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    구아이아콜로부터 고수율의 바이오연료를 제조하는 방법
    1.
    发明公开
    구아이아콜로부터 고수율의 바이오연료를 제조하는 방법 有权
    从GUAIACOL制备高产生物素的方法

    公开(公告)号：KR1020130017250A

    公开(公告)日：2013-02-20

    申请号：KR1020110079566

    申请日：2011-08-10

    Applicant: 한국과학기술연구원

    Inventor： 서동진 ,  하정명 ,  최재욱 ,  양기석 ,  윤영현 ,  이초림 ,  윤지선 ,  서영웅

    IPC: C10G3/00 ,  C10L1/02 ,  C07C4/06 ,  B01J23/40

    CPC classification number: Y02E50/13 ,  Y02P30/20 ,  C10G3/00 ,  B01J23/40 ,  C07C4/06 ,  C10L1/02

    Abstract: PURPOSE: A manufacturing method is provided to offer a manufacturing method of high-yield biofuel by hydrogenation-dehydration reaction of guaiacol using bifunctional catalyst and using biomass as a source including guaiacol. CONSTITUTION: A manufacturing method of biofuel includes a stage of injecting bifunctional catalyst including reaction solution including guaiacol, metal catalyst and acid catalyst into a reactor; a stage of cleaning a reactor and inside of a pipe connected with the reactor; a stage of increasing entire pressure of hydrogen and reaction solution by injecting hydrogen into the reactor; a stage of mixing hydrogen and reaction solution; a stage of progressing hydrogenation dehydration reaction; a stage of cooling the reactor; and a stage of collecting and analyzing a created product inside of the reactor. The metal catalyst is a metal nano particle for hydrogenation. The metal catalyst is one or alloy consisting of more than two of a group consisting of Pt, Pd, Ru, Ir and Rh. The acid catalyst is an acid catalyst for dehydration, is porous or non-porous catalytic converter reacting with a metal catalyst and an acid group is present on the surface of the catalytic converter. The catalytic converter is selected more than one of a group consisting of silica-alumina complex oxide, alumina, an activated carbon, zirconia and silica. The catalytic converter is selectively formed of a group consisting of a bulk, a plate, a powder, a pellet, a ball and an aerogel. The acid group is generated after processing an inorganic acid selected from a group consisting of a nitric acid, a sulfuric acid and a hydrochloric acid. The content of the metal catalyst ranges from 0.1 to 20 weight% based on weight of the catalytic converter. [Reference numerals] (AA) Guaiacol conversion rate or product yield(water%); (BB) Rh/silica-alumina, 20 minutes; (CC) Rh/silica-alumina, 40 minutes; (DD) Rh/silica-alumina, 1 hour; (EE) Rh/silica-alumina, 2 hours; (FF) Guaiacol conversion rate; (GG) Cyclohexane yield; (HH) Cyclohexanol yield; (II) Cyclohexanone yield; (JJ) 2-methoxy cyclohexanone yield; (KK) Phenol yield

    Abstract translation: 目的：提供一种制造方法，通过双功能催化剂和使用生物质作为来源包括愈创木酚的方法，通过愈创木酚的氢化 - 脱水反应提供高产率生物燃料的制造方法。 构成：生物燃料的制造方法包括将包含愈创木酚，金属催化剂和酸催化剂的反应溶液的双功能催化剂注入反应器的阶段; 清洁反应器和与反应器连接的管道内部的阶段; 通过将氢气注入反应器来提高氢气和反应溶液的全部压力的阶段; 氢和反应溶液的混合阶段; 进行氢化脱水反应的一个阶段; 冷却反应堆的阶段 以及收集和分析反应堆内部产生的产品的阶段。 金属催化剂是用于氢化的金属纳米颗粒。 金属催化剂是由Pt，Pd，Ru，Ir和Rh组成的组中的两种以上组成的一种或合金。 酸催化剂是用于脱水的酸催化剂，是与金属催化剂反应的多孔或无孔催化转化器，并且在催化转化器的表面上存在酸基团。 催化转化器选自二氧化硅 - 氧化铝复合氧化物，氧化铝，活性炭，氧化锆和二氧化硅中的一种以上。 催化转化器选择性地由本体，板，粉末，丸粒，球和气凝胶组成。 在加工选自硝酸，硫酸和盐酸的无机酸之后产生酸基。 金属催化剂的含量基于催化转化器的重量为0.1-20重量％。 （参考号）（AA）愈创木酚转化率或产率（水％）; （BB）Rh /二氧化硅 - 氧化铝，20分钟; （CC）Rh /二氧化硅 - 氧化铝，40分钟; （DD）Rh /二氧化硅 - 氧化铝，1小时; （EE）Rh /二氧化硅 - 氧化铝，2小时; （FF）愈创木酚转化率; （GG）环己烷收率; （HH）环己醇产率; （II）环己酮产率; （JJ）2-甲氧基环己酮产率; （KK）苯酚产率

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