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公开(公告)号：KR101413070B1
公开(公告)日：2014-07-18
申请号：KR1020100118331
申请日：2010-11-25
Applicant: 제일모직주식회사
Abstract: (A) 유기 바인더 수지, (B) 반응성 불포화 화합물, (C) 광중합 개시제, (D) 카본 블랙 및 은-주석 함유 합금을 포함하는 흑색 안료, 그리고 (E) 용매를 포함하는 흑색 감광성 수지 조성물 및 이를 이용한 차광층이 제공된다.
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公开(公告)号：KR1020110079199A
公开(公告)日：2011-07-07
申请号：KR1020090136184
申请日：2009-12-31
Applicant: 제일모직주식회사
CPC classification number: G03F7/027 , G02B5/223 , G02F1/133512 , G03F7/0007 , G03F7/028 , G03F7/033 , G03F7/0388 , G03F7/105
Abstract: PURPOSE: A black photo-sensitive resin composition is provided to form a light shielding layer with the superior mechanical characteristic, the high optical density, the low dielectric constant, and the superior chemical resistance characteristic. CONSTITUTION: A black photo-sensitive resin composition includes a compound, a binder resin, a reactive unsaturated compound, a photo-polymerizable initiator, a pigment, and a solvent. The compound is represented by chemical formula 1. In the chemical formula 1, the A is alicyclic group or aryl group. The R1 and the R2 are selected from a group including hydrogen, hydroxyl group, substituted or non-substituted alkyl group, substituted or non-substituted alkenyl group, substituted or non-substituted alkynyl group, substituted or non-substituted alkoxy group, and substituted or non-substituted aryl group. The X is hydroxyl group or alkoxy group. The m is the integer of 0 to 6. The n is the integer of 1 to 3.
Abstract translation: 目的：提供黑色光敏树脂组合物以形成具有优异的机械特性，高光密度，低介电常数和优异的耐化学性特性的遮光层。 构成：黑色光敏树脂组合物包括化合物，粘合剂树脂，反应性不饱和化合物，光聚合引发剂，颜料和溶剂。 该化合物由化学式1表示。在化学式1中，A是脂环基或芳基。 取代或未取代的烯基，取代或未取代的炔基，取代或未取代的烷氧基，取代或未取代的烷氧基，取代或未取代的烷基，取代或未取代的烷基， 或未取代的芳基。 X是羟基或烷氧基。 m为0〜6的整数.n为1〜3的整数。
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公开(公告)号：KR1020100066197A
公开(公告)日：2010-06-17
申请号：KR1020080124880
申请日：2008-12-09
Applicant: 제일모직주식회사
CPC classification number: G03F7/027 , G02B5/223 , G02B5/23 , G02F1/133512 , G03F7/0007 , G03F7/031 , G03F7/032 , G03F7/033 , G03F7/0388 , G03F7/105
Abstract: PURPOSE: A black photosensitive resin composition and black matrix and a column spacer which are manufactured using the same are provided to have a low dielectric constant while having excellent optical density when a thin film is formed and to display high compressive displacement and a high recovery rate. CONSTITUTION: A black photosensitive resin comprises: cardo-based binder resin 0.5 ~ 20 weight%; reactive unsaturated compound 1 ~ 20 weight%; photopolymerization initiator 0.1 ~ 10 weight%; pigment 0.5 ~ 20 weight%; and a solvent. The pigment includes an organic pigment and an inorganic compound with a mixing ratio of 1 ~ 10 : 1. The cardo-based binder resin is a polymer having a repeating unit which is marked as a chemical formula 1. The average molecular weight of the cardo-based binder resin is 1,000 ~ 20,000 g/mol.
