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公开(公告)号：KR1020020019237A
公开(公告)日：2002-03-12
申请号：KR1020000052400
申请日：2000-09-05
Applicant: 한국과학기술연구원 , 한화케미칼 주식회사
CPC classification number: H01L51/0043 , C08G61/02 , C08L65/00 , C09K11/06 , H01L51/0035 , H01L51/0038 , H01L51/0039 , Y10S428/917
Abstract: PURPOSE: A fullerene-based polymer and an electroluminescent device using the polymer are provided, wherein the polymer is prepared by simple method, is soluble in an organic solvent and can be mixed with other polymers easily. CONSTITUTION: The fullerene-based polymer is represented by the formula 1, wherein R1, R2 and R3 are independent each another and are H, an aromatic or aliphatic alkyl or alkoxy group of C1-C22, an aryl or aryloxy group of C6-C18, cyano group, cyanoethyl group, an alkyl or aryl derivative of silicon, tin and germanium; X is diacetylene, diethynyl aryl or divinyl aryl group, or a single bond; and n is an integer equal to or greater than 1. Preferably n is an integer of 1-1,000. The electroluminescent device contains a luminescent layer comprising the fullerene-based polymer and other polymers.
Abstract translation: 目的：提供一种富勒烯类聚合物和使用该聚合物的电致发光元件，其中聚合物通过简单的方法制备，可溶于有机溶剂中，并且可以容易地与其它聚合物混合。 构成：富勒烯类聚合物由式1表示，其中R1，R2和R3彼此独立，为H，C1-C22的芳族或脂族烷基或烷氧基，C6-C18的芳基或芳氧基 ，氰基，氰基乙基，硅，锡和锗的烷基或芳基衍生物; X是乙炔基，二乙炔基芳基或二乙烯基芳基，或单键; n为1以上的整数。n为1-1000的整数。 电致发光器件含有包含富勒烯类聚合物和其它聚合物的发光层。
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公开(公告)号：KR1020030034659A
公开(公告)日：2003-05-09
申请号：KR1020010066330
申请日：2001-10-26
Applicant: 한국과학기술연구원
IPC: C09K11/06
CPC classification number: C08G73/10 , Y10S428/917 , Y10T428/31507 , Y10T428/31855
Abstract: PURPOSE: Fluorene-like compounds having polyphenylene, polymers thereof and an EL element containing the same are provided. The fluorene-like compounds are used as a principal ingredient of organic and polymeric electroluminescence elements and/or other optical elements. CONSTITUTION: Fluorene-like compounds having polyphenylene are prepared by Diels-Alder reaction of a compound having one or more of cyclopentadienones and a compound having one or more of acetylenes. The fluorene-like compounds are represented by the formula(1), wherein R1, R2, R1' and R2' are the same or different, and are independently a substituent selected from the group consisting of hydrogen, C1 to C22 aliphatic or alicyclic alkyl and alkoxy, C6 to C18 aryl or aryloxy, silicone, alkyl and aryl derivatives of tin or germanium, and halogen atom; Ar and Ar2 are the same or different, and are independently hydrogen, trimethylsillyl, bromine, alkyl, or C6 to C18 aromatics such as phenyl, naphthyl and derivatives thereof; Ar' is a substituent selected from the group consisting of aromatics and hetero compounds such as phenylene, naphthalene, anthracene, fluorene, thiophene, pyrrole, pyridine, aryloxadiazol, triazole, carbazole, arylamine, arylsilane and derivatives thereof; m is 0 or 1; and n is 1.
Abstract translation: 目的：提供具有聚亚苯基的芴类化合物，其聚合物和含有它们的EL元件。 芴类化合物用作有机和聚合物电致发光元件和/或其它光学元件的主要成分。 构成：具有聚亚苯基的芴类化合物通过具有一个或多个环戊二烯酮和具有一个或多个炔属的化合物的化合物的Diels-Alder反应制备。 芴类化合物由式（1）表示，其中R 1，R 2，R 1'和R 2'相同或不同，并且独立地是选自氢，C 1至C 22脂族或脂环族烷基 烷氧基，C6至C18芳基或芳氧基，硅或锗的硅氧烷，烷基和芳基衍生物和卤素原子; Ar和Ar 2相同或不同，独立地为氢，三甲基硅烷基，溴，烷基或C 6至C 18芳族化合物如苯基，萘基及其衍生物; Ar'是选自芳烃和杂化合物如亚苯基，萘，蒽，芴，噻吩，吡咯，吡啶，芳基恶唑，三唑，咔唑，芳基胺，芳基硅烷及其衍生物的取代基。 m为0或1; n为1。
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3.发明授权
公开(公告)号：KR100411465B1
公开(公告)日：2003-12-18
申请号：KR1020010066330
申请日：2001-10-26
Applicant: 한국과학기술연구원
IPC: C09K11/06
CPC classification number: C08G73/10 , Y10S428/917 , Y10T428/31507 , Y10T428/31855
Abstract: A fluorene compound and polymers thereof having a polyphenylene group, and EL element comprising the same, which can be prepared through a Diels-Alder reaction of a compound having one or more cyclopentadienone group and a compound having one or more acetylene group and can be used as a core material for organic and polymeric EL element and/or other optical devices.
Abstract translation: 具有聚亚苯基的芴化合物及其聚合物及含有其的EL元件，其可通过具有一个或多个环戊二烯酮基团的化合物与具有一个或多个乙炔基团的化合物的Diels-Alder反应制备并可使用 作为有机和聚合物EL元件和/或其他光学器件的核心材料。
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