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公开(公告)号：WO2013073826A1
公开(公告)日：2013-05-23
申请号：PCT/KR2012/009589
申请日：2012-11-14
Applicant: 한국과학기술연구원
IPC: H01M4/48 , H01M10/052 , H01M4/1391 , C01G45/00
CPC classification number: C01G45/00 , B82Y30/00 , C01P2004/64 , H01M4/1391 , H01M4/485 , H01M4/505 , H01M10/052
Abstract: 본 발명은 ZnO 및 MnO가 화학적으로 결합된 복합체, 이를 포함하는 리튬 이차전지용 음극 활물질 및 이의 제조방법에 관한 것이다. 본 발명에 따르면, 전기적 특성이 우수한 리튬 이차전지용 음극의 제공을 가능케 하는 ZnO-MnO 복합체 및 이를 포함하는 음극 활물질이 제공되며, 상기 음극 활물질을 보다 단순화된 공정으로 제조할 수 있는 방법이 제공된다.
Abstract translation: 本发明涉及其中ZnO与MnO化学键合的配合物，涉及其含有锂二次电池的负极活性物质及其制造方法。 根据本发明，具有优异的电特性以便能够生产用于锂二次电池的负极的ZnO-MnO络合物，含有该锂二次电池的负极活性材料及其制造方法 提供了通过简化过程的活性材料。
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公开(公告)号：KR1020130052926A
公开(公告)日：2013-05-23
申请号：KR1020110118275
申请日：2011-11-14
Applicant: 한국과학기술연구원
IPC: H01M4/48 , H01M10/052 , H01M4/1391 , C01G45/00
CPC classification number: C01G45/00 , B82Y30/00 , C01P2004/64 , H01M4/1391 , H01M4/485 , H01M4/505 , H01M10/052
Abstract: PURPOSE: A negative electrode active material is provided to provide a negative electrode for lithium secondary batteries with excellent electric performance and to be simply manufactured. CONSTITUTION: A negative electrode active material comprises a composite particle which is chemically coupled with ZnO and MnO. The composite particle has an average particle diameter of 100 nm or less. A manufacturing method of a negative electrode active material comprises a step of molding a composite particle which is chemically coupled with ZnO and MnO by treating ZnMn2O4 powder in an inert or reduction atmosphere. The heat treatment is conducted at 600-900 °C for 4-10 hours. The ZnMn2O4 powder is prepared by a solvothermal synthesis method or a co-precipitation method. [Reference numerals] (AA) ZnMn2O4 powder; (BB) ZnO-MnO complex; (CC) Thermal treatment under inactive or reduction atmosphere(at 600-900°C for 4-10 hours)
Abstract translation: 目的：提供负极活性物质，以提供具有优异电性能的锂二次电池用负极，并且简单地制造。 构成：负极活性材料包括与ZnO和MnO化学偶联的复合颗粒。 复合粒子的平均粒径为100nm以下。 负极活性物质的制造方法包括通过在惰性或还原气氛中处理ZnMn 2 O 4粉末来模制与ZnO和MnO化学偶合的复合粒子的工序。 热处理在600-900℃进行4-10小时。 通过溶剂热合成法或共沉淀法制备ZnMn2O4粉末。 （AA）ZnMn2O4粉末; （BB）ZnO-MnO络合物; （CC）在无活性或还原气氛（600-900℃，4-10小时）下进行热处理
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公开(公告)号：KR101232263B1
公开(公告)日：2013-02-12
申请号：KR1020110023359
申请日：2011-03-16
Applicant: 한국과학기술연구원
CPC classification number: Y02E60/128 , Y02T10/7011
Abstract: 본 발명은 리튬-공기 전지용 탄소계 양극에 관한 것으로서, 보다 상세하게는 연속상의 다공성 집전체(current collector), 및 표면적이 500 내지 2000 ㎡/g이고 공극량이 0.5 내지 5 ㎤/g인 탄소 분말과 바인더 수지를 포함하며, 상기 집전체의 공극 내에 포함되는 조성물을 포함하는 리튬-공기 전지용 탄소계 양극; 상기 탄소 전극의 제조 방법; 및 상기 탄소계 양극을 포함하는 리튬-공기 전지에 관한 것이다.
