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    폴리아릴렌계 화합물과 그 중합체 및 이들을 이용한 ＥＬ소자
    1.
    发明公开
    폴리아릴렌계 화합물과 그 중합체 및 이들을 이용한 ＥＬ소자 有权
    基于聚亚烷基的化合物，其聚合物和使用其的EL元件

    公开(公告)号：KR1020040091851A

    公开(公告)日：2004-11-02

    申请号：KR1020030025469

    申请日：2003-04-22

    Applicant: 한국과학기술연구원

    Inventor： 조현남 ,  정성현 ,  박석진

    IPC: C09K11/06

    CPC classification number: C08G61/125 ,  C08G61/10 ,  C08G61/12 ,  C08G61/123 ,  C08G61/124 ,  C08G61/126 ,  Y10S428/917

    Abstract: PURPOSE: Provided are a polyarylene-based compound and a polymer thereof, which are identical in structure and are soluble into organic solvents, and thus are applicable to electronic elements such as electroluminescence(EL) elements. CONSTITUTION: The polyarylene-based compound and the polymer thereof are each represented by the formula 1, wherein each of R1, R2, R1' and R2' is the same or different and is a substituent selected from the group consisting of hydrogen, aromatic or aliphatic alkyl and alkoxy group, aryl group or aryloxy group, alkyl and aryl derivatives of silicone, tin or germanium and halogen atom; Ar1 or Ar2 are the same or different, and may include hydrogen, trimethylsilyl, bromine and alkyl and represents an aromatic group such as phenyl, naphthyl and derivatives thereof; and each of Ar and Ar' is an arylene group selected from the group consisting of phenylene, naphthalene, anthracene, fluorene, thiophene, pyrrole, pyridine, aryloxadiazole, triazole, carbazole, arylamine, arylsilane and derivatives thereof; m is 0 or 1; and n is 1.

    Abstract translation: 目的：提供结构相同且可溶于有机溶剂的聚亚芳基系化合物及其聚合物，因此可用于电致发光（EL）元件等电子元件。 构成：聚亚芳基系化合物及其聚合物各自由式1表示，其中R 1，R 2，R 1'和R 2'各自相同或不同，并且是选自氢，芳族或 脂族烷基和烷氧基，芳基或芳氧基，硅氧烷，锡或锗和卤原子的烷基和芳基衍生物; Ar 1或Ar 2可以相同或不同，可以包括氢，三甲基甲硅烷基，溴和烷基，代表芳基如苯基，萘基及其衍生物; Ar和Ar'分别为亚苯基，萘，蒽，芴，噻吩，吡咯，吡啶，芳基恶唑，三唑，咔唑，芳基胺，芳基硅烷及其衍生物的亚芳基。 m为0或1; n为1。

    피롤계 화합물, 그 중합체 및 이들을 이용한 ＥＬ 소자
    2.
    发明公开
    피롤계 화합물, 그 중합체 및 이들을 이용한 ＥＬ 소자 失效
    基于PYRROLE的化合物，其聚合物和使用其的EL器件

    公开(公告)号：KR1020040014814A

    公开(公告)日：2004-02-18

    申请号：KR1020020047559

    申请日：2002-08-12

    Applicant: 한국과학기술연구원

    Inventor： 조현남 ,  정성현 ,  손상원 ,  원제홍

    IPC: C08F226/06

    CPC classification number: H05B33/14 ,  C08G61/125 ,  C08G73/0611 ,  C09K11/06 ,  C09K2211/1466 ,  H01L51/0035 ,  H01L51/0038 ,  H01L51/0043

    Abstract: PURPOSE: A pyrrole-based polymer and an electroluminescence device using the polymer are provided, to obtain a novel pyrrole-based polymer showing excellent solubility in an organic solvent, light-emitting property and transporting property. CONSTITUTION: The pyrrole-based polymer is represented by the formula 1, wherein R1 and R2 are identical or different each other and are H, an aliphatic or alicyclic alkyl, acyl or alkoxy group of C1-C24, an aryl or aryloxy group of C6-C30, a halogen-containing substituent, a silicon-containing substituent, an organic acid or an ester of organic acids; Ar1, Ar2 and Ar3 are identical or different one another and are an aromatic group of C6-C30, or a halogen, metal or hetero atom-containing aromatic group; Ar' is an aromatic group or a hetero atom-containing cyclic group; m is an integer of 0 or more; and n is an integer of 1 or more.

