계단량체와공중합할수 있는단량체또는이들의조합이그라프트중합된공중합체인그라프트아크릴계공중합체(A); 방향족비닐-시안화비닐계공중합체(B); 및폴리알킬(메타)아크릴레이트수지(C)를포함하는열가소성수지를제공한다. 상기방향족비닐-시안화비닐계공중합체(B)는시안화비닐화합물을포함하고, 상기시안화비닐화합물은상기방향족비닐-시안화비닐계공중합체(B) 총량에대해 5 내지 25 중량%로포함될수 있다.
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公开(公告)号：KR1020140068672A
公开(公告)日：2014-06-09
申请号：KR1020120136457
申请日：2012-11-28
Applicant: 제일모직주식회사
Abstract: Provided is a composition comprising: (A) a graft copolymer consisting of (A-1) an acrylic graft copolymer which is obtained by grafting an aromatic vinyl monomer and a cyanized vinyl monomer to an acrylic rubber polymer and (A-2) a diene-based graft copolymer which is obtained by grafting an aromatic vinyl monomer and a cyanized vinyl monomer to a diene-based rubber polymer; (B) a styrene-based copolymer; (C) a light stabilizer; and (D) an ultraviolet ray absorbent.
Abstract translation: 提供了一种组合物，其包含：（A）由（A-1）丙烯酸接枝共聚物组成的接枝共聚物，其通过将芳族乙烯基单体和氰化乙烯基单体接枝到丙烯酸类橡胶聚合物上获得，和（A-2）二烯 基的接枝共聚物，其通过将芳族乙烯基单体和氰化乙烯基单体接枝到二烯系橡胶聚合物上而获得; （B）苯乙烯类共聚物; （C）光稳定剂; 和（D）紫外线吸收剂。
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公开(公告)号：KR101466152B1
公开(公告)日：2014-11-27
申请号：KR1020100134928
申请日：2010-12-24
Applicant: 제일모직주식회사
CPC classification number: C08L33/08 , C08L33/18 , C08L35/06 , C08L51/003 , C08L51/04 , C08L2205/03 , C08L35/08
Abstract: (A) 이중층 고무를 포함하는 코어-쉘 구조의 제1 아크릴계 공중합체, (B) 단일층 고무를 포함하는 코어-쉘 구조의 제2 아크릴계 공중합체, (C) α-메틸 스티렌, 페닐 N-치환 말레이미드, 또는 이들의 조합을 포함하는 방향족 비닐 화합물과 시안화 비닐 화합물의 내열 공중합체, 그리고 (D) 20,000 내지 30,000 g/mol의 중량평균 분자량을 가진 폴리알킬(메타)아크릴레이트를 포함하는 아크릴계 수지 조성물, 및 이를 이용한 성형품이 제공된다.
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