본 발명에 따른 탄소계 양극은 리튬의 산화반응이 원활하게 일어날 수 있는 최적의 공극을 제공함에 따라, 이를 포함하는 리튬-공기 전지는 방전 성능이 안정적이며, 에너지 밀도가 높고, 이론 방전 용량에 가까운 성능을 발현할 수 있는 장점이 있다.-
Patent Agency Ranking4.发明公开리튬-공기전지(Li-Air battery)용 공기전극의 제조 방법 및 이를 이용한 리튬-공기 전지(Li-Air battery) 无效用于锂离子空气电池的空气喷涂涂覆碳基空气阴极的制备方法和使用其的LI空气电池
公开(公告)号：KR1020140022735A
公开(公告)日：2014-02-25
申请号：KR1020130096423
申请日：2013-08-14
Applicant: 한국과학기술연구원
IPC: H01M4/88 , H01M4/1393 , H01M12/06
CPC classification number: H01M4/88 , H01M4/8668 , H01M4/8828 , H01M4/8882 , H01M4/9016 , H01M4/96 , H01M8/0232 , H01M12/08 , Y02E60/128
Abstract: The present invention relates to a method for manufacturing an air electrode for a lithium-air battery having a high capacity and excellent cycle characteristics, and a lithium-air battery using the same. More particularly, the present invention can improve homogeneity on the surface of an electrode due to active materials uniformly dispersed not only on the surface of a current collector but also on a frame inside, by coating electrode active material slurry including carbon or carbon, a catalyst and a binder on the current collector of an air electrode via a spray coating method. Therefore, the present invention improves the characteristics of a lithium-air battery and provides an air electrode having the characteristics of a secondary battery and a lithium-air battery including the same, as a cathode. [Reference numerals] (AA) Comparative example 2; (BB) Comparative example 1; (CC) Example 1
Abstract translation: 本发明涉及一种具有高容量和优异的循环特性的锂空气电池用空气电极的制造方法和使用其的锂空气电池。 更具体地，本发明可以通过涂覆包括碳或碳的电极活性材料浆料，由于活性材料不仅均匀分散在集电体的表面上而且在框架内部均匀分散，可以改善电极表面的均匀性，催化剂 以及通过喷涂法在空气电极的集电体上的粘合剂。 因此，本发明改进了锂空气电池的特性，并且提供了具有二次电池和包含该空气电池的锂空气电池的特性的空气电极作为阴极。 （附图标记）（AA）比较例2; （BB）比较例1; （CC）实施例1
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公开(公告)号：KR100772966B1
公开(公告)日：2007-11-02
申请号：KR1020060049711
申请日：2006-06-02
Applicant: 한국과학기술연구원
IPC: A61F2/28
CPC classification number: A61F2/2803 , A61L27/18 , A61L27/365 , A61L2300/604
Abstract: A biodegradable polymer material for fixing bone and a method for manufacturing the same are provided to improve crystallizing degree and orientating property of PLCL copolymer, to minimize molecular weight loss by thermal decomposition of polymer, and to allow flexibility and high strength. A method for manufacturing a biodegradable polymer material for fixing bone including the steps of: manufacturing PLCL copolymer with an average molecular weight more than 100,000 Da by polymerizing PLLA AND PCL; cooling the manufactured PLCL copolymer after vacuum compression shaping; pressing out the above product; and performing thermal fixation of the above product.
Abstract translation: 提供了用于固定骨的可生物降解的聚合物材料及其制造方法，以改善PLCL共聚物的结晶度和取向性能，通过聚合物的热分解使分子量损失最小化，并且允许柔软性和高强度。 一种用于制造用于固定骨的可生物降解的聚合物材料的方法，包括以下步骤：通过聚合PLLA和PCL制备平均分子量大于100,000Da的PLCL共聚物; 在真空压缩成型后冷却制造的PLCL共聚物; 压出上述产品; 并进行上述产品的热固定。
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公开(公告)号：KR1020120105736A
公开(公告)日：2012-09-26
申请号：KR1020110023359
申请日：2011-03-16
Applicant: 한국과학기술연구원
CPC classification number: Y02E60/128 , Y02T10/7011 , H01M4/96 , H01M4/661 , H01M4/808 , H01M4/8668 , H01M12/08
Abstract: PURPOSE: A carbon-based positive electrode for lithium-air battery is provided to provide a lithium secondary battery with stable charging performance, high energy density and charging capacity near theoretical discharge capacity by comprising optimized pores in which oxidation of lithium is activated. CONSTITUTION: A carbon-based positive electrode for lithium-air battery comprises a current collector of continuous phase, a composition comprised in pores of the current collector, comprising carbon powder and binder resin with a surface area is 500-2000 m^2/g and a pore amount of 0.5-5 cm^3/g. the composition comprises 100-450 parts by weight of carbon powder based on 100 parts by weight of the binder resin. The binder resin is one or more selected from polyvinylidene fluoride, polytetrafluoroethylene, and polytrifluorostyrenesulfonic acid.