    Abstract translation: 目的：提供使用该聚合物的吡咯系聚合物和电致发光元件，得到在有机溶剂中显示出优异的溶解性的新颖的吡咯系聚合物，发光特性和输送性。 构成：吡咯基聚合物由式1表示，其中R1和R2彼此相同或不同，为H，C1-C24的脂族或脂环族烷基，酰基或烷氧基，C6的芳基或芳氧基 -C30，含卤素的取代基，含硅取代基，有机酸或有机酸的酯; Ar1，Ar2和Ar3彼此相同或不同，为C6-C30的芳族基团或含卤素，金属或含杂原子的芳族基团; Ar'是芳族基团或含杂原子的环状基团; m为0以上的整数， n为1以上的整数。

    폴리페닐렌을 갖는 플로렌계 화합물, 그 중합체 및 이들을포함하는 ＥＬ 소자
    3.
    发明公开
    폴리페닐렌을 갖는 플로렌계 화합물, 그 중합체 및 이들을포함하는 ＥＬ 소자 失效
    具有聚苯乙烯的氟类化合物，其聚合物和含有它的EL元素

    公开(公告)号：KR1020030034659A

    公开(公告)日：2003-05-09

    申请号：KR1020010066330

    申请日：2001-10-26

    Applicant: 한국과학기술연구원

    Inventor： 조현남 ,  정성현 ,  손상원 ,  김종복

    IPC: C09K11/06

    CPC classification number: C08G73/10 ,  Y10S428/917 ,  Y10T428/31507 ,  Y10T428/31855

    Abstract: PURPOSE: Fluorene-like compounds having polyphenylene, polymers thereof and an EL element containing the same are provided. The fluorene-like compounds are used as a principal ingredient of organic and polymeric electroluminescence elements and/or other optical elements. CONSTITUTION: Fluorene-like compounds having polyphenylene are prepared by Diels-Alder reaction of a compound having one or more of cyclopentadienones and a compound having one or more of acetylenes. The fluorene-like compounds are represented by the formula(1), wherein R1, R2, R1' and R2' are the same or different, and are independently a substituent selected from the group consisting of hydrogen, C1 to C22 aliphatic or alicyclic alkyl and alkoxy, C6 to C18 aryl or aryloxy, silicone, alkyl and aryl derivatives of tin or germanium, and halogen atom; Ar and Ar2 are the same or different, and are independently hydrogen, trimethylsillyl, bromine, alkyl, or C6 to C18 aromatics such as phenyl, naphthyl and derivatives thereof; Ar' is a substituent selected from the group consisting of aromatics and hetero compounds such as phenylene, naphthalene, anthracene, fluorene, thiophene, pyrrole, pyridine, aryloxadiazol, triazole, carbazole, arylamine, arylsilane and derivatives thereof; m is 0 or 1; and n is 1.

    Abstract translation: 目的：提供具有聚亚苯基的芴类化合物，其聚合物和含有它们的EL元件。 芴类化合物用作有机和聚合物电致发光元件和/或其它光学元件的主要成分。 构成：具有聚亚苯基的芴类化合物通过具有一个或多个环戊二烯酮和具有一个或多个炔属的化合物的化合物的Diels-Alder反应制备。 芴类化合物由式（1）表示，其中R 1，R 2，R 1'和R 2'相同或不同，并且独立地是选自氢，C 1至C 22脂族或脂环族烷基 烷氧基，C6至C18芳基或芳氧基，硅或锗的硅氧烷，烷基和芳基衍生物和卤素原子; Ar和Ar 2相同或不同，独立地为氢，三甲基硅烷基，溴，烷基或C 6至C 18芳族化合物如苯基，萘基及其衍生物; Ar'是选自芳烃和杂化合物如亚苯基，萘，蒽，芴，噻吩，吡咯，吡啶，芳基恶唑，三唑，咔唑，芳基胺，芳基硅烷及其衍生物的取代基。 m为0或1; n为1。

    폴리(플로렌비닐렌-파라페닐렌비닐렌)계 공중합 전기발광고분자 및 이의 제조방법
    5.
    发明授权
    폴리(플로렌비닐렌-파라페닐렌비닐렌)계 공중합 전기발광고분자 및 이의 제조방법 失效
    电致发光聚氟乙烯 - 共对苯乙烯及其制备方法

    公开(公告)号：KR100510057B1

    公开(公告)日：2005-08-25

    申请号：KR1020020064323

    申请日：2002-10-21

    Applicant: 한국과학기술연구원

    Inventor： 조현남 ,  진성호 ,  정성현 ,  박혜진

    IPC: C08G61/00 ,  C09K11/06

    Abstract: 본 발명은 발광 고분자의 주쇄에 다양한 형태의 치환기를 도입하여 밴드 갭(band gap)을 조절함으로써 발광색이 조절될 수 있는, 전기광학 특성이 우수한 새로운 폴리(플로렌비닐렌-파라페닐렌비닐렌)계 공중합 전기발광 고분자 및 이의 제조방법에 관한 것이다. 본 발명에 따른 폴리(플로렌비닐렌-파라페닐렌비닐렌)계 공중합 전기 발광 고분자는 그 주쇄에 다양한 입체적 장애를 가져올 수 있는 치환기가 도입된 실릴페닐기 또는 전자 주게(electron donor) 치환기인 알콕시기가 도입되어 있는 것을 특징으로 한다. 본 발명의 전기발광 고분자는 유기 용매에 대한 용해성, 전극과의 계면 접착력, 박막 특성, 전계에 대한 안정성 등이 우수하므로, 전기 발광 다이오드의 발광층으로 사용될 수 있다.