Abstract translation: 目的：使用它们制造的黑色感光性树脂组合物和黑色矩阵和柱状隔离物具有低介电常数，同时在形成薄膜时具有优异的光密度，并且显示高压缩位移和高回收率 。 构成：黑色感光树脂包括：0.5〜20重量％的基于卡诺的粘合剂树脂; 反应性不饱和化合物1〜20重量％; 光聚合引发剂0.1〜10重量％ 颜料0.5〜20重量％ 和溶剂。 该颜料包括有机颜料和混合比为1〜10:1的无机化合物。基于硬质的粘合剂树脂是具有标记为化学式1的重复单元的聚合物。该卡的平均分子量 基粘合剂树脂为1,000〜20,000g / mol。
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4.发明授权
公开(公告)号：KR100838452B1
公开(公告)日：2008-06-16
申请号：KR1020070028097
申请日：2007-03-22
Applicant: 제일모직주식회사
Abstract: A cardo-based resin, a photosensitive resin composition containing the resin as a binder, and a black matrix prepared by using the composition are provided to improve the storage stability of the composition and to enhance heat resistance, chemical resistance, development and adhesion. A cardo-based resin is represented by the formula 1, wherein R1 and R2 are independently H, a halogen atom or a C1-C5 alkyl group; R3 is a vinyl group, an acryl group or a methacryl group; Z is a residue of an acid anhydride or an acid dianhydride; X is -CO-, -SO2-,l -C(CF3)2-, -Si(CH3)2-, -CH2-, -C(CH3)2-, -O-, or the group represented by the formula (a); and k is 1-20.
Abstract translation: 提供一种cardo基树脂，含有作为粘合剂的树脂的感光性树脂组合物和使用该组合物制备的黑色基体，以提高组合物的储存稳定性并提高耐热性，耐化学性，显影性和粘合性。 基于树脂的树脂由式1表示，其中R 1和R 2独立地为H，卤素原子或C 1 -C 5烷基; R3是乙烯基，丙烯酰基或甲基丙烯酰基; Z是酸酐或酸二酐的残基; X是-CO-，-SO 2 - ， - C（CF 3）2 - ，-Si（CH 3）2 - ， - CH 2 - ， - C（CH 3）2 - （一个）; k为1-20。
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公开(公告)号：KR101432604B1
公开(公告)日：2014-08-22
申请号：KR1020110119615
申请日：2011-11-16
Applicant: 제일모직주식회사
Abstract: (A) 서로 다른 흡광도를 갖는 제1 옥심계 화합물 및 제2 옥심계 화합물을 1:4 내지 4:1의 중량비로 포함하는 광중합 개시제, (B) 유기 바인더 수지, (C) 흑색 안료, (D) 반응성 불포화 화합물 및 (E) 용매를 포함하는 흑색 감광성 수지 조성물, 그리고 이를 이용하여 제조된 차광층이 제공된다.
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Patent Agency Ranking
公开(公告)号：KR1020110062157A
公开(公告)日：2011-06-10
申请号：KR1020090118749
申请日：2009-12-02
Applicant: 제일모직주식회사
CPC classification number: G03F7/0045 , G03F7/004 , G03F7/0047 , G03F7/11
Abstract: PURPOSE: A photosensitive resin composition is provided to form a film with high insulating property and after image and to use as a light blocking layer for enhancing contrast or chromogenic effect of a color filter. CONSTITUTION: A photosensitive resin composition comprises (A) 0.5-20 weight% of cardo-based binder resin, (B) 0.5-20 weight% of reactive unsaturated compound, (C) 0.05-10 weight% of photopolymerization initiator, (D) 1-20 weight% of pigment, and (E) a remaining amount of a solvent. The metal content is 1,500 ppm or less. The pigment comprises phthalocyanine-based pigment. The metal is copper(Cu), zinc(Zn), molybdenum(Mo) or combination thereof.
Abstract translation: 目的：提供一种感光性树脂组合物以形成具有高绝缘性和图像后的膜，并且用作用于增强滤色器的对比度或显色效果的遮光层。 构成：感光性树脂组合物含有（A）0.5-20重量％的基于硬质的粘合剂树脂，（B）0.5-20重量％的反应性不饱和化合物，（C）0.05-10重量％的光聚合引发剂，（D） 1-20重量％的颜料，和（E）剩余量的溶剂。 金属含量为1500ppm以下。 颜料包括酞菁基颜料。 金属是铜（Cu），锌（Zn），钼（Mo）或其组合。
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公开(公告)号：KR1020090056735A
公开(公告)日：2009-06-03
申请号：KR1020070124022
申请日：2007-11-30
Applicant: 제일모직주식회사
IPC: G03F7/028
CPC classification number: G03F7/028 , G02B5/223 , G03F7/0007 , G03F7/027 , G03F7/032 , G03F7/0388 , G03F7/105
Abstract: A black photosensitive resin composition and an optical shield layer manufactured by using the composition are provided to ensure excellent insulation, high optical density, good heat resistance and chemical resistance. A black photosensitive resin composition comprises a cardo-based binder resin 0.5 ~ 20 weight%; a reactive unsaturated compound 1 ~ 20 weight%; a photopolymerization initiator 0.1 ~ 10 weight%; blacked organic pigment 5 ~ 40 weight%; and the balance of solvent. The cardo-based binder resin is copolymerized with chemical formulae 1-3. In chemical formula 2, R1 shows a hydrogen atom, C1-10 alkylene group, aryl group, phenylene group, benzyl group or C1-8 alkoxy group; and X shows a halogen atom.