Abstract translation: 目的：提供一种用于锂空气电池的碳基正极，通过包括锂的氧化被激活的优化孔来提供具有稳定的充电性能，高能量密度和接近理论放电容量的充电容量的锂二次电池。 构成：用于锂空气电池的碳基正电极包括连续相集流体，包含在集电器的孔中的组合物，其包含表面积为500-2000m 2 / g的碳粉和粘合剂树脂 孔数为0.5-5cm 3 / g。 基于100重量份的粘合剂树脂，该组合物包含100-450重量份的碳粉末。 粘合剂树脂是选自聚偏二氟乙烯，聚四氟乙烯和聚三氟乙烯磺酸中的一种或多种。
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公开(公告)号：KR1020140068287A
公开(公告)日：2014-06-09
申请号：KR1020120130974
申请日：2012-11-19
Applicant: 한국과학기술연구원
CPC classification number: Y02E60/128 , B01J23/468 , B01J23/002 , B01J23/6447 , B01J35/02 , B01J35/1019 , B01J37/0009 , B01J37/12 , B01J2523/00 , B01J2523/44 , B01J2523/54 , B01J2523/827 , H01M4/92 , H01M12/08
Abstract: The present invention relates to a complex metal oxide catalyst for lithium-air secondary batteries which can inhibit overvoltage which occurs during the charge/discharge of the lithium-air secondary batteries and oxidative decomposition of an electrolyte generated at both poles during charging, and a manufacturing method thereof. The complex metal oxide catalyst for lithium-air secondary batteries according to an embodiment of the present invention is represented by chemical formula 1. In the formula, A is lead (Pb) or bismuth (Bi), x is 0 or 1 and δ is 0 or 1.
Abstract translation: 本发明涉及一种用于锂空气二次电池的复合金属氧化物催化剂，其可以抑制在充电期间在锂二次电池的充电/放电期间发生的过电压和在两极产生的电解质的氧化分解，以及制造 方法。 根据本发明的实施方式的锂空气二次电池用复合金属氧化物催化剂由化学式1表示。在该式中，A为铅（Pb）或铋（Bi），x为0或1，δ为 0或1。
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公开(公告)号：KR101361754B1
公开(公告)日：2014-02-13
申请号：KR1020110118275
申请日：2011-11-14
Applicant: 한국과학기술연구원
IPC: H01M4/48 , H01M10/052 , H01M4/1391 , C01G45/00
CPC classification number: C01G45/00 , B82Y30/00 , C01P2004/64 , H01M4/1391 , H01M4/485 , H01M4/505 , H01M10/052
Abstract: 본 발명은 리튬이차전지용 음극 활물질 및 이의 제조방법에 관한 것으로서, 보다 상세하게는 ZnMn
2 O
4 분말을 열처리하여 형성되는 ZnO-MnO 복합체 입자를 포함하는 음극 활물질 및 이의 제조방법에 관한 것이다. 본 발명에 따르면, 전기적 특성이 우수한 리튬이차전지용 음극의 제공을 가능케 하는 음극 활물질이 제공되며, 상기 음극 활물질을 보다 단순화된 공정으로 제조할 수 있는 방법이 제공된다.Abstract translation: 本发明涉及其中ZnO与MnO化学键合的配合物，涉及其含有锂二次电池的负极活性物质及其制造方法。 根据本发明，具有优异的电特性以便能够生产用于锂二次电池的负极的ZnO-MnO络合物，含有该锂二次电池的负极活性材料及其制造方法 提供了通过简化过程的活性材料。
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