    관능기를 함유한 플로렌계 화합물, 그 중합체 및 이들을이용한 ＥＬ 소자
    6.
    发明公开
    관능기를 함유한 플로렌계 화합물, 그 중합체 및 이들을이용한 ＥＬ 소자 失效
    含有氟化物的化合物，其聚合物和使用其的电致发光器件

    公开(公告)号：KR1020020088937A

    公开(公告)日：2002-11-29

    申请号：KR1020010028020

    申请日：2001-05-22

    Applicant: 한국과학기술연구원

    Inventor： 조현남 ,  김영철 ,  홍재민 ,  정성현 ,  손상원

    IPC: C09K11/06

    CPC classification number: C07C69/76 ,  C07C22/04 ,  C07C25/22 ,  C07C25/24 ,  C07C33/36 ,  C07C43/21 ,  C07C47/546 ,  C07C47/575 ,  C07C63/49 ,  C07C65/26 ,  C07C205/06 ,  C07C205/22 ,  C07C205/35 ,  C07C205/38 ,  C07C211/50 ,  C07C255/34 ,  C07C255/51 ,  C07C261/02 ,  C07C2603/18 ,  C07F5/025 ,  C09B11/02 ,  C09B23/141 ,  C09B69/10

    Abstract: PURPOSE: Provided are a fluorene based compound having various functional groups, which can be applied as electroluminescence material, and other optoelectronic material, a polymer thereof, and an electroluminescence device using the same as illuminant. CONSTITUTION: The fluorene based compound is represented by formula 1. In the formula 1, R represents hydrogen, an aliphatic or alicyclic alkyl or alkoxy group having C1-C22, aryl or aryloxy group having C6-C18, or alkyl or aryl derivatives such as silicon, tin, or germanium, R' represents a functional group positioned in meta or para position of phenyl group, which is optionally selected from the group consisting of ether, ester, amine, amide, aldehyde, ketone, sulfone, sulfide, nitro, nitrile, acetylene, halogen, carboxylic acid, boric acid, vinyl, hydrazide, isocyanate, urethane, carbonate, chloromethyl, hydroxy, anhydride, cyanate, azomethine, quinoline, oxadiazole, and azo groups, and n is 0 or 1.

    Abstract translation: 目的：提供具有各种官能团的芴基化合物，其可以用作电致发光材料，以及其它光电子材料，其聚合物，以及使用其作为发光体的电致发光器件。 构成：芴基化合物由式1表示。在式1中，R表示氢，具有C 1 -C 22的脂族或脂环族烷基或烷氧基，具有C 6 -C 18的芳基或芳氧基，或烷基或芳基衍生物，例如 硅，锡或锗，R'表示位于苯基的间位或对位的官能团，其任选地选自醚，酯，胺，酰胺，醛，酮，砜，硫醚，硝基， 腈，乙炔，卤素，羧酸，硼酸，乙烯基，酰肼，异氰酸酯，氨基甲酸酯，碳酸酯，氯甲基，羟基，酸酐，氰酸酯，偶氮甲碱，喹啉，恶二唑和偶氮基，n为0或1。

    폴리페닐렌을 갖는 플로렌계 화합물, 그 중합체 및 이들을포함하는 ＥＬ 소자
    9.
    发明授权
    폴리페닐렌을 갖는 플로렌계 화합물, 그 중합체 및 이들을포함하는 ＥＬ 소자 失效
    폴리페닐을갖는플렌렌렌계합물합물EL EL EL EL EL EL EL EL EL EL EL

    公开(公告)号：KR100411465B1

    公开(公告)日：2003-12-18

    申请号：KR1020010066330

    申请日：2001-10-26

    Applicant: 한국과학기술연구원

    Inventor： 조현남 ,  정성현 ,  손상원 ,  김종복

    IPC: C09K11/06

    CPC classification number: C08G73/10 ,  Y10S428/917 ,  Y10T428/31507 ,  Y10T428/31855

    Abstract: A fluorene compound and polymers thereof having a polyphenylene group, and EL element comprising the same, which can be prepared through a Diels-Alder reaction of a compound having one or more cyclopentadienone group and a compound having one or more acetylene group and can be used as a core material for organic and polymeric EL element and/or other optical devices.

    Abstract translation: 具有聚亚苯基的芴化合物及其聚合物及含有其的EL元件，其可通过具有一个或多个环戊二烯酮基团的化合物与具有一个或多个乙炔基团的化合物的Diels-Alder反应制备并可使用 作为有机和聚合物EL元件和/或其他光学器件的核心材料。

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