Abstract translation: 提供黑色感光性树脂组合物和通过使用该组合物制造的光学屏蔽层，以确保优异的绝缘性，高密度，良好的耐热性和耐化学性。 黑色感光性树脂组合物含有0.5〜20重量％的卡诺基粘合剂树脂; 反应性不饱和化合物1〜20重量％; 光聚合引发剂0.1〜10重量％ 黑色有机颜料5〜40重量％; 和溶剂的平衡。 将基于Cardo的粘合剂树脂与化学式1-3共聚。 在化学式2中，R 1表示氢原子，C 1-10亚烷基，芳基，亚苯基，苄基或C 1-8烷氧基; X表示卤素原子。
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公开(公告)号：KR1020120044870A
公开(公告)日：2012-05-08
申请号：KR1020100118331
申请日：2010-11-25
Applicant: 제일모직주식회사
CPC classification number: G03F7/027 , C08L33/04 , C09B11/24 , G02B5/223 , G03F7/0007 , G03F7/028 , G03F7/032 , G03F7/033 , G03F7/0388 , G03F7/105
Abstract: PURPOSE: Black photo-sensitive resin compositions and a light shielding layer using the same are provided to reduce dielectric constant and to improve optical density without the damage of workability. CONSTITUTION: Black photo-sensitive resin compositions include 0.5 to 20 weight% of organic binder resins, 1 to 20 weight% of reactive unsaturated compounds, 0.1 to 10 weight% of photopolymerizable initiators, 1 to 40 weight% of black pigments with carbon black and silver-tin containing alloy, and remaining amount of solvents. The ratio of the carbon black and the silver-tin containing alloy is 1:9 to 9:1 by weight ratio. The organic binder resins include cardo-based binder resins. The carbon binder resins are compounds with repeating units represented by chemical formula 1. In chemical formula 1, R 24 to R27 are identical or different and are hydrogen elements, halogen elements, or substituted or non-substituted C1 to C20 alkyl groups; R28 and R29 are identical or different and are hydrogen elements or CH_2ORa; Ra is a vinyl group, an acryl group, or a methacryl group; R30 is identical or different and is a hydrogen element, a substituted or non-substituted C1 to C20 alkyl group, a substituted or non-substituted C2 to C20 alkenyl group, acryl group, or methacryl group; Z1 is identical or different and is one of a single bond, O, CO, SO_2, CRbRc, SiRdRe, or compounds represented by chemical formulas 2 to 12; Rb to Re are identical or different and are hydrogen elements or substituted or non-substituted C1 to C20 alkyl groups; and Z2 is identical or different and is an acid anhydride residue or an acid dianhydride group.
Abstract translation: 目的：提供黑色光敏树脂组合物和使用其的遮光层以降低介电常数并提高光密度而不损害可加工性。 构成：黑色感光树脂组合物包含0.5-20重量％的有机粘合剂树脂，1-20重量％的反应性不饱和化合物，0.1-10重量％的可光聚合的引发剂，1-40重量％的具有炭黑的黑色颜料和 含银锡合金和剩余量的溶剂。 炭黑和含银锡合金的比例为1:9〜9:1（重量比）。 有机粘合剂树脂包括cardo基粘合剂树脂。 碳粘合剂树脂是具有由化学式1表示的重复单元的化合物。在化学式1中，R 24至R 27相同或不同，为氢元素，卤素元素或取代或未取代的C1至C20烷基; R 28和R 29相同或不同，为氢元素或CH 2 OR a; Ra是乙烯基，丙烯酰基或甲基丙烯酰基; R30相同或不同，为氢元素，取代或未取代的C1至C20烷基，取代或未取代的C2至C20烯基，丙烯酰基或甲基丙烯酰基; Z1是相同或不同的，是单键O，CO，SO_2，CRbRc，SiRdRe或化学式2至12表示的化合物之一; Rb至Re相同或不同，为氢元素或取代或未取代的C1至C20烷基; Z2相同或不同，为酸酐残基或酸二酐基。
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公开(公告)号：KR1020110027079A
公开(公告)日：2011-03-16
申请号：KR1020090085009
申请日：2009-09-09
Applicant: 제일모직주식회사
CPC classification number: G03F7/027 , C08L33/04 , C09B11/24 , G02B5/223 , G02F1/133512 , G03F7/0007 , G03F7/028 , G03F7/032 , G03F7/0388 , G03F7/105
Abstract: PURPOSE: A black photo-sensitive resin composition and a light shielding layer formed using the same are provided to improve heat resistance and chemical resistance by including a cardo-based binder resin. CONSTITUTION: A black photo-sensitive resin composition includes 0.5 to 20 weight% of a cardo-based binder resin, 1 to 20 weight% of a reactive unsaturated compound, 0.1 to 10 weight% of a photo-polymerization initiator, 1 to 25 weight% of black mixed pigment, and a solvent. The black mixed pigment is black by including orange, blue, violet pigments in the ratio of 20 to 45: 20 to 45: 5 to 20 weight%. Based on the black photo-sensitive resin composition, a spacer(20) is formed.
Abstract translation: 目的：提供黑色光敏树脂组合物和使用其的遮光层，以通过包含基于硬质的粘合剂树脂来提高耐热性和耐化学性。 构成：黑色感光性树脂组合物含有0.5〜20重量％的cardo系粘合剂树脂，1〜20重量％的反应性不饱和化合物，0.1〜10重量％的光聚合引发剂，1〜25重量％ ％的黑色混合颜料和溶剂。 黑色混合颜料是黑色的，包括比例为20:45:20:45:5-20重量％的橙色，蓝色，紫色颜料。 基于黑色光敏树脂组合物，形成间隔物（20）。
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公开(公告)号：KR100725023B1
公开(公告)日：2007-06-07
申请号：KR1020060100167
申请日：2006-10-16
Applicant: 제일모직주식회사
Abstract: Provided is a cardo type resin-containing resin composition, which is useful for forming a micropattern, and imparts excellent heat resistance, chemical resistance, developability and adhesion to a color filter for display devices. The resin composition comprises a cardo type resin having repeating units represented by a formula 1. In the formula 1, each of R1 and R2 represents H, a halogen atom or a C1-C5 alkyl group; R3 is a vinyl, acryl or methacryl group; Z is a residue of acid anhydrides or acid dianhydrides; and X represents -CO-, -SO2-, -C(CF3)2-, -Si(CH3)2-, -CH2-, -C(CH3)2-, -O-, or an aromatic divalent radical. The resin composition comprises: (a) 1-30 wt% of a cardo type resin; (b) 1-30 wt% of a reactive unsaturated compound; (c) 0.1-10 wt% of an initiator; and the balance amount of water.
Abstract translation: 本发明提供一种可用于形成微细图案的含有Cardo型树脂的树脂组合物，其对显示装置用滤色器赋予优异的耐热性，耐化学药品性，显影性和密合性。 所述树脂组合物包含具有由式1表示的重复单元的卡多型树脂。在式1中，R 1和R 2各自表示H，卤素原子或C 1 -C 5烷基; R3是乙烯基，丙烯酰基或甲基丙烯酰基; Z是酸酐或酸二酐的残基; 且X表示-CO - ， - SO 2 - ， - C（CF 3）2 - ， - Si（CH 3）2 - ， - CH 2 - ， - C（CH 3）2 - ， - O-或芳族二价基团。 该树脂组合物包含：（a）1-30重量％的cardo型树脂; （b）1-30重量％的反应性不饱和化合物; （c）0.1-10wt％的引发剂; 和平衡量的水。
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